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流动催化热解法制备高质量多壁碳纳米管的研究

High-quality multiwalled carbon nanotubes prepared by the floating catalytic pyrolysis
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摘要 以甲烷为碳源,N2和H2作载气,二茂铁作催化剂前驱体,采用流动催化热解法制备出大量高质量取向性好的多壁碳纳米管(MWCNTs)。利用扫描电子显微镜(SEM),透射电子显微镜(TEM)和Raman光谱对碳纳米管的形貌和结构进行了表征。该制备过程工艺简单并且成本低廉,对实现碳纳米管的规模生产具有重要意义。 Methane was used as carbon source , nitrogen and hydrogen as carrier gas, and ferroeene as catalyst precursor to prepare high-quality aligned multiwalled carbon nanotubes at 850℃ by the floating catalytic pyrolysis method. And their morphology and structures were characterized by scanning electron microscopy, transmission electron microscopy and Raman spectrum. This synthesis technique shed light on large-scale synthesis of carbon nanotubes for its simplified processing and low-cost.
出处 《化工新型材料》 CAS CSCD 北大核心 2008年第12期73-74,共2页 New Chemical Materials
关键词 流动催化热解法 多壁碳纳米管 扫描电子显微镜 floating catalytic pyrolysis, multiwalled carbon nanotube, scanning electron microscopy
作者简介 侯超(1985-),男,在读硕士研究生,主要从事碳纳米管的研究。 联系人:刘宝春,男,博士,教授。
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参考文献8

  • 1Kim Y A, Hayashi T, Endo M, et al. Synthesis and structural characterization of thin multi-walled carbon nanotubes with a partially facetted cross section by a floating reactant method [J]. Carbon 2005, 43, 2243-2250.
  • 2Terrones M, Grobert N, Zhang J P, et al. Preparation of aligned carbon nanotubes catalysed by laser-etched cobalt thin films [J]. Chem Phys Lett, 1998, 285: 299-305.
  • 3Samant M K, Haram S K, Kapoor S. Synthesis of carbon nanotubes by catalytic vapor decomposition (CVD) method: Optimization of various parameters for the maximum yield[J]. Pramana J Phys. 2007, 68 (1) : 52-56.
  • 4王红娟,彭峰,黎志欣,朱汉才,邝志敏.Fe-Mo/MgO催化剂CVD法制备碳纳米管[J].化学反应工程与工艺,2005,21(1):76-80. 被引量:7
  • 5Wang X K, Lin X W, Meslch M, et al. Effect of hydrogen on the formation of carbon nanotubes[J]. J Mater Res, 1995, 10 (8) : 1997.
  • 6Kibria A K M F, Mo Y H , Nahm K S. Synthesis of carbon nanotubes over nickel-iron catalysts supported on alumina under controlled conditions[J]. Catal Lett, 2001,71 (3-4): 229-236.
  • 7Barreiro A ,Selbmann D ,Pichler T,et al, On the effects of solution and reaction parameters for the aerosol-assisted CVD growth of long carbon nanotubes [J]. Appl Phys A, 2006, 82: 720-721.
  • 8Lyu S C , Liu B C , Lee S H , et al. Large-scale synthesis of high-quality double-walled carbon nanotubes by catalytic decomposition of n-hexane[J]. J Phys Chem B, 2004, 108 (7): 2194.

二级参考文献12

  • 1王红娟,彭峰,黎志欣,朱汉才,邝志敏.CVD法制备碳纳米管的影响因素研究[J].石油化工,2004,33(z1):114-116. 被引量:2
  • 2Iijima S. Helical Microtubules of Graphitic Carbon. Nature, 1991, 354:56~58
  • 3Dai H J. Carbon Nanotubes: Opportunities and Challenges. Surf Sci, 2002, 500 (1~3): 218~241
  • 4Postma H W C, Teepen T, Yao Z, et al. Carbon Nanotube Single-Electron Transistors at Room Temperature. Science, 2001, 293(5527): 76~79
  • 5Tang Z K, Zhang L Y, Wang N, et al. Superconductivity in 4 Angstrom Single-Walled Carbon Nanotubes. Science, 2001, 292(5526): 2462~2465
  • 6Soneda Y, Duclaux L, Beguin F. Synthesis of High Quality Multi-Walled Carbon Nanotubes from the Decomposition of Acetylene on Iron-Group Metal Catalysts Supported on MgO. Carbon, 2002, 40(6): 965~969
  • 7Zhang R Y, Amlani I, Baker J, et al. Chemical Vapor Deposition of Single-Walled Carbon Nanotubes Using Ultrathin Ni/Al Film as Catalyst. Nano Letters, 2003. 3(6): 731~735
  • 8Li Q W, Yah H, Zhang J, et al. Effect of Hydrocarbons Precursors on the Formation of Carbon Nanotubes in Chemical Vapor Deposition. Carbon, 2004, 42(4) : 829~835
  • 9Lee T Y, Han H H, Choi S H, et al. Comparison of Source Gases and Catalyst Metals for Growth of Carbon Nanotube. Surface and Coatings Technology, 2003, 169~170:348
  • 10Jung M J, Kwang Y E, Lee J K, et al. Growth of Carbon Nanotubes by Chemical Vapor Depositon. Diamond and Related Mate rials, 2001, 10(3~7): 1235~1240

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