摘要
The palladium acetate-catalyzed synthesis of benzophenone in the mixture of water and ionic liquid is described. The Pd(OAc)2-H2O-[bmim][PF6]catalytic system is a desired green midium and is superior to the previous methods in organic systems in terms of reaction conditions, efficiency, and reaction time. It can be recovered and reused eight times with high efficiency and the use of expensive and environmentally unfavorable phosphine ligand is avoided.
The palladium acetate- catalyzed synthesis of benzophenone in the mixture of water and ionic liquid is described. The Pd（OAc）2 -H2O- [ bmim] [ PF6 ] catalytic system is a desired green midium and is superior to the previous methods in organic systems in terms of reaction conditions, efficiency, and reaction time. It can be recovered and reused eight times with high efficiency and the use of expensive and environmentally unfavorable phosphine ligand is avoided.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2008年第3期333-336,共4页
Chemical Research and Application
基金
国家自然基金资助项目(No.20571063)
作者简介
联系人：辛炳炜（1968-），女，博士，副教授，研究方向：绿色有机合成和金属有机催化。Email：bingweixin2@163．com
