摘要
碘冉酸阴离子桥联双核铜（Ⅱ）配合物的合成与磁性孟祥军寇会忠邹国彰廖代正姜宗慧＊王耕霖（南开大学化学系天津３０００７１）关键词碘冉酸，Ｃｕ（Ⅱ），双核配合物，合成，磁性１９９６－０８－２０收稿，１９９６－１１－１８修回国家自然科学基金资助项目随着生物无...
The preparation and characterization of a series of dinuclear copper(Ⅱ) complexes, Cu 2L 2IA(ClO 4) 2, are presented. The ligand L is 1,10 phenanthroline(phen), 5 nitro 1,10 phenanthroline(NO 2 phen) and 2,2 bipyridine, and IA denotes the dianion of iodanilic acid. The complexes are characterized by elemental analysis, IR, electronic spectra, ESR and variable temperature magnetic susceptibility measurements. The coordination geometry of copper(Ⅱ) ion is probably a distorted square pyramid. Room temperature ESR spectra of all the complexes studied show the Δ M s=±2 half field transitions. The variable temperature magnetic susceptibility of Cu 2(phen) 2IA(ClO 4) 2 had been measured (4 2￣300 K) and the exchange parameter, J , was found to be -29 18 cm -1 using the Heisenberg model. This indicates that an antiferromagnetic interaction exists between the metal ions.
出处
《应用化学》
CAS
CSCD
北大核心
1997年第2期60-62,共3页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金
关键词
碘冉酸
双核配合物
合成
磁性
铜配合物
iodanilic acid,Cu(Ⅱ),dinuclear complex,synthesis,magnetism
