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联噻唑衍生物荧光猝灭汞离子传感器的研究 被引量:2

Synthesis of(4,4′-Di(tert-butyl)-2,2′-bithiazole) and Its Fluorescence Response Toward Mercury(Ⅱ)
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摘要 合成了一种新的荧光体4,4′-叔丁基-2,2′-联噻唑(D tBBT),并将其PVC敏感膜用于Hg(Ⅱ)的检测。实验表明,Hg(Ⅱ)对D tBBT的荧光具有猝灭作用,当Hg(Ⅱ)浓度为1.0×10^-9~1.0×10^-5mol/L时,体系荧光猝灭度与Hg(Ⅱ)的浓度呈线性关系,据此建立了测定痕量Hg(Ⅱ)的高灵敏、高选择性方法,并用于河水中Hg(Ⅱ)的测定,获得了满意的结果。 New luminescent moleculel 4,4′-di(tert-butyl)-2,2′-bithiazole was synthesized and it′s fluorescence in PVC film has good response to Hg(Ⅱ) at 488 nm.The thin film exhibits good linear response within Hg(Ⅱ) concentration range 5.0×10-9-5.0×10-5 mol/L,with good sensitivity and selectivity with Hg(Ⅱ).This method has been applied for the determination of Hg(Ⅱ) in water samples containing potential interferents with satisfactory recovery.
出处 《分析测试学报》 CAS CSCD 北大核心 2007年第5期722-723,726,共3页 Journal of Instrumental Analysis
基金 西南科技大学青年教师预研基金项目(ZK04300206ZX3127)
关键词 荧光敏感材料 4 4′-叔丁基-2 2′-联噻唑(DtBBT) Hg(Ⅱ) 荧光猝灭 传感器 Fluorescence sensitized material 4,4′-di(tert-butyl)-2,2′-bithiazole Hg(Ⅱ) Fluorescence quenching Sensor
作者简介 熊小莉(1970-),女,硕士,四川大英人,讲师.Tel:0816-6332495,E-mail:xiongxiaoli@swust.edu.cn
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