摘要
Hydrothermal treatment of racemic atropisomeric ligand diethyl (R,S)-7,7′-dimethyl-4,4′-biquinoline-3,3′-dicarboxylate (DDBD) in the presence of pyridine over 4 days at 140 ℃ with Zn(OAc)2 offers zinc coordination polymer {Zn(DBD)(pyridine)2(H2O)}n{Zn(DBD)(H2O)1/2}n (1), which shows weak fluorescence at about 490 nm at solid state at room temperature. CCDC: 631007.
Hydrothermal treatment of racemic atropisomeric ligand diethyl （R,S）-7,7＇-dimethyl-4,4＇-biquinoline-3,3＇-dicarboxylate （DDBD） in the presence of pyridine over 4 days at 140 ℃ with Zn（OAc）2 offers zinc coordination polymer [{Zn（DBD）（pyridine）2（H2O）}n{Zn（DBD）（H2O）n}]n （1）, which shows weak fluorescence at about 490 nm at solid state at room temperature. CCDC： 631007.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2007年第7期1306-1308,共3页
Chinese Journal of Inorganic Chemistry
基金
东南大学启动基金资助项目
关键词
锌配位聚合物
4
4′-喹啉酸
晶体结构
荧光性质
zinc coordination polymer
4,4＇-quinoline acid
crystal structure
fluorescence
作者简介
王威，男，28岁，副教授；研究方向：手性配合物分子电子学。E-mail：chem_wangw@seu．edu．cn
