摘要
首次合成了具有生物活性的系列配合物RE(Ⅲ)-ADP(稀土-腺苷二磷酸)和RE(Ⅲ)-AMP(稀土-腺苷-磷酸)(RE=Y,La,Ce,Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho,Er,Tm,Yb,Lu),根据红外、紫外、荧光、X射线衍射、元素分析、络合滴定等分析结果,研究了[RE(Ⅲ)(ADP)(H_2O)_3]和[RE(Ⅲ)(AMP)_2(H_2O)_4]H两个系列配合物的化学组成和性质。
The preparation of RE( Ⅲ )-ADP (rare earth-adenosine-5'-diphosphate) and RE( Ⅲ )-AMP(rare earth-adenosine-5'-raonophosphate) (RE = Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb, Lu) complexes possessing biological activities are first reported. The chemical compositions and trie properties of some of them have been elucidated on the basis of IR, UV, fluorescence, X-ray, elemental analysis and complexometric titratioh. The formulae of the complexes are [RE(Ⅲ) (ADP)(H2O)3] and [(RE(Ⅲ)(AMP)2(H2O)4]H, respectively.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1990年第8期805-808,共4页
Chemical Journal of Chinese Universities
关键词
稀土配合物
ADP
AMP
合成
RE( Ⅲ )-ADP, RE( Ⅲ )-AMP, Complex, Rare earth
