摘要
为探索制备PBX的新方法，利用原位聚合反应，直接在HMX表面包覆一层热塑性高聚物，获得了分别以端羟基聚丁二烯（HTPB），聚叠氮缩水甘油醚（GAP）、3，3-双（叠氮甲基）环氧丁烷-四氢呋喃共聚醚（BAMO-THF）3种黏结剂包覆的PBX。通过光学显微镜、显微-红外、光电子能谱（XPS）、元素分析和机械感度测定对包覆效果进行表征。结果表明，HMX表面较均匀地包覆上了一层聚合物，黏结剂的质量分数约为4％～5％，包覆HTPB的HMX机械感度明显下降，而包覆GAP和BAMO-THF的HMX机械感度略有降低。
In order to find a new method for preparing plastic bonded explosive （PBX） moulding powders, syclotetramethylene tetranitramine （HMX） was coated by a layer thermoplastic polymer using in-situ polymerization, and three kinds of HMX moulding powders coated by hydroxy-terminated polybutadiene （HTPB）, glycidyl azide polymer （GAP）,copolymer of 3, 3-bis-azidomethyl oxetalae and tetrahydrofuran （BAMO-THF） respectively were prepared accordingly. The moulding powders were analyzed by optical microscope, microscope- FTIR, and XPS, elemental analyses, impact sensitivity and friction sensitivity. The results show that HMX particles were uniformly coated by a layer of polymer. The content of binder is about 4%-5%. In comparison with pure HMX, mechanic sensitivity of HMX particles coated by HTPB had a remarkable decrease, but those by GAP and BAMO-THF only had a slightly decrease.
出处
《火炸药学报》
EI
CAS
CSCD
2007年第1期40-43,共4页
Chinese Journal of Explosives & Propellants
基金
中国工程物理研究院科学技术基金重大项目资助(2004Z0503)
关键词
高分子化学
原位聚合
HMX
PBX
包覆
high polymer chemistry
in-situ polymerization
HMX
PBX
coating
作者简介
黄亨建（1968-），男，副研究员，从事含能材料研究。
