摘要
对零价铁体系中邻氯苯酚的降解规律和影响因素进行了研究。采用间歇实验的方法,分别考察了pH值、铁粉添加量、初始浓度和铁碳比对邻氯苯酚去除率的影响。结果表明,邻氯苯酚在零价铁作用下,降解规律符合一级反应动力学模型;在本实验条件下,零价铁降解邻氯苯酚的最佳pH值为4~5,铁粉添加量为5~6g,溶液初始浓度为350~500mg/L,铁碳质量比为1.5~5。
The factors affecting the degradation of o-chlorophenol in zerovalent iron systems have been investigated. Laboratory batch experiments were run with varying pH values, quantities of zerovalent iron, initial solution concentration and iron-carbon ratios. The results show that the degradation of o-chlorophenol follows a first-order kinetics model. Degradation of o-chiorophenol was found to be maximized under the following condi- tions: pH of 4-5, quantity of zerovalent iron of 5 - 6 g, initial solution concentration of 350 - 500 mg/L and iron-carbon ratios of 1.5 - 5.
出处
《北京化工大学学报(自然科学版)》
EI
CAS
CSCD
北大核心
2007年第1期89-91,共3页
Journal of Beijing University of Chemical Technology(Natural Science Edition)
关键词
零价铁
邻氯苯酚
气相色谱
动力学模型
zerovalent iron
o-chlorophenol
gas chromatograph
kinetics
作者简介
男,1982年生,硕士生
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