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溶胶-凝胶法制备RDX/SiO_2纳米复合含能材料 被引量:18

Preparation of RDX/SiO_2 Nanocomposite Energetic Materials by Sol-Gel Method
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摘要 利用溶胶-凝胶法制备RDX纳米复合含能材料的干凝胶及气凝胶。采用透射电镜(TEM)和X射线衍射(XRD)对其形貌和晶体结构进行表征,测试了其热分解性能和撞击感度。结果表明,RDX含量为45%的RDX/SiO2纳米复合含能材料气凝胶的DSC分解峰温提前了15.4℃。SiO2凝胶基体可以降低RDX的撞击感度,并且随SiO2基体含量的增大降低幅度增大。 The xerogel and aerogel RDX/SiO2 nanocomposite energetic materials were prepared using sol-gel method. TEM and XRD were used to analyze the surface topography and the crystal structure. The thermal decomposition and the impact sensitivity for RDX/SiO2 nanocomposites were also tested. The results show that compared with pure RDX ,the DSC decomposition peak temperature of the aerogel RDX/SiO2 containing 45% RDX decreases by 15.4 ℃. The xerogel framework can effectively desensitize RDX, and the impact sensitivity descreases greatly with the increase of the SiO2 framework content.
出处 《含能材料》 EI CAS CSCD 2007年第1期16-18,22,共4页 Chinese Journal of Energetic Materials
基金 中国工程物理研究院重大基金资助(批准号:2004Z0503)
关键词 物理化学 溶胶-凝胶法 RDX/SiO2 热分解 撞击感度 physical chemistry sol-gel RDX/SiO2 thermal decomposition impact sensitivity
作者简介 池钰(1981-).女。硕士研究生,从事含能材料研究。
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参考文献7

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