摘要
采用水热合成方法,得到了双核Cd(II)配合物:Cd2(C7H4O2Cl)4(H2O)(phen)2.对该化合物的单晶进行X-射线衍射分析,确定了分子结构,在晶体堆积中,配合物分子以氢键形式形成1D无限结构;同时对该化合物的UV-VIS-NIR,IR和荧光光谱进行了测定和分析指认.
A dinuclear complex, Cd2(C7H4O2Cl)4(H2O) (phen)2, has been hydrothermally synthesized . The structure of the complex was determined by single crystal X-ray diffraction. In the crystal, the dinuclear unit is linked into a 1D hydrogen-bonded chain. In addition, the UV-VIS-NIR, IR and fluorescence spectra of the complex were measured and analyzed.
出处
《辽宁师范大学学报(自然科学版)》
CAS
北大核心
2006年第4期449-452,共4页
Journal of Liaoning Normal University:Natural Science Edition
基金
国家自然科学基金资助项目(90201018
20571037)
关键词
双核Cd(Ⅱ)配合物
晶体结构
光谱
氢键
dinuclear Cd ( Ⅱ ) complex
crystal structure
spectra
hydrogen bond
作者简介
牛淑云(1942-).女.吉林长春人.辽宁师范大学教授,博士生导师.