期刊文献+

聚合物类型对油水界面性质影响研究 被引量:9

Research on effects of polymer types on oil/water interfacial property
在线阅读 下载PDF
导出
摘要 采用界面张力仪和表面粘弹性仪研究了部分水解聚丙烯酰胺(HPAM)和疏水缔合聚合物(HAP)对油水界面性质的影响。研究结果表明,疏水缔合聚合物HAP可以显著降低煤油/模拟水体系界面张力,但对模拟油/模拟水体系界面张力影响较小;部分水解聚丙烯酰胺类聚合物CA对煤油/模拟水和模拟油/模拟水体系界面张力无明显影响。无论是煤油/模拟水体系还是模拟油/模拟水体系,随聚合物溶液浓度的增加,部分水解聚丙烯酰胺类聚合物CA均使体系界面剪切粘度逐渐增大。而疏水缔合聚合物HAP均使体系的界面剪切粘度先增加,后降低,而后再增加。部分水解聚丙烯酰胺(HPAM)相对分子质量较大时,HPAM溶液/模拟油体系的界面剪切粘度较大。 Interfacial properties of the polymer including partially hydrolyzed polyacrylamide(HPAM) and hydrophobically associating polymer(HAP) solution/model oil are studied respectively by dataphysics interfacial tension meter and SVR-S interfacial viscoelastic meter.Results show that,HAP can decrease interfacial tension of kerosene/formation water obviously,but impact little on that of model oil/formation water.The effects of polymer CA on interfacial tension of kerosene/formation water and model oil/ formation water are neither obvious.Polymer CA can increase interfacial shear viscosity of both kerosene/formation water and model oil/formation water as concentration of which was increased.When concentration of HAP is increased,interfacial shear viscosity of systems experiences a process of increasing at first,then decreasing,and then increasing.Interfacial shear viscosity of HPAM solution/model oil is higher when relative molecular weight of HPAM is bigger.
出处 《大庆石油地质与开发》 CAS CSCD 北大核心 2006年第6期87-90,共4页 Petroleum Geology & Oilfield Development in Daqing
基金 国家重点基础研究发展计划资助项目(课题编号:2005CB221305)
关键词 部分水解聚丙烯酰胺 疏水缔合聚合物 界面张力 界面剪切粘度 HPAM hydrophobically associating polymer interfacial tension interfacial shear viscosity
作者简介 周立娟(1975-),女,辽宁葫芦岛人,在读硕士,从事三次采油研究工作。
  • 相关文献

参考文献10

  • 1葛广章,王勇进,王彦玲,辛寅昌,姜庆利.聚合物驱及相关化学驱进展[J].油田化学,2001,18(3):282-284. 被引量:64
  • 2Kulike W M,Kniewske R.Langfristige konfonnationsanderung von makromolekülen in iosung[ J ].Makromol.Chem.,1980,181:823-838.
  • 3Libeyre R,Sarazin D,Francois J.Automatized photogoniodiffusometer and coupling with automatized viscosimeter[ J ].Polym.Bull.,1981,4:53-60.
  • 4Ryles R G.Chemical stability limits of water-solube polymers used in oil recovery processes[ J ].SPE Reservoi Engineering,1988,3(1):23-34.
  • 5Muller G,Fenyo J C,Selegny E J.High molecular weight hydrolyzed polyacrylamide.Ⅲ.Effect of temperature on chemical stability[ J ].Appl.Polym.Sci.,1980,25 (4):627-633.
  • 6Evani S,Rose G D.Water-solube hydrophobe association polymers[ J].Polym.Mater.Sci.Eng.,1987,57:477 -481.
  • 7Peiffer D G.Hydrophobically associating polymers and their interactions with rod -like micelles[J].Polymer,1990,31:2352-2359.
  • 8Alain D,Dominique H.Synthesis and thermo-associative property in aqueous solution of graft copolymers containing poly (N-isopropylacrylamide) side chains[J].Polymer,1999,40:4941-4951.
  • 9姜桂元,任鲲,徐春明,林梅钦,罗维迁.疏水缔合聚合物的合成及溶液性能研究[J].石油大学学报(自然科学版),2003,27(6):80-82. 被引量:15
  • 10Miller R,Wüstneck R,Kragel J.Dilational and shear rheology of adsorption layers at liquid interfaces[ R ].Colloids and Surfaces A:physicochemical and engineering aspects,1996,111:75-118.

二级参考文献4

共引文献77

同被引文献194

引证文献9

二级引证文献98

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部