摘要
５，１２－二苯基－７，１４─二甲基－１，４，８，１１－四氮杂环十四烷－Ｎ－乙酸及其Ｃｕ（Ⅱ）、Ｎｉ（Ⅱ）配合物的合成与表征张悠金，贺群，谢复新，许志强，倪诗圣（合肥经济技术学院加工工艺系合肥２３００５２）（安徽大学化学系合肥）关键词四氮杂环十四烷－Ｎ...
A novel 14 membered N-acetic acid substituted tetraazamacrocyclic ligand, 5,12-diphenyl-7,14-dimethyl-l,4,8,11-tetraazacyclotetradecane-N-acetic acid (HL ) has been synthesized in dry methanol by the interaction of 5, 12-diphenyl-7, 14-dimethyl-1,4,8,11-tetraazacyclotetradecane with bromoacetic acid. Its Cu (Ⅱ) and Ni(Ⅱ) complexes have also been prepared. The ligand and the complexes have been characterized by elemental analysis . IR,￣1H NMR,MS,UV-Vis spectra and conductivity measurements.
出处
《应用化学》
CSCD
北大核心
1996年第4期104-106,共3页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金
关键词
配合物
四氮杂大环
铜
镍
HL
tetraazacyclotetradecane-N-acetic acid
complex
synthesis
characterization
