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用红外光谱法测定硼酸三甲酯对金属氧化物的路易斯碱性的研究 被引量:3

Study on the Determination of Boric Acid Trimethvl Ester to Lewis Base Properties of Metal Oxides by Using Infrared Spectrum
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摘要 对金属氧化物的路易斯碱性进行红外光谱研究,采用硼酸三甲酯作为探针分子表征MgO、CaO、ZrO2、TiO2、SnO2和Sb2O5的表面路易斯碱中心及其碱的强度。 The lewis base properties of metal oxides have been investigated by using infrared spectra,surface lewis base sites and their basic strength of MgO,CaO,ZrO2,TiO2,SnO2 and Sb2O5 have been characterized by using boric acid trimethyl ester as a probe molecule.
作者 付仕福
出处 《衡阳医学院学报》 1996年第1期1-3,共3页
基金 国家自然科学基金
关键词 金属氧化物 路易斯碱性 红外光谱 硼酸三甲酯 metal oxides lewis base property infrared spectrum
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  • 1傅仕福,廖力夫,吕昌银,汪敏,李灿,辛勤,张慧.以硼酸三甲酯为探针分子红外光谱法测定Al_2O_3、SiO_2的路易斯碱性的研究[J].南华大学学报(自然科学版),2004,18(3):56-58. 被引量:2
  • 2Li Can,Fu Shi fu.Xin Qin,et al.An Infrared Spectroscopic Study on the Lewis Base Properties of Metal Oxides by using a Novel Probe Molecule:Boric Acid Trimethyl Ester[J].J.CHEM.SOC.,CHEM.COMMUN.1994,18:47~48.
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  • 7Choudhary V R, Rane V H. Acidity/Basicity of Rare-Earth Oxides and Their Catalytic Activity in Oxidative Coupling of Methane toC2-Hydrocaubons[J]. J. Catal. , 1991,130 : 411.
  • 8Barthomeuf D. Conjugate Acid-Base Pairs in Zeolites[J]. J. Phys. Chem. , 1984,88 : 42.
  • 9Li C,Fu S F,Xin Q,Zhang H. An Infrared Spectroscopic Study on the Lewis Base Properties of Metal Oxides by Using a NovelProbe Molecule : Boric Acid Trimethyl Ester[J]. J. Chem. Soc. Chem. Commun. , 1994,2 : 17-18.
  • 10Li Can,Fu Shi-fu.Xin Qin,et al.An Infrared Spectroscopic Study on the Lewis Base Properties of Metal Oxides by using a Novel Probe Molecule:Boric Acid Trimethyl Ester [J].J.CHEM.SOC.,CHEM.COMMUN,1994(18):47~48.

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