摘要
以三氨基胍盐酸盐和2,4-戊二酮为原材料,通过成环反应,氧化脱氢,肼基取代,三步合成了3,6-二肼基-1,2,4,5-四嗪,同时,对3,6-二肼基-1,2,4,5-四嗪的含能盐的合成进行了研究。对文献报道的反应路线进行了适当的放大研究。通过红外光谱分析、元素分析、质谱分析和1HNMR等方法对产物的结构特征进行了鉴定。
3,6-Dihydrazine-1,2,4,5-tetrazine and its energetic salts were synthesized from the easily available starting materials like triaminoguanidine and 2,4-penatanedione. The synthesis route in literature was magnified properly. Moreover, the synthesized compoundswere characterized by spectra analysis（IR, NMR, EA and MS） and the explosive properties （impact and friction sensitivity） and thermal properties （TGA/DTG） were studied.
出处
《含能材料》
EI
CAS
CSCD
2006年第2期116-117,122,共3页
Chinese Journal of Energetic Materials
关键词
有机化学
3
6-二肼基-1
2
4
5-四嗪
合成
四嚷
高氮化合物
organic chemistry
3,6-dihydrazine-1,2,4,S-tetrazine
synthesis
tetrazine
high-nitrogen energetic material
作者简介
潘劼（1977-）,男,工程师，主要从事有机合成研究。e—mail；panjiepjg@163．com
