摘要
The surface oxidation behavior of pressureless sintered Al2O3/SiC nanocomposite was studied from 1000 to 1400 ℃ for more than 10 h in air. Weight gain during the process of heat treatment was measured by TG analysis. Phase transformation and microstructure changes of these specimens due to oxidation were investigated with X-ray diffraction （XRD）, SEM and EDX technology. Thermogravimetric analysis show that the weight gain as a result of oxidation of SiC become significant above 1200 ℃. In the range of 1000 - 1300 ℃, the SiC grits are usually coated with a layer of amorphous silica after oxidation. Above 1300 ℃, the amorphous silica reacted with alumina matrix and formed mullite or crystallized into cristobalite. The rate of oxidation depends on the formation of dense cristobalite film. Large amount of needle-like mullite and alumina crystals are formed on the surface after oxidation at 1400℃.
The surface oxidation behavior of pressureless sintered Al2O3/SiC nanocomposite was studied from 1000 to 1400 ℃ for more than 10 h in air. Weight gain during the process of heat treatment was measured by TG analysis. Phase transformation and microstructure changes of these specimens due to oxidation were investigated with X-ray diffraction （XRD）, SEM and EDX technology. Thermogravimetric analysis show that the weight gain as a result of oxidation of SiC become significant above 1200 ℃. In the range of 1000 - 1300 ℃, the SiC grits are usually coated with a layer of amorphous silica after oxidation. Above 1300 ℃, the amorphous silica reacted with alumina matrix and formed mullite or crystallized into cristobalite. The rate of oxidation depends on the formation of dense cristobalite film. Large amount of needle-like mullite and alumina crystals are formed on the surface after oxidation at 1400℃.
基金
Project supported bythe Ministry of Science and Technology via‘863’High Technology Projects (2002AA332080)
作者简介
Cai Shu （1965-）, Female, Doctor, Professor. Corresponding author （E-mail： caishu@tju.edu.cn）
