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扩散层形态对质子交换膜燃料电池性能的影响 被引量:8

Influence of gas diffusion layer morphology on the performance of proton exchange membrane fuel cell
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摘要 研究了扩散层中过渡层所用碳粉的性质和担载量对质子交换膜燃料电池(PEMFC)性能的影响。采用扫描电镜对以AcetyleneBlack、VulcanXC-72、KetjenBlackEC300J和BlackPearls2000四种碳粉制备的扩散层表面形态进行了表征,并分别在1.40mg/cm2和1.00mg/cm2碳粉担量下比较了由这四种碳粉制备的扩散层的电极性能。在以AcetyleneBlack为过渡层碳粉材料时优化了碳粉的担量。实验结果表明随过渡层中所用碳粉比表面积的降低电极性能增加;过渡层中碳粉担量存在一个最佳值;担量为1.00mg/cm2的AcetyleneBlack制备扩散层的电极性能最好,最高比功率可达0.75W/cm2。 Influence of the inter-media layer on the performance of proton exchange membrane fuel cell was studied. Morphologies of gas diffusion layers fabricated by Acetylene Black, Vulcan XC-72, KetjenBlack EC 300 J and Black Pearls 2000 carbons were investigated by scanning electron microscopy. The performances of electrodes with different carbon powders were compared at the loadings of 1.4 mg/cm^2 and 1.0 mg/cm^2 respectively. It has been found that the electrode performance increases with the decreasing surface area of carbon powders. And there is an optimum carbon loading in the gas diffusion layer. The electrode with 1.0 mg/cm^2 Acetylene Black shows the best performance of 0.75 W/cm^2.
出处 《电源技术》 CAS CSCD 北大核心 2005年第9期570-573,共4页 Chinese Journal of Power Sources
基金 国家自然科学基金资助项目(No.20206030) 国家自然科学基金重点资助项目(No.50236010)
关键词 质子交换膜燃料电池 扩散层 过渡层 碳粉 proton exchange membrane fuel cell gas diffusion layer inter-media layer carbon powder
作者简介 王晓丽(1978-),女,辽宁省人,博士生,主要研究方向为质子交换膜燃料电池。 联系人:张华民
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  • 1于景荣,衣宝廉,韩明,邵志刚,程晓亮.高功率密度质子交换膜燃料电池研究[J].电源技术,2000,24(3):131-134. 被引量:21
  • 2QI Z G, KAUFMAN A. Improvement of water management by a microporous sublayer for PEM fuel cells [J]. J Power Sources, 2002,109: 38-46.
  • 3PARK G G. SOHN Y J, YANG T H, et al. Effect of PTFE contents in the gas diffusion media on the performance of PEMFC [J]. J Power Sources, 2004,131: 182-187.
  • 4PAGANIN V A, TICIANELLI E A, GONZALEZ E R. Development and Electrochemical studies of gas diffusion electrodes for polymer electrolyte fuel cells[J]. J Appl Electrochem, 1996, 26: 297-304.
  • 5ANTOLINI E, PASSOS R R, TICIANELLI E A. Effects of the cathode gas diffusion layer characteristics on the performance of polymer electrolyte fuel cells[J]. J Appl Electrochem, 2002, 32: 383-388.
  • 6GIORGI L. ANTOLINI E, POZIO A, et al. Influence of the PTFE content in the diffusion layer of low-Pt loading electrodes for polymer electrolyte fuel cells[J]. Electrochim Acta, 1998, 43(24):3 675-3 680.
  • 7MOREIRA J. OCAMPO A L. Influence of the hydrophobic material content in the gas diffusion electrodes on the performance of a PEM fuel cell [J]. International Journal of Hydrogen Energy, 2003, 28:625-627.
  • 8JORDAN L R, SHUKLA A K, BEHRSING T, et al. Diffusion layer parameters influencing optimal fuel cell performance [J]. J Power Sources. 2000, 86: 250-254.
  • 9JORDAN L R, SHUKLA A K, BEHRSING T, et al. Effect of the diffusion-layer morphology, on the performance of polymer electrolyte fuel cells at atmospheric pressure[J]. J Appl Electrochem,2000, 30: 641-646.
  • 10PASSALACQUA E, SQUADRITO G, LUFRANO F, et al. Effects of the diffusion layer characteristics on the performance of polymer electrolte fuel cell electrodes [J]. J Appl Electrochem,2001, 31: 449--454.

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