摘要
在Ｈ＿６ＴｅＯ＿６／ＫＯＨ水溶液中以臭氧为氧化剂，将二价铜化合物氧化成三价铜化合物，并获得一个新的三价铜化合物Ｂａ＿４Ｋ［Ｃｕ（Ｈ＿２ＴｅＯ＿６）＿２］（ＯＨ）＿４·６Ｈ＿２Ｏ；描述了碱性溶液中“Ｃｕ（Ⅲ）／Ｃｕ（Ⅱ）”循环伏安图。对铜（Ⅲ）化合物，Ｎａ＿４Ｈ［Ｃｕ（Ｈ＿２ＴｅＯ＿６）＿２］·１７Ｈ＿２Ｏ以及相应的铜（Ⅱ）配合物的电子光谱和Ｃｕ２ｐＸＰＳ进行了研究，给出了其配位场场强参数和Ｃｕ２ｐＸＰＳ的电子结合能。由于价态升高，光电子空穴寿命缩短，Ｃｕ２ｐＸＰＳ的谱峰增宽。
Detailed investigation on the preparation and properties of telluratocuprate(Ⅱ,Ⅲ)complexes has been performed.In the solution of H6TeO6/KOH,Cu(Ⅲ)complex wasobtained by adopting ozone as oxidant and a new copper(Ⅲ)compound Ba4K[Cu(H2TeO6)2](OH)4· 6H2O was isolated.The cyclic voltammogram of “Cu(Ⅲ)/Cu(Ⅱ)”couple in alka-line solution was described. According to the electronic spectra and Cu2p XPS of the new Cu(Ⅲ)compound, Na4H[Cu(H2TeO6)2]·17H2O and related Cu(Ⅱ) complexes, the ligandfield parameters and the binding energies of Cu2p3/2 for these Cu(Ⅲ)and Cu(Ⅱ)complexeswere determined.
出处
《应用化学》
CAS
CSCD
北大核心
1995年第5期33-36,共4页
Chinese Journal of Applied Chemistry
基金
国家自然科学基金资助课题
关键词
高碲酸合铜
配合物
光电子能谱
合成
telluratocuprate(Ⅱ,Ⅲ)complex,ozone oxidation,voltammogram,electronicspectrum,XPS
