摘要
以４－溴－１，８－萘酐为原料，经亚胺化、乌尔曼缩合、Ｐｓｃｈｏｒｒ闭环等反应，合成了Ｎ－羟乙基－苯并硫杂蒽３，４－二甲酰亚胺（１）和７Ｈ－苯并咪唑［２，１－ａ］苯并硫杂蒽－７－酮及异构体（Ⅱ和Ⅱ＇），测定了它们的吸收光谱和荧光发射光谱以及光化学稳定性。塑料ＡＢＳ经它们着色后，荧光效果非常明显。
N-hydroxyethyl-Benzo[K. 1] thioxanthene-3, 4-dicarboximide(Ⅰ) and 7H-benzimidazo[2,1-a ]benz [d, e] isoquinolin-7-one(Ⅱ) together with its isomer(Ⅱ’) were synthesized through imidation, Ullmann condensation and Pschorr ring close reaction with 4-bromo-1, 8-naphthailc anhydride as starting material. Their absorption spectra and fluorescence emission spectra were measured and photo-stability was tested. They can colour plastics as fluorescent dyes.
出处
《染料工业》
1995年第2期8-10,共3页
Dyestuff Industry
