摘要
合成了O 乙基二硫代碳酸铋配合物。通过元素分析、红外光谱和X 射线单晶衍射对其结构进行了表征。测试结果表明 :该配合物为三斜晶系 ,空间群P墿,a =1 0 5 5 1(3)nm ,b =1 933(3)nm ,c=1 4 15 3(3)nm ,α =92 0 77(3)°,β =90 4 5 1(4 )°,γ =10 0 5 37(3)° ,Z =4 ,V =1 75 0 5 (7)nm3 ,Dc =2 173g/cm3 ,μ(MoKα) =10 786mm-1,F(0 0 0 ) =10 88,R1=0 0 5 0 0 ,wR2 =0 0 718。在晶体中 ,配合物分子间通过Bi…O和Bi…S弱相互作用 。
The one-dimensional infinite chain complex (Bi(S_2COC_2H_5)_3) was synthesized by the reaction of Bi(NO_3)_3·5H_2O and NaS_2COC_2H_5.The complex was characterized by elemental analysis,IR and the crystal structure was determined by X-ray single crystal diffraction.The crystal belongs to triclinic with space group Pī,a=1.0551(3)nm,b=1.933(3)nm,c=1.4153(3)nm,α=92.077(3)°,β=90.451(4)°,γ=100.537(3)°,(Z=4,)V=1.7505(7)nm^3,Dc=2.173g/cm^3,(μ(MoKα)=)10.786mm^(-1),F(000)=1088,R_1=0.0500,wR_2=0.0718.The molecules were packed in the unit cell in one-dimensional chain structure through weak interaction of Bi…O and Bi…S.
出处
《化学试剂》
CAS
CSCD
北大核心
2004年第5期263-265,282,共4页
Chemical Reagents
基金
教育部骨干教师基金 ( 2 0 5 0 )
山东省自然科学基金资助项目 (L2 0 0 3B0 1)
