摘要
Compound B was synthesized through oxidative coupling reaction of p-phenylene-diamine and compound A(acetylamino-capped aniline dimer). This synthetic route protected the N-phenyl-1,4-phenylenediamine from further reaction. The pentamer was synthesized by the hydrolysis of compound B(acetylamino-capped aniline pentamer) and was characterized by IR, elemental analysis and MALDI-TOF-MS. The chemical oxidation process of the pentamer was studied by UV-Vis spectra. It was found the pentamer was oxidized to its EB form and then to the pernigraniline oxidation state.
Compound B was synthesized through oxidative coupling reaction of p-phenylene-diamine and compound A(acetylamino-capped aniline dimer). This synthetic route protected the N-phenyl-1,4-phenylenediamine from further reaction. The pentamer was synthesized by the hydrolysis of compound B(acetylamino-capped aniline pentamer) and was characterized by IR, elemental analysis and MALDI-TOF-MS. The chemical oxidation process of the pentamer was studied by UV-Vis spectra. It was found the pentamer was oxidized to its EB form and then to the pernigraniline oxidation state.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2004年第9期1768-1770,共3页
Chemical Journal of Chinese Universities
基金
国家"九七三"计划项目 (批准号 :0 0 1CB610 5 0 5 )
重大国际合作项目 (批准号 :2 0 3 2 0 12 0 169)资助
