摘要
三-（2-甲基氮丙啶）氧化膦（MAPO）为黄色油状液体,其化学性质活泼,可用作塑料、橡胶及造纸业中高分子化合物的交联剂等。本文对MAPO进行了<sup>1</sup>H、<sup>13</sup>C、<sup>15</sup>N、<sup>31</sup>P和<sup>17</sup>O的核磁共振研究及量子化学计算。结果表明,该化合物存在4种异构体,其中2种为对映体,并得到了这4种异构体的几何构型。
1H, 13C, 15N, 31P and 17O NMR spectra of tri(2-methyl-1-aziridinyl) phosphine oxide were studied and simulated. The quantum chemical calculations on this compound were also carried out by AMI program. The optimized results show that there exist four kinds of isomers for the compound, two of them are enantiomer, and their geometrical configurations were obtained.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
1993年第12期1740-1742,共3页
Chemical Journal of Chinese Universities
关键词
异构体
NMR
MAPO
Tri(2-methyl-1-aziridinyl) phosphine oxide, Isomers, NMR
