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Ti-MCM-41介孔分子筛催化氧化噻吩性能 被引量:2

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摘要 水热合成了Ti-MCM-41介孔分子筛催化剂,并采用XRD、FT-IR进行了表征。进一步考察了反应时间、反应温度和催化剂用量对Ti-MCM 41催化模型油中噻吩氧化反应催化性能的影响。结果表明:所制备Ti-MCM-41介孔分子筛晶型良好且掺杂钛很好地进入了分子筛骨架中,其对H_2O_2氧化噻吩的反应具有良好的催化性能,当反应温度为60℃,催化剂用量为0.2 g,反应3 h之后效果最佳,氧化脱除率可达93.17%。
出处 《化工进展》 EI CAS CSCD 北大核心 2011年第S1期534-536,共3页 Chemical Industry and Engineering Progress
基金 国家自然科学基金资助(21076110)项目
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参考文献10

  • 1豆茂峰,金胜明,付英,常燕,关豪元,杨敏.介孔分子筛Ti–MCM–41的制备和结构(英文)[J].硅酸盐学报,2008,36(1):65-68. 被引量:9
  • 2郭建维,王乐夫,刘卅.Ti-MCM-41分子筛催化剂的表面硅烷化改性研究[J].高校化学工程学报,2005,19(6):772-775. 被引量:7
  • 3许磊,王公慰,魏迎旭,齐越.MCM-41介孔分子筛合成研究Ⅰ.水热合成法[J].催化学报,1999,20(3):247-250. 被引量:28
  • 4Wagner A Carvalho,Paula B Varaldo,Martin Wallau,et al.Mesoporous redox molecular sieves analogous to MCM- 41. Zeolites . 1997
  • 5Wagner A Carvalho,Paula B Varaldo,Martin Wallau,et al.Mesoporous redox molecular sieves analogous to MCM- 41. Zeolites . 1997
  • 6Beck JS,Vartuli JC,Roth WJ,et al.A new family of mesoporous molecular sieves prepared with liquid crystal templates. Journal of the American Chemical Society . 1992
  • 7Peter T Tanev,Malama Chibwa,Thomas J Pinnvaia,et al.Tianium-containing mesoporous molecular sieves for catalytic oxidation of aromatic compounds. Nature . 1994
  • 8C T Kresge,M E Leonowicz,W J Roth,et al.Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism. Nature . 1992
  • 9Corma A,Navarro MT,Perez-Pariente J.Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbons. Journal of the Chemical Society Chemical Communications . 1994
  • 10Corma A.From microporous to mesoporous molecular sieve materials and their use in catalysis. Chemical Reviews . 1997

二级参考文献11

  • 1宋大佑 徐家宁 等.-[J].高等学校化学学报,1992,13(10):1209-1209.
  • 2Gianotti E, Frache A, Scolucia, Thomas J M, et al. The identy of titanium centers in microporous aluminophosphates compared with Ti-MCM-41 mesoporous catalyst and titanolsilsespuioxane dimer molecular complex:a spectroscopy study [J]. Journal of Molecular Catalysis A, 2003, 204-205: 483-489.
  • 3Luo Y, Luo G Z. Guo Y L, Wang Y S. Study on Ti-MCM-41 zeolites prepared with inorganic Ti sources: Synthesis, characterization and catalysis [J]. Catalytic Communications, 2002, (3): 129-134.
  • 4Matteo Guidotti,Nicolleta Ravasio, Rinaldo Psaro, Giovanni Ferraris, Epoxidation on titanium-containing silicates: do structural features really affect the catalytic performance? [J]. Journal of Catalysis. 2003, 214: 242-250.
  • 5Blasco T, Corma A, Navarro M T, Pariente J P. Synthesis, characterization, and catalytic activity of Ti-MCM-41 structures [J]. Journal of Catalysis. 1995, 156: 65-74.
  • 6Corma A, Navarro M T, Pariente J P. Synthesis of an ultralarge pore titanium silicate isomorphous to MCM-41 and its application as a catalyst for selective oxidation of hydrocarbons [J]. J Chem Soc Chem Commun, 1994, (2): 147-148.
  • 7许磊,王公慰,魏迎旭,齐越,刘宪春,包信和.MCM-41介孔分子筛合成研究Ⅱ.微波辐射合成法[J].催化学报,1999,20(3):251-255. 被引量:37
  • 8郭建维,王乐夫.静电S^+X^—I^+组装途径合成中孔杂原子分子筛[J].催化学报,2000,21(5):393-394. 被引量:2
  • 9张文华,施剑林,陈航榕,闫继娜,华子乐,严东生.Ti(IV)在介孔氧化硅MCM-41中的液相移植[J].无机材料学报,2001,16(1):87-92. 被引量:22
  • 10罗勇,卢冠忠,黄家桢,郭杨龙,王筠松.用无机钛源合成Ti—MCM—41的研究[J].化学学报,2001,59(9):1401-1405. 被引量:7

共引文献41

同被引文献23

  • 1陈彤,祝良芳,胡常伟.Zr-Ni/Al_2O_3催化剂上苯由H_2O_2氧化直接氨基化制苯胺[J].分子催化,2005,19(4):275-279. 被引量:6
  • 2杨春华,秦玉华,刘扬,关晓辉.固体超强酸S_2O_8^(2-)/Fe_2O_3-TiO_2-Nd_2O_3催化合成乙酸薄荷酯的研究[J].东北电力大学学报,2007,27(2):40-42. 被引量:10
  • 3Kresge C T, Leonowice M E, Roth W J, et al. Ordered mesoporous molecular sieves synthesized by a liquid-crystal template mechanism[J].Nature, 1992, 359 (6397): 710-712.
  • 4Beck J S, Vartuli J C, Roth W J, et al. Anew family ofmesoporous molecular sieves prepared with liquid crystal templates[J]. Journal of the American Chemical Society, 1992, 114 (27): 10834-10843.
  • 5Horcajada P, Ramila A, Perez-pariente J, et al. Influence of pore size of MCM-41 matrices on drug delivery rate[J]. Microporous and MesoporousMaterials, 2004, 68 (1): 105-109.
  • 6Anglin E J, Chang L, Freeman W R, et al. Porous silicon in drug delivery devices and materials[J]. Advanced Drug Delivery Reviews, 2008, 60 (11): 1266-1277.
  • 7Zhang K, Chert I4 L, Albela B, et al. High-temperature synthesis and formation mechanism of stable, ordered MCM-41 silicas by using surfactant eetyltrimethylarnmonium tosylate as template[J]. European Journal of Inorganic Chemistry, 2011, 2011 ( 1 ): 59-67.
  • 8Gupta A K, Gupta M. Synthesis and surface engineering of iron oxide nanoparticles for biomedical applications[J]. Biomaterials, 2005, 26 (18): 3995-4021.
  • 9Hidalgo J M, Jurado M J, Carnpelo J M, et al. Preparation of mesoporous organically modified titanium materials and their activity in the oxidation of cyclohexene[J]. Catalysis Letters, 2008, 126 (1-2): 179-187.
  • 10George J, Shylesh S, Singh A P. Vanadium-containing ordered mesoporous silicas: Synthesis, characterization and catalytic activity in the hydroxylation of biphenyl[J]. Applied Catalysis A: General, 2005, 290 (1): 148-158.

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