摘要
Using 12-tungstosilicic acid (SiW 12 4? ) as the catalyst, rhodamine B (RhB) dye in an aerated aqueous solution can undergo an effective photocatalytic stepwise N-deethylation process under visible light irradiation, and dioxygen is reduced to hydrogen peroxide by the reduced (SiW 12 4? ). This provides the potential for moving polyoxometalate-based photocatalytic processes from the near-UV into the visible region of the spectrum.
Using 12-tungstosilicic acid as the catalyst, rhodamine B(RhB) dye in an aerated aqueous solution can undergo an effective photocatalytic stepwise N-deethylation process under visible light irradiation, and dioxygen is reduced to hydrogen peroxide by the reduced . This provides the potential for moving polyoxometalate-based photocatalytic processes from the near-UV into the visible region of the spectrum.
基金
This work was supported by the National Natural Science Foundation of China(Grant Nos.20133010,20077027,4001161947,070301)
the Chinese Academy of Sciences,and the Ministry of Science and Technology of China.
作者简介
ZHAO Jincai(赵进才), Correspondence should be addressed to Zhao Jincai (email: jczhao@iccas.ac.cn)
