期刊文献+

氧气沿面放电臭氧合成机理 被引量:3

Ozone Synthesis in Oxygen in Surface Discharge
在线阅读 下载PDF
导出
摘要 提出了一种氧气沿面放电过程中臭氧合成的“双区模型”,即氧分子离解区和与之分离的臭氧形成区. 臭氧的产生率由离解区氧原子的产生效率和形成区氧原子转化为臭氧的效率决定.沿面放电中臭氧的产生率低 电场时随电场升高而增大,高电场时随电场增大而减小.在氧气的击穿电场附近和低温条件下可以获得较高的臭 氧合成效率. A two-region-reactor model is presented to investigate the ozone synthesis in the surface discharge in oxygen, in which the production of oxygen atom and ozone is assumed to take place in two separated regions, i.e. the dissociation and the formation regions. The calculation results show that the ozone generation is determined by the generation of the oxygen atom which is only related to the discharge process in dissociation region, and by the transformation ratio of oxygen atoms into ozone molecules which is determined by the three body reactions in the formation region. The ozone generation of the surface discharge type ozonizer increases as the reduced field increasing at lower field but decreases almost proportionally at higher field (or the applied voltage). A good efficiency of ozone formation can be obtained at moderate field and lower temperature during the surface discharge.
出处 《北京理工大学学报》 EI CAS CSCD 北大核心 2005年第z1期263-266,共4页 Transactions of Beijing Institute of Technology
关键词 臭氧 沿面放电 双区模型 ozone surface discharge two-region-reactor model
作者简介 欧阳吉庭(1966-),男,副教授,E-mail:jtouyang@bit.edu.cn.
  • 相关文献

参考文献8

  • 1[1]Kogelschatz U, Eliasson B, Egli W. Dielectric barrier discharges: Their history, discharge physics and industrial applications[J].Pure Chem Plasma Process,2003, 23: l -46.
  • 2[2]Eliasson B, Kogelschatz U. Ozone synthesis from oxygen in dielectric barrier discharges [J]. J Phys D: Appl Phys, 1987,20:1421 - 1437.
  • 3[3]Peyrous R, Pignolet P, Held B. Kinetic simulation of gaseous species created by an electric discharge in dry or humid oxygen [J]. J Phys D: Appl Phys, 1989, 22: 1658-1667.
  • 4[4]Sios-Nagy G, Dombi D. Gas phase reaction in silent electric discharge [J]. Ozone Sci Eng, 1996, 18: 141- 157.
  • 5[5]Ouyang J T, Feng C G, Hui H X. Kinetic and photochemical data for atmospheric chemistry [J]. J Phys D: Appl Phys,1998, 31: 1852-1856.
  • 6[6]Masuda S, Akusuke A, Kuroda M, et al. A ceramic-based ozonizer using high frequency discharge[J]. IEEE Trans-PS,1988, 24(2): 223-231.
  • 7[8]Baulch D L, Cox R A, Crutzen P J, et al. Kinetic and photochemical data for atmospheric chemistry [J]. J Phys Chem RefData, 1982, 11(2): 327-496.
  • 8[9]Eliasson B, Kogelschatz U. Basic data for modeling of electrical discharge in gases [R]. Asea Brown Boveri Coporate Research Report, KLR 86-11C, 1986.

同被引文献36

引证文献3

二级引证文献13

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部