摘要
Copper-zinc heterometallic 1D chain coordination polymer has been synthesized and characterized by elemental analysis, and IR spectra etc. The crystal structure was determined by single-crystal X-ray diffraction analyses. The title complex is 1D chain coordination polymer with the chemical formula {[CuLZn·CuLZn(H2O)]·H2O}n, where H4L=N-(2-hydroxybenzamido)-N’-(3-carboxy- lsalicylidene)ethylenediamine. Its structural unit is comprosed of two tetranuclear cycles formed by two dissymmetrical tetranuclear units. These units polymerized each other to form 1D chain coordi- nation polymer.
Copper-zinc heterometallic 1D chain coordination polymer has been synthesizedand characterized by elemental analysis, and IR spectra etc. The crystal structure was determinedby single-crystal X-ray diffraction analyses. The title complex is 1D chain coordination polymerwith the chemical formula {[CuLZn·CuLZn(H_2O)]·H_2O}_n, whereH_4L=N-(2-hydroxybenzamido)-N''-(3-carboxy-lsalicylidene)ethylenediamine. Its structural unit iscomprosed of two tetranuclear cycles formed by two dissymmetrical tetranuclear units. These unitspolymerized each other to form 1D chain coordination polymer.
