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双液系折光率-组成-温度间的关系模型及应用 被引量:4

The Correlation Model of Refractive index Component and Temperature in Two-component System and It's Application
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摘要 以环己烷-乙醇双液系的折光率测定为例,探讨建立双液系折光率-组成-温度关系模型,用以快速、准确测定双液系组成的方法。该方法是在不同温度下,测定不同溶液组成的折光率,利用最小二乘法拟合出折光率-温度,折光率-组成以及折光率-组成-温度间的关系模型,然后用拟合好的关系模型预测测试结果。实验结果表明,直接用拟合的关系模型确定双液系组成是有效而可行的。 Based on the modeling of refractive index,component and temperature in the cyclohexane-alcohol two- component system, a method was discussed for determining the component of two-component system rapidly and accurately. First of all, a series of refractive index of two-component system were determined in out-of-tempera- ture and out-of-component. The relation model of refractive index,temperature and component were fit by the least square method and used for forecasting the measurement and test results. The results show the method is feasible and effective for direct-determining the component of two-component system.
作者 粟智
出处 《仪器仪表学报》 EI CAS CSCD 北大核心 2003年第z2期34-35,41,共3页 Chinese Journal of Scientific Instrument
关键词 双液系 折光率 Two-component system Refractive index Model
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参考文献3

  • 1[1]A.Weissberger Ed.Techniques of Chemistry,Vol,I:Physical method chemistry,pt Ⅲ,A:Refraction,Scattering of Light and microscopy,John Willey & Sons.Inc,1972,207.
  • 2[2]孙尔康,徐维清,邱金恒编.物理化学实验.南京:南京大学出版社,2002:25~28
  • 3[6]John H.Mathews,Kurtis D.Fink.Ed.Numerical Methods Using MATLAB (Third Edition).Beijing:Publish House of Electronics Industry,2002,252.

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