期刊文献+

间苯三酚合成研究进展 被引量:3

Research progress of 1, 3, 5-benzenetriol
在线阅读 下载PDF
导出
摘要 间苯三酚是一种比较昂贵的重要中间体,工业合成具有一定的技术难度。阐述了国内外间苯三酚合成技术的研究进展,包括(异丙)苯法、三硝基甲苯法、氯代苯法、苯胺法等具有工业化价值的几种工艺路线的收率、工艺条件及工业化可行性。建议国内企业应该采用较为先进的(异丙)苯法或氯代苯法工艺提高产品质量。 There are some technical difficulties in the synthesis of 1, 3, 5-benzenetriol as a costly intermediate industrially.Research progress of several industrialized technological routes using cumene/benezene, 2, 4, 6-trinitrotoluene, chlorobenzene,aniline as a resource at home and abroad is reviewed, including the analysis of yield, process and industrialization feasibility. It issuggested that China's companies should use advanced cumene/benezene or chlorobenzene process to improve the product quality.
出处 《现代化工》 CAS CSCD 北大核心 2003年第z1期41-43,45,共4页 Modern Chemical Industry
关键词 间苯三酚 中间体 合成 应用 1,3,5-benzenetriol intermediate synthesis application
作者简介 汪宝和(1964-),男,硕士,副研究员,主要从事树脂催化剂、精细化工过程的开发与研究,022-27401299,bhwang@tju.edu.cn.
  • 相关文献

参考文献21

  • 1[1]Diane F B,Suzanne H. [J]. Pharmacology and Therapeutics,2001,90(2) :157 - 177.
  • 2[2]Flavin M T,Rizzo J D.[J] .J Med Chem,1996,39(6) :1303 - 1313.
  • 3[3]Hooker Electrochemical Company. Meta-substituted phenols and method for their synthesis[P]. GB 751598,1956 - 06 - 27.
  • 4[4]Sumitomo Chemical Company, Limited. Process for producing[ P]. US4469899,1984 - 09 - 04.
  • 5[5]Mitsui Petrochem Ind Ltd. Preparation of phloroglucin [ P]. JP 58-150529A,1983-09-07.
  • 6[6]Mitsui Petrochem Ind Ltd. Separation method of phloroglucin [ P]. JP 58 - 150530A, 1983 - 09 - 07.
  • 7[7]Mitsui Petrochem Ind Ltd. Separation of phloroglucin [ P ]. JP58 - 157736A, 1983 - 09 - 19.
  • 8[8]Mitsui Petrochem Ind Ltd. Separation of phloroglucin [ P ]. JP 58- 157737A, 1983- 09- 19.
  • 9[9]Battaafsche Petroleum. Preparation of isopropyl-benzenes [ P ]. GB 809909,1959 - 03 - 04.
  • 10[10]Allied Chem. Preparation of alkylated aromatic compounds[P]. GB 1014750,1966 - 08 - 23.

同被引文献40

  • 1李珊山,张朝英,李洪霞.痤疮系统性治疗的现状与展望[J].吉林大学学报(医学版),2005,31(5):814-815. 被引量:10
  • 2宋志光,李静,刘庆文,李叶芝,黄化民.(+)-菊花烯酮的Baeyer-Villiger反应[J].高等学校化学学报,2005,26(12):2264-2266. 被引量:2
  • 3朱峰,乔建军.聚酮合成酶底物专一性的研究进展[J].中国抗生素杂志,2006,31(11):641-645. 被引量:5
  • 4谢广群,曹端林,王建龙.均苯三酚的研究进展[J].中北大学学报(自然科学版),2007,28(1):64-68. 被引量:3
  • 5LIU L X,CHEN J.Solubility of hesperetin in arious solvents from (288.2 to 323.2)K[J].J Chem Eng Data,2008,53:1649-1650.
  • 6WINGARD R E.Conversion of hesperidin into hesperetin:US,4150038[P].1979.
  • 7NEWHALL W F,TING S V.Degradation oh hesperetin and naringenin to phloroglucinol[J].J Agr Food Chem,1967,15(5):776-777.
  • 8JEONG T S,KIM E E,LEE C H,et al.Hypocholesterolemic activity of hesperetin derivatives[J].Bioorganic﹠Medicinal Chemistry Letter,2003,13(16):2663-2665.
  • 9LU J,BENJAMIN M M,KORSHIN G V,et al.Reactions of the flavonoid hesperetin with chlorine:a spectroscopic study of the reaction pathways[J].Environ Sci Technol,2004,38(17):4603-4611.
  • 10BERNINI R,MINCIONE E,CORTESE M,et al.Conversion of naringenin and hesperetin by heterogeneous catalytic Baeyer-Villiger reaction into lactones exhibiting apoptotic activity[J].Tetrahedron Letters,2003,44:4823-4825.

引证文献3

二级引证文献16

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部