期刊文献+

碳纳米管/聚偏氟乙烯复合材料的制备及其介电性能 被引量:3

Preparation and Dielectric Property of Carbon Nanotube/Polymer Composite
在线阅读 下载PDF
导出
摘要 作者研究了未经处理的多壁碳纳米管/聚偏氟乙烯(MWNT/PVDF)复合材料体系的介电性能发现,在低频下,复合材料的介电常数随MWNT的含量增加而迅速增加,当体积分数为2.0%时,介电常数高达300左右,并且复合材料的渗流阈值仅为1.61%.MWNT较大的长径比和较高的电导率导致复合体系渗流阈值较低.发生渗流效应时,复合材料的介电损耗低于0.4,与频率无关.因此,可以认为未经过化学处理的碳纳米管可以大幅度地改善PVDF基复合材料的介电性能. Dielectric properties of the untreated multi-wall carbon-nanotubes/poly(vinylidene fluoride) (MWNT/PVDF) composites are studied. Towardslow frequencies, the dielectric constant of a composite with about 2.0% of MWNT increases rapidly and the value of the dielectric constant is as high as 300. However, by a calculation, the percolation threshold of the MWNT/PVDF composites is only 1.61% (0.0161 volume fraction) of MWNT. Both the large aspect ratio and the high conductivity of the MWNT may lead to the low per...
作者 王岚 党智敏
出处 《四川大学学报(自然科学版)》 CAS CSCD 北大核心 2005年第S1期242-246,共5页 Journal of Sichuan University(Natural Science Edition)
关键词 碳纳米管 制备 介电性能 复合材料 carbon nanotube preparation dielectric property composite
  • 相关文献

参考文献19

二级参考文献166

共引文献384

同被引文献21

  • 1徐任信,陈文,王钧,周静,杨小利.聚苯胺改性PVDF薄膜的结构与介电性能研究[J].塑料科技,2006,34(2):18-21. 被引量:7
  • 2Iijima S. Helical Microtubes of Graphitic Carbon [J]. Nature, 1991,345 : 56-58.
  • 3Ebbesen T W, Ajayan P M. Large-scale Synthesis of Carbon Nanotubes [J].Nature, 1992, 358:220-222.
  • 4Ajayan P M, Ichihasi T, Iijima S, et al. Distribution of Pentagons and Shapes in Carbon Nanotubes and Nanoparticles [J]. Chemical Physics Letters, 1993, 202:384-388.
  • 5Li W Z, Xie S S, Qian L X, et al. Large-scale Synthesis of Alignel Carbon Nanotubes[J]. Science, 1996,274:1701- 1703.
  • 6Yao Zhen, Postma Henk W C, Bblents L. Carbon Nanotube Intramolecular Junctions [J]. Nature, 1999, 402:273-276.
  • 7Ingan S O, Lundstr M I. Materials Science Carbon Nanotube Muscles [J]. Science, 1999, 284: 1281-1282.
  • 8Qian Dong, Wagner G J, Liu W K. Mechanics of Carbon Nanotubes [J]. Appl Mech Rev, 2002, 55: 495-532.
  • 9Tang B Z, Xu H. Preparation, Alignment, and Optical Properties of Soluble Poly(phenylacetylene)--wrapped Carbon Nanotubes[J]. Macromolecules, 1999, 32(8):2569-2576.
  • 10Zhang $ H, Zhang N Y, Huang C, et al. Microstructure and Electromechanical Properties of Carbon Nanotube/ Poly (vinylidene fluoride trifluoroethylene chlorofluoroethylene) Composites[J]. Advanced Materials, 2005, 17 (15) : 1897-1901.

引证文献3

二级引证文献7

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部