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Synthesis of unique-morphological hollow microspheres of MoS2@montmorillonite nanosheets for the enhancement of photocatalytic activity and cycle stability 被引量:8

Synthesis of unique-morphological hollow microspheres of MoS2@montmorillonite nanosheets for the enhancement of photocatalytic activity and cycle stability
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摘要 In this work,MoS2@montmorillonite nanosheets hollow microspheres(MoS2@MMTNS-HMS)with a novel morphology structure was successfully synthesized through loading MoS2 to the surface of MMTNS-HMS via hydrothermal method.The novel material has been characterized through the measurements of SEM,TEM,Raman spectra and UV–vis absorption spectra.The results have shown that MoS2@MMTNS-HMS emerges higher light-utilization efficiency,density of edge active sites and separation of photoelectrons,owing to its unique hollow structure,vertically-aligned MoS2 nanosheets,which greatly enhances its photocatalytic activity.Furthermore,the cycle stability of MoS2@MMTNS-HMS is much higher than that of pristine MoS2,which is attributed to that MMTNS-HMS greatly inhibits the oxidation of MoS2 during photocatalytic.MoS2@MMTNS-HMS could be a promising photocatalyst for the applications in the elimination of organic pollutants. In this work, MoS2@montmorillonite nanosheets hollow microspheres(MoS2@MMTNS-HMS) with a novel morphology structure was successfully synthesized through loading MoS2 to the surface of MMTNS-HMS via hydrothermal method. The novel material has been characterized through the measurements of SEM, TEM, Raman spectra and UV–vis absorption spectra. The results have shown that MoS2@MMTNS-HMS emerges higher light-utilization efficiency, density of edge active sites and separation of photoelectrons, owing to its unique hollow structure, vertically-aligned MoS2 nanosheets, which greatly enhances its photocatalytic activity. Furthermore, the cycle stability of MoS2@MMTNS-HMS is much higher than that of pristine MoS2, which is attributed to that MMTNS-HMS greatly inhibits the oxidation of MoS2 during photocatalytic. MoS2@MMTNS-HMS could be a promising photocatalyst for the applications in the elimination of organic pollutants.
出处 《Journal of Materials Science & Technology》 SCIE EI CAS CSCD 2020年第6期88-97,共10页 材料科学技术(英文版)
基金 The financial supports to this work from the National Natural Science Foundation of China under the projects Nos.51674183,51904215 and 51874220 are gratefully acknowledged supported by the Natural Science Foundation of Hubei Province of China(2018CFB468) the Excellent Dissertation Cultivation Funds of Wuhan University of Technology(2018-YS-050).
关键词 MOS2 MONTMORILLONITE Hollow MICROSPHERE Photocatalytic Methyl ORANGE MoS2 Montmorillonite Hollow microsphere Photocatalytic Methyl orange
作者简介 Corresponding author:Yunliang Zhao,E-mail addresses:zyl286@whut.edu.cn(Y.Zhao);Corresponding author:Shaoxian Song,E-mail addresses:ssx851215@whut.edu.cn(S.Song).
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