Metal containing ZSM-5 can produce higher hydrocarbons in methane oxidation. Many researchers have studied the applicability of HZSM-5 and modify ZSM-5 for methane conversion to liquid hydrocarbons, but their research...Metal containing ZSM-5 can produce higher hydrocarbons in methane oxidation. Many researchers have studied the applicability of HZSM-5 and modify ZSM-5 for methane conversion to liquid hydrocarbons, but their research results still lead to low conversion, low selectivity and low heat resistance. The modified HZSM-5, by loading with tungsten （W）, could enhance its heat resistant performance, and the high reaction temperature （800 ℃） did not lead to a loss of the W component by sublimation. The loading of HZSM-5 with tungsten and copper （Cu） resulted in an increment in the methane conversion as well as CO2 and C5＋ selectivities. In contrast, CO, C2-3 and H2O selectivities were reduced. The process of converting methane to liquid hydrocarbons （C5＋） was dependent on the metal surface area and the acidity of the zeolite. High methane conversion and C5＋ selectivity, and low H20 selectivity are obtained over W/3.0Cu/HZSM.展开更多
The laser induced plasma dynamics of graphite material are investigated by optical emission spectroscopy. Abla- tion and excitation of the graphite material is performed by using an 1064nm Nd：YAG laser in different a...The laser induced plasma dynamics of graphite material are investigated by optical emission spectroscopy. Abla- tion and excitation of the graphite material is performed by using an 1064nm Nd：YAG laser in different ambient pressures. Characteristics of graphite spectra as line intensity variations and signal-to-noise ratio are presented with a main focus on the influence of the ambient pressure on the interaction of laser-induced graphite plasma with an ambient environment. Atomic emission lines are utilized to investigate the dynamical behavior of plasma, such as the excitation temperature and electron density, to describe emission differences under different ambient conditions. The excitation temperature and plasma electron density are the primary factors which contribute to the differences among the atomic carbon emission at different ambient pressures. Reactions between the plasma species and ambient gas, and the total molecular number are the main factors influencing molecular carbon emis- sion. The influence of laser energy on the plasma interaction with environment is also investigated to demonstrate the dynamical behavior of carbon species so that it can be utilized to optimize plasma fluctuations.展开更多
With the development of communication systems, computer networks, and other information and communication technology （ICT） infrastructures, challenges in communications and efficient communications for green technol...With the development of communication systems, computer networks, and other information and communication technology （ICT） infrastructures, challenges in communications and efficient communications for green technologies are rising in recent years. In order to reduce the environmental problems thereby creating a sustainable environment, there is an urgent need for new models, algorithms, methodologies, platforms, tools, devices, and systems. Hence, green computing and communications solutions should be effectively and practically designed with more renewable energy, higher energy efficiency, lower greenhouse gas emission, and environmental friendly materials.展开更多
In recent years, the potential of renewable green energy sources has been extensively studied. The proven technology which is photovoltaic solar cells strictly depends on daylight and produces low-efficiently. To over...In recent years, the potential of renewable green energy sources has been extensively studied. The proven technology which is photovoltaic solar cells strictly depends on daylight and produces low-efficiently. To overcome the restrictions, one technology studied is through harvesting the thermal radiation energy which can provide a 24-hour energy source. The continuity of energy sources promises very good energy conversion especially for military applications. This article presents a new structure that can harvest the abundant thermal radiation energy into usable energy at the wavelength of l0 lum. A rectangular structure with a perturbation slit was designed to integrate with a rectifier circuit for green energy conversion. The slit tunnel junction guided the electromagnetic field into a junction where the energy could be collected and converted. An enhancement factor of approximately 110.6 can be achieved by a perturbation slit length of 1.0 μm. The results extracted from the proposed design promise a better candidate to overcome the disadvantages of photovoltaic solar cells for energy harvesting devices.展开更多
基金Supported by Ministry of Science,Technology and Environment,Malaysia.
文摘Metal containing ZSM-5 can produce higher hydrocarbons in methane oxidation. Many researchers have studied the applicability of HZSM-5 and modify ZSM-5 for methane conversion to liquid hydrocarbons, but their research results still lead to low conversion, low selectivity and low heat resistance. The modified HZSM-5, by loading with tungsten （W）, could enhance its heat resistant performance, and the high reaction temperature （800 ℃） did not lead to a loss of the W component by sublimation. The loading of HZSM-5 with tungsten and copper （Cu） resulted in an increment in the methane conversion as well as CO2 and C5＋ selectivities. In contrast, CO, C2-3 and H2O selectivities were reduced. The process of converting methane to liquid hydrocarbons （C5＋） was dependent on the metal surface area and the acidity of the zeolite. High methane conversion and C5＋ selectivity, and low H20 selectivity are obtained over W/3.0Cu/HZSM.
基金Supported by the FRGS under Grant No R.J130000.7809.4F519
文摘The laser induced plasma dynamics of graphite material are investigated by optical emission spectroscopy. Abla- tion and excitation of the graphite material is performed by using an 1064nm Nd：YAG laser in different ambient pressures. Characteristics of graphite spectra as line intensity variations and signal-to-noise ratio are presented with a main focus on the influence of the ambient pressure on the interaction of laser-induced graphite plasma with an ambient environment. Atomic emission lines are utilized to investigate the dynamical behavior of plasma, such as the excitation temperature and electron density, to describe emission differences under different ambient conditions. The excitation temperature and plasma electron density are the primary factors which contribute to the differences among the atomic carbon emission at different ambient pressures. Reactions between the plasma species and ambient gas, and the total molecular number are the main factors influencing molecular carbon emis- sion. The influence of laser energy on the plasma interaction with environment is also investigated to demonstrate the dynamical behavior of carbon species so that it can be utilized to optimize plasma fluctuations.
文摘With the development of communication systems, computer networks, and other information and communication technology （ICT） infrastructures, challenges in communications and efficient communications for green technologies are rising in recent years. In order to reduce the environmental problems thereby creating a sustainable environment, there is an urgent need for new models, algorithms, methodologies, platforms, tools, devices, and systems. Hence, green computing and communications solutions should be effectively and practically designed with more renewable energy, higher energy efficiency, lower greenhouse gas emission, and environmental friendly materials.
文摘In recent years, the potential of renewable green energy sources has been extensively studied. The proven technology which is photovoltaic solar cells strictly depends on daylight and produces low-efficiently. To overcome the restrictions, one technology studied is through harvesting the thermal radiation energy which can provide a 24-hour energy source. The continuity of energy sources promises very good energy conversion especially for military applications. This article presents a new structure that can harvest the abundant thermal radiation energy into usable energy at the wavelength of l0 lum. A rectangular structure with a perturbation slit was designed to integrate with a rectifier circuit for green energy conversion. The slit tunnel junction guided the electromagnetic field into a junction where the energy could be collected and converted. An enhancement factor of approximately 110.6 can be achieved by a perturbation slit length of 1.0 μm. The results extracted from the proposed design promise a better candidate to overcome the disadvantages of photovoltaic solar cells for energy harvesting devices.
