High-entropy alloy composites(HEACs)have attracted significant attention due to their exceptional mechanical properties and chemical stability.By adjusting the content of reinforcing particles in the high-entropy allo...High-entropy alloy composites(HEACs)have attracted significant attention due to their exceptional mechanical properties and chemical stability.By adjusting the content of reinforcing particles in the high-entropy alloy and by employing advanced additive manufacturing techniques,high-performance HEACs can be fabricated.However,there is still considerable room for improvement in their performance.In this study,CoCrFeMnNi HEA powders were used as the matrix,and NiCoFeAlTi high-entropy intermetallic powders were used as the high-entropy reinforcement(HER).CoCrFeMnNi/NiCoFeAlTi HEACs were fabricated using selective laser melting technology.The study results indicate that after aging,the microstructure of HEACs with HER exhibits Al-and Ti-rich nano-oxide precipitates with an orthorhombic CMCM type structure system.After aging at 873 K for 2 h,HEACs with HER achieved excellent overall mechanical properties,with an ultimate tensile strength of 731 MPa.This is attributed to the combined and synergistic effects of precipitation strengthening,dislocation strengthening,and the high lattice distortion caused by high intragranular defects,which provide a multi-scale strengthening and hardening mechanism for the plastic deformation of HEACs with HER.This study demonstrates that aging plays a crucial role in controlling the precipitate phases in complex multi-element alloys.展开更多
Ar-N_(2)-O_(2)ternary shielding gas is employed in dissimilar welding between high nitrogen steel and low alloy steel.The effect of O_(2)and N_(2)is investigated based on the systematical analysis of the metal transfe...Ar-N_(2)-O_(2)ternary shielding gas is employed in dissimilar welding between high nitrogen steel and low alloy steel.The effect of O_(2)and N_(2)is investigated based on the systematical analysis of the metal transfer,nitrogen escape phenomenon,weld appearance,nondestructive detection,nitrogen content distribution,microstructure and mechanical properties.There are two nitrogen sources of the nitrogen in the weld:high nitrogen base material and shielding gas.The effect of shielding gas is mainly reflected in these two aspects.The change of the droplet transfer mode affects the fusion ratio,N2in the shielding gas can increase nitrogen content and promote the nitrogen uniform distribution.The addition of 2%O_(2)to Ar matrix can change the metal transfer from globular transfer to spray transfer,high nitrogen base material is thereby dissolved more to the molten pool,making nitrogen content increase,ferrite decrease and the mechanical properties improve.When applying N2-containing shielding gas,arc stability becomes poor and short-circuiting transfer frequency increases due to the nitrogen escape from droplets and the molten pool.Performance of the joints is improved with N_(2)increasing,but internal gas pores are easier to appear because of the poor capacity of low alloy steel to dissolve nitrogen,The generation of pores will greatly reduce the impact resistance.4-8%N2content in shielding gas is recommended in this study considering the integrated properties of the dissimilar welded joint.展开更多
The selective laser melting(SLM)processed aluminum alloys have already aroused researchers’attention in aerospace,rail transport and petrochemical engineering due to the comprehensive advantages of low density,good c...The selective laser melting(SLM)processed aluminum alloys have already aroused researchers’attention in aerospace,rail transport and petrochemical engineering due to the comprehensive advantages of low density,good corrosion resistance and high mechanical performance.In this paper,an Al-14.1Mg-0.47Si-0.31Sc-0.17Zr alloy was fabricated via SLM.The characteristics of single track at different process parameters,and the influence of hatch spacing on densification,microstructural features and tensile properties of block specimens were systematically studied.The hatch spacing has an influence on the overlap ratio of single track,and further affects the internal forming quality of printed specimen.At a laser power of 160 W and scanning speed of 400 mm/s,the densification of block specimen increased first and then decreased with the increase of hatch spacing.The nearly full dense specimen(98.7%)with a tensile strength of 452 MPa was fabricated at a hatch spacing of 80μm.Typical characteristics of dimple and cleavage on the tensile fracture of the AlMgSiScZr alloy showed the mixed fracture of ductility and brittleness.展开更多
The new forming process of AA6061 alloy tube, including solution treatment, granule medium internal high-pressure forming and aging treatment, was developed. The AA6061 alloy tube via heat treatment satisfied the form...The new forming process of AA6061 alloy tube, including solution treatment, granule medium internal high-pressure forming and aging treatment, was developed. The AA6061 alloy tube via heat treatment satisfied the forming requirement, and the granule medium internal high pressure forming method for AA6061 alloy tube was also realized by using convenient implementation with low requirement of equipment and flexible design of product. At a solution temperature of 560℃ and time of 120 min, the elongation of the AA6061 extruded tube increases by 300% and the strength and the hardness dramatically decrease too. Therefore, the AA6061 alloy tube meets the requirement of internal high-pressure forming because of the improvement of formability. The experiments shows that the strength and hardness of AA6061 alloy workpiece recover to that of the as-received alloy at an aging temperature of 180℃ and time of 360 min, and the strength of AA6061 alloy workpiece is equal to the base alloy. The typical parts of convex ring tube, stepped shaft tube and hexagonal tube were successfully produced in lab by using the present forming method. The forming tests show that the maximum expansion ratio(MER) of the AA6061 extruded tube increases by 25.5% and the material properties of formed AA6061 alloy tube reached the performance of as-received alloy.展开更多
High nitrogen stainless steel with nitrogen content of 0.75%was welded by gas metal arc welding with Ar-N_(2)-O_(2)ternary shielding gas.The effect of the ternary shielding gas on the retention and improvement of nitr...High nitrogen stainless steel with nitrogen content of 0.75%was welded by gas metal arc welding with Ar-N_(2)-O_(2)ternary shielding gas.The effect of the ternary shielding gas on the retention and improvement of nitrogen content in the weld was identified.Surfacing test was conducted first to compare the ability of O_(2)and CO_(2)in prompting nitrogen dissolution.The nitrogen content of the surfacing metal with O_(2)is slightly higher than CO_(2).And then AreN_(2)-O_(2)shielding gas was applied to weld high nitrogen stainless steel.After using N_(2)-containing shielding gas,the nitrogen content of the weld was improved by 0.1 wt%.As N_(2)continued to increase,the increment of nitrogen content was not obvious,but the ferrite decreased from the top to the bottom.When the proportion of N_(2)reached 20%,a full austenitic weld was obtained and the tensile strength was improved by 8.7%.Combined with the results of surfacing test and welding test,it is concluded that the main effect of N_(2)is to inhibit the escape of nitrogen and suppress the nitrogen diffusion from bottom to the top in the molten pool.展开更多
A new method named rotating extrusion was developed to mitigate residual distortion of thin-plate weldments. The basic principle and characteristic of rotating extrusion as well as an efficient rotating extrusion devi...A new method named rotating extrusion was developed to mitigate residual distortion of thin-plate weldments. The basic principle and characteristic of rotating extrusion as well as an efficient rotating extrusion device were introduced. Systematic trials were conducted to investigate the influence of several technological parameters including the distance between the extrusion tool and welding torch, the pressure acting on weldment, the dimension of the extrusion tool and its rotational speed on distortion control effect. Experimental results show that, as for 2A12T4 aluminum alloy weldment with 2 mm in thickness, 150 mm in width and 350 mm in length, when appropriate technological parameters are adopted, rotating extrusion can reduce its buckling deflection to below 3% of the original value. Implementing rotating extrusion during welding with an extrusion tool more than 100 mm away from the welding torch may achieve better distortion mitigation effect.展开更多
Wearable electronics in future necessarily assemble integrated circuits(ICs)on printed circuit board(PCB)or flexible printed circuit(FPC)substrates[1].Before that,flex-on-board(FOB)assembly is to attach thin-film adhe...Wearable electronics in future necessarily assemble integrated circuits(ICs)on printed circuit board(PCB)or flexible printed circuit(FPC)substrates[1].Before that,flex-on-board(FOB)assembly is to attach thin-film adhesives between rigid and flexible substrates in current wearable electronics,such as smart watches[2].FOB is an alternative interconnection for the conventio-nal socket-type interconnection[3],by achieving a thinner package size,a higher electrical property,a fine-pitch capability and a higher long-term reliability[4].展开更多
基金Project supported by ClassⅢPeak Discipline of Shanghai-Materials Science and Engineering(High-Energy Beam Intelligent Processing and Green Manufacturing),China。
文摘High-entropy alloy composites(HEACs)have attracted significant attention due to their exceptional mechanical properties and chemical stability.By adjusting the content of reinforcing particles in the high-entropy alloy and by employing advanced additive manufacturing techniques,high-performance HEACs can be fabricated.However,there is still considerable room for improvement in their performance.In this study,CoCrFeMnNi HEA powders were used as the matrix,and NiCoFeAlTi high-entropy intermetallic powders were used as the high-entropy reinforcement(HER).CoCrFeMnNi/NiCoFeAlTi HEACs were fabricated using selective laser melting technology.The study results indicate that after aging,the microstructure of HEACs with HER exhibits Al-and Ti-rich nano-oxide precipitates with an orthorhombic CMCM type structure system.After aging at 873 K for 2 h,HEACs with HER achieved excellent overall mechanical properties,with an ultimate tensile strength of 731 MPa.This is attributed to the combined and synergistic effects of precipitation strengthening,dislocation strengthening,and the high lattice distortion caused by high intragranular defects,which provide a multi-scale strengthening and hardening mechanism for the plastic deformation of HEACs with HER.This study demonstrates that aging plays a crucial role in controlling the precipitate phases in complex multi-element alloys.
文摘Ar-N_(2)-O_(2)ternary shielding gas is employed in dissimilar welding between high nitrogen steel and low alloy steel.The effect of O_(2)and N_(2)is investigated based on the systematical analysis of the metal transfer,nitrogen escape phenomenon,weld appearance,nondestructive detection,nitrogen content distribution,microstructure and mechanical properties.There are two nitrogen sources of the nitrogen in the weld:high nitrogen base material and shielding gas.The effect of shielding gas is mainly reflected in these two aspects.The change of the droplet transfer mode affects the fusion ratio,N2in the shielding gas can increase nitrogen content and promote the nitrogen uniform distribution.The addition of 2%O_(2)to Ar matrix can change the metal transfer from globular transfer to spray transfer,high nitrogen base material is thereby dissolved more to the molten pool,making nitrogen content increase,ferrite decrease and the mechanical properties improve.When applying N2-containing shielding gas,arc stability becomes poor and short-circuiting transfer frequency increases due to the nitrogen escape from droplets and the molten pool.Performance of the joints is improved with N_(2)increasing,but internal gas pores are easier to appear because of the poor capacity of low alloy steel to dissolve nitrogen,The generation of pores will greatly reduce the impact resistance.4-8%N2content in shielding gas is recommended in this study considering the integrated properties of the dissimilar welded joint.
基金Project(51775481)supported by the National Natural Science Foundation of ChinaProject(E2019203418)supported by the Natural Science Foundation of Hebei Province,China。
文摘The selective laser melting(SLM)processed aluminum alloys have already aroused researchers’attention in aerospace,rail transport and petrochemical engineering due to the comprehensive advantages of low density,good corrosion resistance and high mechanical performance.In this paper,an Al-14.1Mg-0.47Si-0.31Sc-0.17Zr alloy was fabricated via SLM.The characteristics of single track at different process parameters,and the influence of hatch spacing on densification,microstructural features and tensile properties of block specimens were systematically studied.The hatch spacing has an influence on the overlap ratio of single track,and further affects the internal forming quality of printed specimen.At a laser power of 160 W and scanning speed of 400 mm/s,the densification of block specimen increased first and then decreased with the increase of hatch spacing.The nearly full dense specimen(98.7%)with a tensile strength of 452 MPa was fabricated at a hatch spacing of 80μm.Typical characteristics of dimple and cleavage on the tensile fracture of the AlMgSiScZr alloy showed the mixed fracture of ductility and brittleness.
基金Project(51305386)supported by the National Natural Science Foundation of ChinaProject(E2013203093)supported by the Natural Science Foundation of Hebei Province,China
文摘The new forming process of AA6061 alloy tube, including solution treatment, granule medium internal high-pressure forming and aging treatment, was developed. The AA6061 alloy tube via heat treatment satisfied the forming requirement, and the granule medium internal high pressure forming method for AA6061 alloy tube was also realized by using convenient implementation with low requirement of equipment and flexible design of product. At a solution temperature of 560℃ and time of 120 min, the elongation of the AA6061 extruded tube increases by 300% and the strength and the hardness dramatically decrease too. Therefore, the AA6061 alloy tube meets the requirement of internal high-pressure forming because of the improvement of formability. The experiments shows that the strength and hardness of AA6061 alloy workpiece recover to that of the as-received alloy at an aging temperature of 180℃ and time of 360 min, and the strength of AA6061 alloy workpiece is equal to the base alloy. The typical parts of convex ring tube, stepped shaft tube and hexagonal tube were successfully produced in lab by using the present forming method. The forming tests show that the maximum expansion ratio(MER) of the AA6061 extruded tube increases by 25.5% and the material properties of formed AA6061 alloy tube reached the performance of as-received alloy.
文摘High nitrogen stainless steel with nitrogen content of 0.75%was welded by gas metal arc welding with Ar-N_(2)-O_(2)ternary shielding gas.The effect of the ternary shielding gas on the retention and improvement of nitrogen content in the weld was identified.Surfacing test was conducted first to compare the ability of O_(2)and CO_(2)in prompting nitrogen dissolution.The nitrogen content of the surfacing metal with O_(2)is slightly higher than CO_(2).And then AreN_(2)-O_(2)shielding gas was applied to weld high nitrogen stainless steel.After using N_(2)-containing shielding gas,the nitrogen content of the weld was improved by 0.1 wt%.As N_(2)continued to increase,the increment of nitrogen content was not obvious,but the ferrite decreased from the top to the bottom.When the proportion of N_(2)reached 20%,a full austenitic weld was obtained and the tensile strength was improved by 8.7%.Combined with the results of surfacing test and welding test,it is concluded that the main effect of N_(2)is to inhibit the escape of nitrogen and suppress the nitrogen diffusion from bottom to the top in the molten pool.
基金Project(2007DFR70070) supported by Sino-Russia Intergovernmental Science and Technology Cooperation Program
文摘A new method named rotating extrusion was developed to mitigate residual distortion of thin-plate weldments. The basic principle and characteristic of rotating extrusion as well as an efficient rotating extrusion device were introduced. Systematic trials were conducted to investigate the influence of several technological parameters including the distance between the extrusion tool and welding torch, the pressure acting on weldment, the dimension of the extrusion tool and its rotational speed on distortion control effect. Experimental results show that, as for 2A12T4 aluminum alloy weldment with 2 mm in thickness, 150 mm in width and 350 mm in length, when appropriate technological parameters are adopted, rotating extrusion can reduce its buckling deflection to below 3% of the original value. Implementing rotating extrusion during welding with an extrusion tool more than 100 mm away from the welding torch may achieve better distortion mitigation effect.
文摘Wearable electronics in future necessarily assemble integrated circuits(ICs)on printed circuit board(PCB)or flexible printed circuit(FPC)substrates[1].Before that,flex-on-board(FOB)assembly is to attach thin-film adhesives between rigid and flexible substrates in current wearable electronics,such as smart watches[2].FOB is an alternative interconnection for the conventio-nal socket-type interconnection[3],by achieving a thinner package size,a higher electrical property,a fine-pitch capability and a higher long-term reliability[4].
基金Project(22A0117)supported by Hunan Provincial Department of Education,ChinaProject(AWJ-20-M02)supported by State Key Laboratory of Advanced Welding and Joining,Harbin Institute of Technology,China。
