There is an urgent need for lithium-ion capacitors(LICs)that have both high energy and high power densities to meet the continuously growing energy storage demands.LICs effectively balance the high energy density of t...There is an urgent need for lithium-ion capacitors(LICs)that have both high energy and high power densities to meet the continuously growing energy storage demands.LICs effectively balance the high energy density of traditional rechargeable batteries with the superior power density and long life of supercapacitors(SCs).Nevertheless,the development of LICs is still hampered by limited kinetic processes and capacity mismatch between the cathode and anode.Metal-organic frameworks(MOFs)and their derivatives have received significant attention because of their extensive specific surface area,different pore structures and topologies,and customizable functional sites,making them compelling candidate materials for achieving high-performance LICs.MOF-derived carbons,known for their exceptional electronic conductivity and large surface area,provide improved charge storage and rapid ion transport.MOF-derived transition metal oxides contribute to high specific capacities and improved electrochemical stability.Additionally,MOF-derived metal compounds/carbons provide combined effects that increase both the capacitive and Faradaic reactions,leading to a superior overall performance.The review begins with an overview of the fundamental principles of LICs,followed by an exploration of synthesis strategies and ligand selection for MOF-based composite materials.It then analyzes the advantages of original MOFs and their derived materials,such as carbon materials and metal compounds,in enhancing LIC performance.Finally,the review discusses the major challenges faced by MOFs and their derivatives in LIC applications and offers future research directions and recommendations.展开更多
In the context of rapid economic development,the pursuit of sustainable energy solutions has become a major challenge.Lithium-ion capacitors(LICs),which integrate the high energy density of lithium-ion batteries with ...In the context of rapid economic development,the pursuit of sustainable energy solutions has become a major challenge.Lithium-ion capacitors(LICs),which integrate the high energy density of lithium-ion batteries with the high power density of supercapacitors,have emerged as promising candidates.However,challenges such as poor capacity matching and limited energy density still hinder their practical application.Carbon nanofibers(CNFs),with their high specific surface area,excellent electrical conductivity,mechanical flexibility,and strong compatibility with active materials,are regarded as ideal electrode frameworks for LICs.This review summarizes key strategies to improve the electrochemical performance of CNF-based LICs,including structural engineering,heteroatom doping,and hybridization with transition metal oxides.The underlying mechanisms of each approach are discussed in detail,with a focus on their roles in improving capacitance,energy density,and cycling stability.This review aims to provide insights into material design and guide future research toward high-performance LICs for next-generation energy storage applications.展开更多
文摘There is an urgent need for lithium-ion capacitors(LICs)that have both high energy and high power densities to meet the continuously growing energy storage demands.LICs effectively balance the high energy density of traditional rechargeable batteries with the superior power density and long life of supercapacitors(SCs).Nevertheless,the development of LICs is still hampered by limited kinetic processes and capacity mismatch between the cathode and anode.Metal-organic frameworks(MOFs)and their derivatives have received significant attention because of their extensive specific surface area,different pore structures and topologies,and customizable functional sites,making them compelling candidate materials for achieving high-performance LICs.MOF-derived carbons,known for their exceptional electronic conductivity and large surface area,provide improved charge storage and rapid ion transport.MOF-derived transition metal oxides contribute to high specific capacities and improved electrochemical stability.Additionally,MOF-derived metal compounds/carbons provide combined effects that increase both the capacitive and Faradaic reactions,leading to a superior overall performance.The review begins with an overview of the fundamental principles of LICs,followed by an exploration of synthesis strategies and ligand selection for MOF-based composite materials.It then analyzes the advantages of original MOFs and their derived materials,such as carbon materials and metal compounds,in enhancing LIC performance.Finally,the review discusses the major challenges faced by MOFs and their derivatives in LIC applications and offers future research directions and recommendations.
文摘In the context of rapid economic development,the pursuit of sustainable energy solutions has become a major challenge.Lithium-ion capacitors(LICs),which integrate the high energy density of lithium-ion batteries with the high power density of supercapacitors,have emerged as promising candidates.However,challenges such as poor capacity matching and limited energy density still hinder their practical application.Carbon nanofibers(CNFs),with their high specific surface area,excellent electrical conductivity,mechanical flexibility,and strong compatibility with active materials,are regarded as ideal electrode frameworks for LICs.This review summarizes key strategies to improve the electrochemical performance of CNF-based LICs,including structural engineering,heteroatom doping,and hybridization with transition metal oxides.The underlying mechanisms of each approach are discussed in detail,with a focus on their roles in improving capacitance,energy density,and cycling stability.This review aims to provide insights into material design and guide future research toward high-performance LICs for next-generation energy storage applications.
