The improvement of question soils with cement shows great technical, economic and environmental advantages. And interest in introducing electrical resistivity measurement to assess the quality of cement treated soils ...The improvement of question soils with cement shows great technical, economic and environmental advantages. And interest in introducing electrical resistivity measurement to assess the quality of cement treated soils has increased markedly recently due to its economical, non-destructive, and relatively non-invasive advantages. This work aims to quantify the effect of cement content （aw）, porosity （nt）, and curing time（T） on the electrical resistivity （p） and unconfined compression strength （UCS） of cement treated soil. A series of electrical resistivity tests and UCS tests of cement treated soil specimen after various curing periods were carried out. A modified Archie empirical law was proposed taking into account the effect of cement content and curing period on the electrical resistivity of cement treated soil. The results show that nt/（aw·T） and nt/（aw·T^1/2） ratio are appropriate parameters to assess electrical resistivity and UCS of cement treated soil, respectively. Finally, the relationship between UCS and electrical resistivity was also established.展开更多
Health state of shield tunnels is one of the most important parameters for structure maintenance.Usually,the shield tunnel is extremely long in longitude direction and composed by many segments.It is difficult to quan...Health state of shield tunnels is one of the most important parameters for structure maintenance.Usually,the shield tunnel is extremely long in longitude direction and composed by many segments.It is difficult to quantify the relationship between the structure damage state and shield tunnel structure deformation by the model test because of unpredictable effects of different scales between model test and prototype tunnel structure.Here,an in-situ monitoring project was conducted to study the excavation induced shield tunnel structure damage,which could be considered a prototype test on the tunnel deformation.The disaster performance of tunnel leakage,segment crack,segment dislocation and segment block drop-off during longitude deformation and cross-section ovality developments was analyzed.The results indicate that instead of the longitude deformation,the ovality value has the strongest correlation to the rest disease performance,which could be used as the assessment index of the tunnel health.For this tunnel,it is in health state when the ovality is less than 0.5%,and the serious damage could be found when the ovality value is higher than 0.77%.The research results provide valuable reference to shield tunnel health assessment and help complete the standard of shield tunnel construction.展开更多
Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composi...Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composition of some beneficial groups. In this work, carbonized leaf powder was evaluated for its adsorption performance towards Ni（II）. According to the results, adsorbent component, dosage, initial solute concentration, solution pH, temperature and contact time can significantly affect the efficiency of Ni（II） removal. Sips model fits the test results best, and the adsorption capacity towards Ni（II） is determined around 37.62 mg/g. The thermodynamic behaviors reveal the endothermic and spontaneous nature of the adsorption. The free adsorption energy （fluctuate around 8 kJ/mol） predicted by D-R model indicates that the adsorption capacity originated from both physical and chemical adsorption. Room temperature （15-25 ℃） is suitable for Ni（II） removal as well as low energy consumption for temperature enhancement. Further conclusions about the mechanism of chemical adsorption are obtained through analysis of the FT-IR test and XRD spectra, which indicates that the adsorption process occurs predominantly between amine, carbonate, phosphate and nickel ions.展开更多
Bentonite has been proven to be effective in enhancing the membrane property of clay, by which landfill liners can have better barrier performance with regard to the migration of contaminants. In this work, 5% sodium ...Bentonite has been proven to be effective in enhancing the membrane property of clay, by which landfill liners can have better barrier performance with regard to the migration of contaminants. In this work, 5% sodium bentonite amended with locally available Fukakusa clay was utilized to evaluate the membrane behavior toward different kinds of ions： K, Na and Ca. The chemico-osmotic efficiency coefficient, co, was obtained in electrolyte solution with different concentrations of 0.5, 1, 5, 10, and 50 mmol/L. According to the results, solute type and ion valence have a significant effect on membrane behaviors. Additionally, co continually decreased as the Na and Ca concentrations increased, which is consistent with the Gouy-Chapman theory. The membrane behavior toward Na was similar to that toward K, according to the chemico-osmotic efficiency coefficient co. In the case of the divalent ion Ca, the membrane behavior was lower compared to monovalent ions Na and K at the same concentration. The mechanisms of the membrane performance change were discussed with the assistance of XRD patterns, free-swelling results and SEM images.展开更多
基金Project(BK2011618) supported by the Natural Science Foundation of Jiangsu Province, ChinaProject(51108288) supported by the National Natural Science Foundation of China
文摘The improvement of question soils with cement shows great technical, economic and environmental advantages. And interest in introducing electrical resistivity measurement to assess the quality of cement treated soils has increased markedly recently due to its economical, non-destructive, and relatively non-invasive advantages. This work aims to quantify the effect of cement content （aw）, porosity （nt）, and curing time（T） on the electrical resistivity （p） and unconfined compression strength （UCS） of cement treated soil. A series of electrical resistivity tests and UCS tests of cement treated soil specimen after various curing periods were carried out. A modified Archie empirical law was proposed taking into account the effect of cement content and curing period on the electrical resistivity of cement treated soil. The results show that nt/（aw·T） and nt/（aw·T^1/2） ratio are appropriate parameters to assess electrical resistivity and UCS of cement treated soil, respectively. Finally, the relationship between UCS and electrical resistivity was also established.
基金Projects(BK20150337,BK20140845,BK20140844)supported by the Natural Science Foundation of Jiangsu Province,ChinaProject(2015Y04)supported by the Transportation Science and Technology Project of Jiangsu Province,China+1 种基金Project(41504081)supported by the National Natural Science Foundation of ChinaProjects(2014M561567,2016T90416)supported by the China Postdoctoral Science Foundation
文摘Health state of shield tunnels is one of the most important parameters for structure maintenance.Usually,the shield tunnel is extremely long in longitude direction and composed by many segments.It is difficult to quantify the relationship between the structure damage state and shield tunnel structure deformation by the model test because of unpredictable effects of different scales between model test and prototype tunnel structure.Here,an in-situ monitoring project was conducted to study the excavation induced shield tunnel structure damage,which could be considered a prototype test on the tunnel deformation.The disaster performance of tunnel leakage,segment crack,segment dislocation and segment block drop-off during longitude deformation and cross-section ovality developments was analyzed.The results indicate that instead of the longitude deformation,the ovality value has the strongest correlation to the rest disease performance,which could be used as the assessment index of the tunnel health.For this tunnel,it is in health state when the ovality is less than 0.5%,and the serious damage could be found when the ovality value is higher than 0.77%.The research results provide valuable reference to shield tunnel health assessment and help complete the standard of shield tunnel construction.
基金Projects(5117916851308310)supported by the National Natural Science Foundation of China+1 种基金Project(LQ13E080007)supported by Zhejiang Provincial Natural Science Foundation,ChinaProject supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Jiangsu Province,China
文摘Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composition of some beneficial groups. In this work, carbonized leaf powder was evaluated for its adsorption performance towards Ni（II）. According to the results, adsorbent component, dosage, initial solute concentration, solution pH, temperature and contact time can significantly affect the efficiency of Ni（II） removal. Sips model fits the test results best, and the adsorption capacity towards Ni（II） is determined around 37.62 mg/g. The thermodynamic behaviors reveal the endothermic and spontaneous nature of the adsorption. The free adsorption energy （fluctuate around 8 kJ/mol） predicted by D-R model indicates that the adsorption capacity originated from both physical and chemical adsorption. Room temperature （15-25 ℃） is suitable for Ni（II） removal as well as low energy consumption for temperature enhancement. Further conclusions about the mechanism of chemical adsorption are obtained through analysis of the FT-IR test and XRD spectra, which indicates that the adsorption process occurs predominantly between amine, carbonate, phosphate and nickel ions.
基金Projects(51179168,51308310)supported by National Natural Science Foundation of ChinaProject(LQ13E080007)supported by Zhejiang Provincial Natural Science Foundation of ChinaProject supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars(Chinese State Education Ministry)
文摘Bentonite has been proven to be effective in enhancing the membrane property of clay, by which landfill liners can have better barrier performance with regard to the migration of contaminants. In this work, 5% sodium bentonite amended with locally available Fukakusa clay was utilized to evaluate the membrane behavior toward different kinds of ions： K, Na and Ca. The chemico-osmotic efficiency coefficient, co, was obtained in electrolyte solution with different concentrations of 0.5, 1, 5, 10, and 50 mmol/L. According to the results, solute type and ion valence have a significant effect on membrane behaviors. Additionally, co continually decreased as the Na and Ca concentrations increased, which is consistent with the Gouy-Chapman theory. The membrane behavior toward Na was similar to that toward K, according to the chemico-osmotic efficiency coefficient co. In the case of the divalent ion Ca, the membrane behavior was lower compared to monovalent ions Na and K at the same concentration. The mechanisms of the membrane performance change were discussed with the assistance of XRD patterns, free-swelling results and SEM images.
