Organic optoelectronic integrated devices（OIDs） with ultraviolet（UV） photodetectivity and different color emitting were constructed by using a thermally activated delayed fluorescence（TADF） material 4, 5-bis（ca...Organic optoelectronic integrated devices（OIDs） with ultraviolet（UV） photodetectivity and different color emitting were constructed by using a thermally activated delayed fluorescence（TADF） material 4, 5-bis（carbazol-9-yl）-1, 2-dicyanobenzene（2 CzPN） as host. The OIDs doping with typical red phosphorescent dye [tris（1-phenylisoquinoline）iridium（Ⅲ）, Ir（piq）3], orange phosphorescent dye {bis[2-（4-tertbutylphenyl）benzothiazolato-N,C-（2＇）]iridium（acetylacetonate）,（tbt）2 Ir（acac）}, and blue phosphorescent dye [bis（2, 4-di-fluorophenylpyridinato）-tetrakis（1-pyrazolyl）borate iridium（Ⅲ）, FIr6] were investigated and compared. The（tbt）2 Ir（acac）-doped orange device showed better performance than those of red and blue devices, which was ascribed to more effective energy transfer. Meanwhile, at a low dopant concentration of 3 wt.%, the（tbt）2 Ir（acac）-doped OIDs showed the maximum luminance, current efficiency, power efficiency of 70786 cd/m^2, 39.55 cd/A, and 23.92 lm/W, respectively, and a decent detectivity of 1.07 × 10^11 Jones at a bias of -2 V under the UV-350 nm illumination. This work may arouse widespread interest in constructing high efficiency and luminance OIDs based on doping phosphorescent dye.展开更多
Nanocrystalline VO2 thin films were deposited onto glass slides by direct current magnetron sputtering and postoxidation. These films undergo semiconductor-metal transition at 70 ℃, accompanied by a resistance drop o...Nanocrystalline VO2 thin films were deposited onto glass slides by direct current magnetron sputtering and postoxidation. These films undergo semiconductor-metal transition at 70 ℃, accompanied by a resistance drop of two magnitude orders. The crystal structures and surface morphologies of the VO2 films were characterized by x-ray diffraction （XRD） and atomic force microscope （AFM）, respectively. Results reveal that the average grain size of VO2 nanograins measured by XRD is smaller than those measured by AFM. In addition, Raman characterization indicates that stoichiometric VO2 and oxygen-rich VO2 phases coexist in the films, which is supported by x-ray photoelectron spectroscopy （XPS） results. Finally, the optical properties of the VO2 films in UV-visible range were also evaluated. The optical band gap corresponding to 2p-3d inter-band transition was deduced according to the transmission and reflection spectra. And the deduced value, Eopt2p-3d ： 1.81 eV, is in good agreement with that previously obtained by theoretical calculation.展开更多
Based on the rate equations describing the erbium-doped fluoride glass （ZBLAN） fibre lasers with different pumping configurations being taken into account, this paper presents theoretical calculations related to the...Based on the rate equations describing the erbium-doped fluoride glass （ZBLAN） fibre lasers with different pumping configurations being taken into account, this paper presents theoretical calculations related to the dynamic population density and the operation performance of a high power mid-infrared all-fibre erbium-doped ZBLAN fibre laser. It shows that the ground-state absorption, excited-state absorption and energy-transfer-upconversion processes co-exist and produce a population balance, causing the laser to operate stably at a continuous wave state. A good agreement between the theoretical results and recent experimental measurement is obtained. Furthermore, the laser structure parameters including fibre length, reflectance of output fibre Bragg grating and pumping configurations are quantitatively optimised to achieve the best performance. The results show, as expected, that the slope efficiency of the fibre laser can be improved significantly through optimisation, which then provides an important guide for the design of high-performance mid-infrared erbium-doped ZBLAN fibre lasers.展开更多
Pentacene organic field-effect transistors （OFETs） based on single- or double-layer biocompatible dielectrics of poly（methyl methacrylate） （PMMA） and/or silk fibroin （SF） are fabricated. Compared with those de...Pentacene organic field-effect transistors （OFETs） based on single- or double-layer biocompatible dielectrics of poly（methyl methacrylate） （PMMA） and/or silk fibroin （SF） are fabricated. Compared with those devices based on sin- gle PMMA or SF dielectric or SF/PMMA bilayer dielectric, the OFETs with biocompatible PMMA/SF bilayer dielectric exhibit optimal performance with a high field-effect mobility of 0.21 cm2/Vs and a current on/off ratio of 1.5 × 104. By investigating the surface morphology of the pentacene active layer through atom force microscopy and analyzing the elec- trical properties, the performance enhancement is mainly attributed to the crystallization improvement of the pentacene and the smaller interface trap density at the dielectric/organic interface. Meanwhile, a low contact resistance also indicates that a good electrode/organic contact is formed, thereby assisting the performance improvement of the OFET.展开更多
Both long-term environmental durability and high reflectance of protected-Al mirrors are of great importance for developing the optical instruments in the vacuum ultraviolet(VUV) applications. In this paper, the depen...Both long-term environmental durability and high reflectance of protected-Al mirrors are of great importance for developing the optical instruments in the vacuum ultraviolet(VUV) applications. In this paper, the dependence of spectral property and environmental durability of MgF2 over-coated Al mirrors using a 3-step method on deposition temperature of the outermost MgF2 layer are investigated in detail. Optics(reflectance), structure(surface morphology and crystalline), and environmental durability(humidity test) are characterized and discussed. The results show that both optical and moistureresistant properties of MgF2 over-coated Al mirrors are dependent on MgF2 deposition temperature, and the optimal deposition temperature for the outermost MgF2 layer should be between 250℃ and 300℃ for MgF2 over-coated Al mirrors to have both reasonably high reflectance in the VUV spectral range and high moisture resistance for long lifetime applications.展开更多
Phase measuring deflectometry(PMD)is a robust,noncoherent technique for the characterization of specular surface.For measuring high specular reflectivity surface,PMD can deliver micron radian range local gradient.Howe...Phase measuring deflectometry(PMD)is a robust,noncoherent technique for the characterization of specular surface.For measuring high specular reflectivity surface,PMD can deliver micron radian range local gradient.However,when the measured surface has low specular reflectivity,the accuracy of the measured gradient is low since the captured fringe pattern shows low signal to noise ratio.The phase error characteristics in PMD system when testing low reflectivity surfaces are analyzed.The analysis illustrates that the random phase error increases rapidly while the nonlinear error drops slowly with the decreasing of the tested surface reflectivity.In order to attain high precision measurement of low reflectivity specular surface,a robust error reduction method based on wavelet de-noising is proposed to reduce the phase error.This error reduction method is compared with several other normally used methods in both simulation and experiment work.The method based on the wavelet de-noising shows better performance when measuring the low reflectivity specular surface.展开更多
Tungsten oxide thin films were deposited on glass substrates by the magnetron sputtering of WO3 bulk at room temperature. The deposited films were annealed at different temperatures in air. The structural measurements...Tungsten oxide thin films were deposited on glass substrates by the magnetron sputtering of WO3 bulk at room temperature. The deposited films were annealed at different temperatures in air. The structural measurements indicate that the films annealed below 300℃ were amorphous, while the films annealed at 400 ℃ were mixed crystalline with hexagonal and triclinic phases of WO3. It was observed that the crystallization of the annealed films becomes more and more distinct with an increase in the annealing temperature. At 400 ℃, nanorod-like structures were observed on the film surface when the annealing time was increased from 60 min to 180 min. The presence of W=O stretching, W-O-W stretching, W-O-W bending and various lattice vibration modes were observed in Raman measurements. The optical absorption behaviors of the films in the range of 450-800 nm are very different with changing annealing temperatures from the room temperature to 400 ℃. After annealing at 400 ℃, the film becomes almost transparent. Increasing annealing time at 400 ℃ can lead to a small blue shift of the optical gap of the film.展开更多
A numerical model of multilayer organic light-emitting devices is presented in this article. This model is based on the drift-diffusion equations which include charge injection, transport, space charge effects, trappi...A numerical model of multilayer organic light-emitting devices is presented in this article. This model is based on the drift-diffusion equations which include charge injection, transport, space charge effects, trapping, heterojunction interface and recombination process. The device structure in the simulation is ITO/CuPc （20 nm）/NPD （40 nm）/Alq3 （60 nm）/LiF/Al. There are two heterojunctions which should be dealt with in the simulation. The I-V characteristics, carrier distribution and recombination rate of a device are calculated. The simulation results and measured data are in good agreement.展开更多
Fluorescence/phosphorescence hybrid white organic light-emitting devices（WOLEDs） based on double emitting layers（EMLs） with high color stability are fabricated.The simplified EMLs consist of a non-doped blue therm...Fluorescence/phosphorescence hybrid white organic light-emitting devices（WOLEDs） based on double emitting layers（EMLs） with high color stability are fabricated.The simplified EMLs consist of a non-doped blue thermally activated delayed fluorescence（TADF） layer using 9,9-dimethyl-9,10-dihydroacridine-diphenylsulfone（DMAC-DPS） and an ultrathin non-doped yellow phosphorescence layer employing bis[2-（4-tertbutylphenyl）benzothiazolato-N,C2＇]iridium（acetylacetonate）（（tbt）_2Ir（acac））.Two kinds of materials of 4,7-diphenyl-1,10-phenanthroline（Bphen） and 1,3,5-tris（2-Nphenylbenzimidazolyl） benzene（TPBi） are selected as the electron transporting layer（ETL）,and the thickness of yellow EML is adjusted to optimize device performance.The device based on a 0.3-nm-thick yellow EML and Bphen exhibits high color stability with a slight Commission International de l＇Eclairage（CIE） coordinates variation of（0.017,0.009） at a luminance ranging from 52 cd/m^2 to 6998 cd/m^2.The TPBi-based device yields a high efficiency with a maximum external quantum efficiency（EQE）,current efficiency,and power efficiency of 10%,21.1 cd/A,and 21.3 lm/W,respectively.The ultrathin yellow EML suppresses hole trapping and short-radius Dexter energy transfer,so that Forster energy transfer（FRET）from DMAC-DPS to（tbt）_2Ir（acac） is dominant,which is beneficial to keep the color stable.The employment of TPBi with higher triplet excited state effectively alleviates the triplet exciton quenching by ETL to improve device efficiency.展开更多
A novel method based on the use of dispersive fibers is proposed and experimentally demonstrated for measuring the high-frequency modulation index,as well as the half-wave voltage,of electro-optic phase modulators.Fib...A novel method based on the use of dispersive fibers is proposed and experimentally demonstrated for measuring the high-frequency modulation index,as well as the half-wave voltage,of electro-optic phase modulators.Fiber dispersion causes the phase modulated signal to become intensity modulated,which allows for the high resolution swept frequency measurement of phase modulators,using a vector network analyzer.The proposed method holds without the restriction of small-signal approximation,which is applicable for the measurement at different driving levels and operating wavelengths.展开更多
Two kinds of compact electromagnetic band gap （EBG） structures are designed. A two layer compact EBG structure configured with cross spiral shape line inductors and interdigital capacitors is first presented. Becaus...Two kinds of compact electromagnetic band gap （EBG） structures are designed. A two layer compact EBG structure configured with cross spiral shape line inductors and interdigital capacitors is first presented. Because of its significantly enlarged equivalent inductor and capacitance, the period of the lattice is approximately 4.5% of the free space wavelength. By insetting several narrow slits in the ground plane, the bandwidth of the main bandgap is enhanced by nearly 19%. Further effort has been made for designing a three layer compact EBG structure. Simulation results show that its period is reduced by about 26% compared to that of proposed two layer EBG structure, and the bandwidth of the main bandgap is about 3 times as that of the proposed two layer EBG structure. The detailed designs including a two layer compact 3×7 EBG array with and without defect ground plane and the three layer EBG array are given and simulation results are presented.展开更多
An original numerical model, based on the standard Berg model, is used to simulate the growth mechanism of Ndoped VOx deposited with changing oxygen flow in the reactive gas mixture. In order to compare with the numer...An original numerical model, based on the standard Berg model, is used to simulate the growth mechanism of Ndoped VOx deposited with changing oxygen flow in the reactive gas mixture. In order to compare with the numerical model, N-doped VOx films are prepared by reactive magnetron sputtering from a metallic vanadium target immersed in a reactive gas mixture of Ar＋O2＋N2. Both experimental and numerical results show that the addition of N2 to the process alleviates the hysteresis effect with respect to the oxygen supply. Film compositions obtained from the XPS analysis are compared to the numerical results and the agreement is satisfactory. The results also show that the compound of VN is only found at very low O concentration because of the replacement reaction of VN by O2 atoms with higher oxygen flow rate.展开更多
The properties of the photonic nanojet generated by a two-layer dielectric microsphere are studied. Simulation results indicate that this novel structure can generate a photonic nanojet outside its volume when the ref...The properties of the photonic nanojet generated by a two-layer dielectric microsphere are studied. Simulation results indicate that this novel structure can generate a photonic nanojet outside its volume when the refractive index contrast relative to the background medium is higher than 2：1 in the condition of plane wave incidence. When the refractive index is smaller than 2, we show that an ultralong nanojet generated by the two-layer hemisphere has an extension of 28.2 wavelengths, and compared with the homogeneous dielectric hemisphere, it has superior performance in jet length and focal distance. Its dependence on the configuration and refractive index is investigated numerically. According to the simulation of the two-layer dielectric microsphere, a photonic nanojet with a full width at half maximum（FWHM） less than 1/2 wavelength is obtained and the tunable behaviors of the photonic nanojet are demonstrated by changing the reflective indices of the material or radius contrast ratio.展开更多
A novel nonlinear mirror structure which can increase the optical signal-to-noise ratio of a distributed fiber Raman temperature sensor is proposed, and 6 dB improvement of the optical signal-to-noise ratio is obtaine...A novel nonlinear mirror structure which can increase the optical signal-to-noise ratio of a distributed fiber Raman temperature sensor is proposed, and 6 dB improvement of the optical signal-to-noise ratio is obtained. With the assistance of the nonlinear mirror, we demonstrate that the spatial resolution of the sensor is improved from 3 m to 1 m, and the temperature accuracy is improved from ±0.6℃ to ±0.2℃. The theoretical analysis and the experimental data are in good agreement.展开更多
By, introducing the random and systematic errors in simulated data computed from conventional frequency-scan and laterally resolved modulated free carrier absorption theory models, we investigate the relative determin...By, introducing the random and systematic errors in simulated data computed from conventional frequency-scan and laterally resolved modulated free carrier absorption theory models, we investigate the relative determination sensitivities of three electronic transport properties, namely, carrier lifetime carrier diffusivity and front surface recombination velocity of silicon wafers determined by frequency-scan and laterally resolved techniques. The phase and amplitude data with random errors as functions of the modulation frequency at zero pump-probe-beam separation or of the two-beam separation at four different modulation frequencies are simultaneously fitted to an appreciated carrier diffusion model to extract three transport parameters. The statistical results and fitted accuracies of the transport parameter determined by both techniques are theoretically analysed. Corresponding experimental results are carried out to compare to the simulated results. The simulated and experimental results show that the determination of the transport properties of silicon wafers by the laterally resolved technique are more accurate, as compared with that by the frequency-scan technique.展开更多
This paper simulates reactive magnetron-sputtering in constant current mode in a Vanadium-O2/Ar system equipped with a DC power supply by adopting both kinetics model and Berg＇s model. The target voltage during the r...This paper simulates reactive magnetron-sputtering in constant current mode in a Vanadium-O2/Ar system equipped with a DC power supply by adopting both kinetics model and Berg＇s model. The target voltage during the reactive sputtering has been investigated as a function of reactive gas flow. Both experiments and simulations demonstrate a hysteresis curve with respect to the oxygen supply. The time-dependent variation of the target mode is studied by measuring the target voltage for various reactive oxygen gas flows and pre-sputtering times. The pre- sputtering time increases with the increased initial target voltage. Furthermore, a corresponding time-dependent model simulating target voltage changes is also proposed. Based on these simulations, we find some relationships between the discharge voltage behaviour and the properties of the formed oxide. In this way, a better understanding of the target voltage changes during reactive sputtering can be achieved. We conclude that the presented theoretical models for parameter-dependent case and time-dependent case are in qualitative agreement with the experimental results and can be used to comprehend the target voltage behaviour in the deposition of vanadium oxide thin films.展开更多
The influence of an ultrathin 4-（dicyanomethylene）-2-t-butyl-6-（1,1,7,7-tetramethyljulolidyl-9-enyl）-4H-pyran （DCJTB） fluorescent dye layer at donor/acceptor heterojunction on the performance of small-molecule o...The influence of an ultrathin 4-（dicyanomethylene）-2-t-butyl-6-（1,1,7,7-tetramethyljulolidyl-9-enyl）-4H-pyran （DCJTB） fluorescent dye layer at donor/acceptor heterojunction on the performance of small-molecule organic photovoltaic （OPV） cell is studied. The structure of OPV cell is of indium-tin oxide （ITO）/copper phthalocyanine （CuPc）/DCJTB/fullerene （C60）/bathophenantbroline （Bphen）/Ag. The results show that open circuit voltage （Voc） increases to 0.57 V as the film thickness of DCJTB layer increases from 0.2 to 2.0 nm. By using an equivalent circuit model, the enhancement of VOC is found to be attributed to the reduced reverse saturation current density （Js） which is due to the lower highest occupied molecular orbital （HOMO） level in DCJTB than that in CuPc. Also, the short circuit current density （JSC） is affected when the DCJTB layer becomes thicker, resulting from the high series resistance RsA due to the low charge carrier mobility of fluorescent red dye.展开更多
The performance of an organic photovoltaic （OPV） cell based on copper phthatocyanine CuPc/C60 with a tris- （8-hydroxyquinolinato） aluminum （Alq3） buffer layer has been investigated. It was found that the power c...The performance of an organic photovoltaic （OPV） cell based on copper phthatocyanine CuPc/C60 with a tris- （8-hydroxyquinolinato） aluminum （Alq3） buffer layer has been investigated. It was found that the power conversion efficiency of the device was 1.51% under illumination with an intensity of 100 mW/cm^2, which was limited by a squareroot dependence of the photocurrent on voltage. The photocurrent optical power density characteristics showed that the OPV cell had a significant space-charge limited photocurrent with a varied saturation voltage and a three quarters power dependence on optical power density. Also, the absorption spectrum was measured by a spectrophotometer, and the results showed that the additional Alq3 layer has a minor effect on photocurrent generation.展开更多
Neutron dose radiation experiment is designed to study the optocoupler＇s displacement effects and the noise characteristics. The burst noise is introduced in optocouplers on neutron radiation, which is indicated from...Neutron dose radiation experiment is designed to study the optocoupler＇s displacement effects and the noise characteristics. The burst noise is introduced in optocouplers on neutron radiation, which is indicated from experiments. With the increasing neutron radiation the displacement defects in space-charge region increase, the scattering enhances and the noise signal mutations increase. All these represent the noise time series mutations, the random pulses and the increasing noise complexity. The burst noise becomes evident, and the power spectrum density, the characteristic frequency and the fractal dimension of time series of noise greatly increase.展开更多
Abstract--Poly4-vinylphenol （P4VP）/multi-wan carbon nanotubes （MWNTs） multi-layer sensitive films were deposited on interdigitated electrodes by airbrush technology to detect toluene vapor at room temperature. The...Abstract--Poly4-vinylphenol （P4VP）/multi-wan carbon nanotubes （MWNTs） multi-layer sensitive films were deposited on interdigitated electrodes by airbrush technology to detect toluene vapor at room temperature. The surface and section morphologies of the multi-layer films were observed by a scanning electron microscope （SEM）. It is found that the resistance of the sensor increases when it is exposed to toluene vapor and the response has a good linearity with the concentration of toluene. The results show that the P4VP/MWNTs three-layer film sensors have better sensing properties compared with the two-layer film sensors. The related sensing mechanism is studied in detail.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.61675041)the National Science Funds for Creative Research Groups of China(Grant No.61421002)
文摘Organic optoelectronic integrated devices（OIDs） with ultraviolet（UV） photodetectivity and different color emitting were constructed by using a thermally activated delayed fluorescence（TADF） material 4, 5-bis（carbazol-9-yl）-1, 2-dicyanobenzene（2 CzPN） as host. The OIDs doping with typical red phosphorescent dye [tris（1-phenylisoquinoline）iridium（Ⅲ）, Ir（piq）3], orange phosphorescent dye {bis[2-（4-tertbutylphenyl）benzothiazolato-N,C-（2＇）]iridium（acetylacetonate）,（tbt）2 Ir（acac）}, and blue phosphorescent dye [bis（2, 4-di-fluorophenylpyridinato）-tetrakis（1-pyrazolyl）borate iridium（Ⅲ）, FIr6] were investigated and compared. The（tbt）2 Ir（acac）-doped orange device showed better performance than those of red and blue devices, which was ascribed to more effective energy transfer. Meanwhile, at a low dopant concentration of 3 wt.%, the（tbt）2 Ir（acac）-doped OIDs showed the maximum luminance, current efficiency, power efficiency of 70786 cd/m^2, 39.55 cd/A, and 23.92 lm/W, respectively, and a decent detectivity of 1.07 × 10^11 Jones at a bias of -2 V under the UV-350 nm illumination. This work may arouse widespread interest in constructing high efficiency and luminance OIDs based on doping phosphorescent dye.
基金Project partly supported by the National Natural Science Foundation of China (Grant No. 60736005)
文摘Nanocrystalline VO2 thin films were deposited onto glass slides by direct current magnetron sputtering and postoxidation. These films undergo semiconductor-metal transition at 70 ℃, accompanied by a resistance drop of two magnitude orders. The crystal structures and surface morphologies of the VO2 films were characterized by x-ray diffraction （XRD） and atomic force microscope （AFM）, respectively. Results reveal that the average grain size of VO2 nanograins measured by XRD is smaller than those measured by AFM. In addition, Raman characterization indicates that stoichiometric VO2 and oxygen-rich VO2 phases coexist in the films, which is supported by x-ray photoelectron spectroscopy （XPS） results. Finally, the optical properties of the VO2 films in UV-visible range were also evaluated. The optical band gap corresponding to 2p-3d inter-band transition was deduced according to the transmission and reflection spectra. And the deduced value, Eopt2p-3d ： 1.81 eV, is in good agreement with that previously obtained by theoretical calculation.
基金supported by the China Postdoctoral Science Foundation (Grant No. 20090451417)the China Postdoctoral Science Special Foundation (Grant No. 201003693)+1 种基金the Fundamental Research Funds for the Central Universities of China (Grant No. ZYGX2009J053)the National Natural Science Foundation of China (Grant No. 60736038)
文摘Based on the rate equations describing the erbium-doped fluoride glass （ZBLAN） fibre lasers with different pumping configurations being taken into account, this paper presents theoretical calculations related to the dynamic population density and the operation performance of a high power mid-infrared all-fibre erbium-doped ZBLAN fibre laser. It shows that the ground-state absorption, excited-state absorption and energy-transfer-upconversion processes co-exist and produce a population balance, causing the laser to operate stably at a continuous wave state. A good agreement between the theoretical results and recent experimental measurement is obtained. Furthermore, the laser structure parameters including fibre length, reflectance of output fibre Bragg grating and pumping configurations are quantitatively optimised to achieve the best performance. The results show, as expected, that the slope efficiency of the fibre laser can be improved significantly through optimisation, which then provides an important guide for the design of high-performance mid-infrared erbium-doped ZBLAN fibre lasers.
基金Project supported by the National Natural Science Foundation of China(Grant No.61177032)the Foundation for Innovation Groups of the National Natural Science Foundation of China(Grant No.61021061)+1 种基金the Fundamental Research Funds for the Central Universities,China(Grant No.ZYGX2010Z004)the Scientific Research Staring Foundation for the Returned Overseas Chinese Scholars of the Education Ministry of China(Grant No.GGRYJJ08-05)
文摘Pentacene organic field-effect transistors （OFETs） based on single- or double-layer biocompatible dielectrics of poly（methyl methacrylate） （PMMA） and/or silk fibroin （SF） are fabricated. Compared with those devices based on sin- gle PMMA or SF dielectric or SF/PMMA bilayer dielectric, the OFETs with biocompatible PMMA/SF bilayer dielectric exhibit optimal performance with a high field-effect mobility of 0.21 cm2/Vs and a current on/off ratio of 1.5 × 104. By investigating the surface morphology of the pentacene active layer through atom force microscopy and analyzing the elec- trical properties, the performance enhancement is mainly attributed to the crystallization improvement of the pentacene and the smaller interface trap density at the dielectric/organic interface. Meanwhile, a low contact resistance also indicates that a good electrode/organic contact is formed, thereby assisting the performance improvement of the OFET.
基金Project supported by the West Light Foundation of the Chinese Academy of Sciencesthe National Natural Science Foundation of China(Grant No.61805247)
文摘Both long-term environmental durability and high reflectance of protected-Al mirrors are of great importance for developing the optical instruments in the vacuum ultraviolet(VUV) applications. In this paper, the dependence of spectral property and environmental durability of MgF2 over-coated Al mirrors using a 3-step method on deposition temperature of the outermost MgF2 layer are investigated in detail. Optics(reflectance), structure(surface morphology and crystalline), and environmental durability(humidity test) are characterized and discussed. The results show that both optical and moistureresistant properties of MgF2 over-coated Al mirrors are dependent on MgF2 deposition temperature, and the optimal deposition temperature for the outermost MgF2 layer should be between 250℃ and 300℃ for MgF2 over-coated Al mirrors to have both reasonably high reflectance in the VUV spectral range and high moisture resistance for long lifetime applications.
基金support by the National Nature Science Foundation of China (61421002, 61327004)
文摘Phase measuring deflectometry(PMD)is a robust,noncoherent technique for the characterization of specular surface.For measuring high specular reflectivity surface,PMD can deliver micron radian range local gradient.However,when the measured surface has low specular reflectivity,the accuracy of the measured gradient is low since the captured fringe pattern shows low signal to noise ratio.The phase error characteristics in PMD system when testing low reflectivity surfaces are analyzed.The analysis illustrates that the random phase error increases rapidly while the nonlinear error drops slowly with the decreasing of the tested surface reflectivity.In order to attain high precision measurement of low reflectivity specular surface,a robust error reduction method based on wavelet de-noising is proposed to reduce the phase error.This error reduction method is compared with several other normally used methods in both simulation and experiment work.The method based on the wavelet de-noising shows better performance when measuring the low reflectivity specular surface.
基金supported by the Young Scientists Fund of the National Natural Science Foundation of China(Grant Nos.11104365 and 11104366)the Hubei Key Laboratory of Low Dimensional Optoelectronic Material and Devices,China(Grant No.13XKL02002)
文摘Tungsten oxide thin films were deposited on glass substrates by the magnetron sputtering of WO3 bulk at room temperature. The deposited films were annealed at different temperatures in air. The structural measurements indicate that the films annealed below 300℃ were amorphous, while the films annealed at 400 ℃ were mixed crystalline with hexagonal and triclinic phases of WO3. It was observed that the crystallization of the annealed films becomes more and more distinct with an increase in the annealing temperature. At 400 ℃, nanorod-like structures were observed on the film surface when the annealing time was increased from 60 min to 180 min. The presence of W=O stretching, W-O-W stretching, W-O-W bending and various lattice vibration modes were observed in Raman measurements. The optical absorption behaviors of the films in the range of 450-800 nm are very different with changing annealing temperatures from the room temperature to 400 ℃. After annealing at 400 ℃, the film becomes almost transparent. Increasing annealing time at 400 ℃ can lead to a small blue shift of the optical gap of the film.
基金Project supported by Zhejiang Yangguang Cooperation Foundation, China (Grant No W050317)
文摘A numerical model of multilayer organic light-emitting devices is presented in this article. This model is based on the drift-diffusion equations which include charge injection, transport, space charge effects, trapping, heterojunction interface and recombination process. The device structure in the simulation is ITO/CuPc （20 nm）/NPD （40 nm）/Alq3 （60 nm）/LiF/Al. There are two heterojunctions which should be dealt with in the simulation. The I-V characteristics, carrier distribution and recombination rate of a device are calculated. The simulation results and measured data are in good agreement.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61675041 and 61605253)the Foundation for Innovation Research Groups of the National Natural Science Foundation of China(Grant No.61421002)the Science&Technology Department Program of Sichuan Province,China(Grant No.2016HH0027)
文摘Fluorescence/phosphorescence hybrid white organic light-emitting devices（WOLEDs） based on double emitting layers（EMLs） with high color stability are fabricated.The simplified EMLs consist of a non-doped blue thermally activated delayed fluorescence（TADF） layer using 9,9-dimethyl-9,10-dihydroacridine-diphenylsulfone（DMAC-DPS） and an ultrathin non-doped yellow phosphorescence layer employing bis[2-（4-tertbutylphenyl）benzothiazolato-N,C2＇]iridium（acetylacetonate）（（tbt）_2Ir（acac））.Two kinds of materials of 4,7-diphenyl-1,10-phenanthroline（Bphen） and 1,3,5-tris（2-Nphenylbenzimidazolyl） benzene（TPBi） are selected as the electron transporting layer（ETL）,and the thickness of yellow EML is adjusted to optimize device performance.The device based on a 0.3-nm-thick yellow EML and Bphen exhibits high color stability with a slight Commission International de l＇Eclairage（CIE） coordinates variation of（0.017,0.009） at a luminance ranging from 52 cd/m^2 to 6998 cd/m^2.The TPBi-based device yields a high efficiency with a maximum external quantum efficiency（EQE）,current efficiency,and power efficiency of 10%,21.1 cd/A,and 21.3 lm/W,respectively.The ultrathin yellow EML suppresses hole trapping and short-radius Dexter energy transfer,so that Forster energy transfer（FRET）from DMAC-DPS to（tbt）_2Ir（acac） is dominant,which is beneficial to keep the color stable.The employment of TPBi with higher triplet excited state effectively alleviates the triplet exciton quenching by ETL to improve device efficiency.
基金Supported by the National Basic Research Program of China under Grant Nos 2012CB315702 and 2011CB301705the National Natural Science Foundation of China under Grant Nos 60907008,61077017 and 61090393the NCET Program under Grant No NCET-11-0069.
文摘A novel method based on the use of dispersive fibers is proposed and experimentally demonstrated for measuring the high-frequency modulation index,as well as the half-wave voltage,of electro-optic phase modulators.Fiber dispersion causes the phase modulated signal to become intensity modulated,which allows for the high resolution swept frequency measurement of phase modulators,using a vector network analyzer.The proposed method holds without the restriction of small-signal approximation,which is applicable for the measurement at different driving levels and operating wavelengths.
基金supported by the National Natural Science Foundation of China under Grant No. 60588502
文摘Two kinds of compact electromagnetic band gap （EBG） structures are designed. A two layer compact EBG structure configured with cross spiral shape line inductors and interdigital capacitors is first presented. Because of its significantly enlarged equivalent inductor and capacitance, the period of the lattice is approximately 4.5% of the free space wavelength. By insetting several narrow slits in the ground plane, the bandwidth of the main bandgap is enhanced by nearly 19%. Further effort has been made for designing a three layer compact EBG structure. Simulation results show that its period is reduced by about 26% compared to that of proposed two layer EBG structure, and the bandwidth of the main bandgap is about 3 times as that of the proposed two layer EBG structure. The detailed designs including a two layer compact 3×7 EBG array with and without defect ground plane and the three layer EBG array are given and simulation results are presented.
文摘An original numerical model, based on the standard Berg model, is used to simulate the growth mechanism of Ndoped VOx deposited with changing oxygen flow in the reactive gas mixture. In order to compare with the numerical model, N-doped VOx films are prepared by reactive magnetron sputtering from a metallic vanadium target immersed in a reactive gas mixture of Ar＋O2＋N2. Both experimental and numerical results show that the addition of N2 to the process alleviates the hysteresis effect with respect to the oxygen supply. Film compositions obtained from the XPS analysis are compared to the numerical results and the agreement is satisfactory. The results also show that the compound of VN is only found at very low O concentration because of the replacement reaction of VN by O2 atoms with higher oxygen flow rate.
基金Project supported by State Key Laboratory of Optical Technologies on Nano-Fabrication and Micro-Engineering,Institute of Optics and Electronics,Chinese Academy of SciencesSichuan Provincial Department of Education,China(Grant No.16ZA0047)+1 种基金the State Key Laboratory of Metastable Materials Science and Technology,Yansan University,China(Grant No.201509)the Large Precision Instruments Open Project Foundation of Sichuan Normal University,China(Grant Nos.DJ2015-57,DJ2015-58,DJ2015-60,DJ2016-58,and DJ2016-59)
文摘The properties of the photonic nanojet generated by a two-layer dielectric microsphere are studied. Simulation results indicate that this novel structure can generate a photonic nanojet outside its volume when the refractive index contrast relative to the background medium is higher than 2：1 in the condition of plane wave incidence. When the refractive index is smaller than 2, we show that an ultralong nanojet generated by the two-layer hemisphere has an extension of 28.2 wavelengths, and compared with the homogeneous dielectric hemisphere, it has superior performance in jet length and focal distance. Its dependence on the configuration and refractive index is investigated numerically. According to the simulation of the two-layer dielectric microsphere, a photonic nanojet with a full width at half maximum（FWHM） less than 1/2 wavelength is obtained and the tunable behaviors of the photonic nanojet are demonstrated by changing the reflective indices of the material or radius contrast ratio.
基金supported by the National Natural Science Foundation of China under Grant No.60377021partially supported by Program for New Century Excellent Talents in University under Grant No. NCET-07-0152Sichuan Scientific Funds for Young Researchers under Grant No. 08ZQ026-012.
文摘A novel nonlinear mirror structure which can increase the optical signal-to-noise ratio of a distributed fiber Raman temperature sensor is proposed, and 6 dB improvement of the optical signal-to-noise ratio is obtained. With the assistance of the nonlinear mirror, we demonstrate that the spatial resolution of the sensor is improved from 3 m to 1 m, and the temperature accuracy is improved from ±0.6℃ to ±0.2℃. The theoretical analysis and the experimental data are in good agreement.
基金Project supported by the Fundamental Research Funds for the Central Universities of China (Grant No. ZYGX2009J051)
文摘By, introducing the random and systematic errors in simulated data computed from conventional frequency-scan and laterally resolved modulated free carrier absorption theory models, we investigate the relative determination sensitivities of three electronic transport properties, namely, carrier lifetime carrier diffusivity and front surface recombination velocity of silicon wafers determined by frequency-scan and laterally resolved techniques. The phase and amplitude data with random errors as functions of the modulation frequency at zero pump-probe-beam separation or of the two-beam separation at four different modulation frequencies are simultaneously fitted to an appreciated carrier diffusion model to extract three transport parameters. The statistical results and fitted accuracies of the transport parameter determined by both techniques are theoretically analysed. Corresponding experimental results are carried out to compare to the simulated results. The simulated and experimental results show that the determination of the transport properties of silicon wafers by the laterally resolved technique are more accurate, as compared with that by the frequency-scan technique.
基金supported by the National Natural Science Foundation of China (Grant No. 60806021)
文摘This paper simulates reactive magnetron-sputtering in constant current mode in a Vanadium-O2/Ar system equipped with a DC power supply by adopting both kinetics model and Berg＇s model. The target voltage during the reactive sputtering has been investigated as a function of reactive gas flow. Both experiments and simulations demonstrate a hysteresis curve with respect to the oxygen supply. The time-dependent variation of the target mode is studied by measuring the target voltage for various reactive oxygen gas flows and pre-sputtering times. The pre- sputtering time increases with the increased initial target voltage. Furthermore, a corresponding time-dependent model simulating target voltage changes is also proposed. Based on these simulations, we find some relationships between the discharge voltage behaviour and the properties of the formed oxide. In this way, a better understanding of the target voltage changes during reactive sputtering can be achieved. We conclude that the presented theoretical models for parameter-dependent case and time-dependent case are in qualitative agreement with the experimental results and can be used to comprehend the target voltage behaviour in the deposition of vanadium oxide thin films.
基金Project partially supported by the National Natural Science Foundation of China(NNSFC)(Grant Nos.60736005 and 60425101-1)the Foundation for Innovative Research Groups of the NNSFC(Grant No.60721001)+3 种基金the Research Fund for the Dectoral Program of Higher Education(RFDP)(Grant No.20090185110020)the Program for New Century Excellent Talents in University,China(Grant No.NCET-06-0812)the Scientific Research Foundation for Returned Overseas Chinese Scholars,State Education Ministry(Grant No.GGRYJJ08-05)the Young Excellence Project of Sichuan Province,China(Grant No.09ZQ026-074)
文摘The influence of an ultrathin 4-（dicyanomethylene）-2-t-butyl-6-（1,1,7,7-tetramethyljulolidyl-9-enyl）-4H-pyran （DCJTB） fluorescent dye layer at donor/acceptor heterojunction on the performance of small-molecule organic photovoltaic （OPV） cell is studied. The structure of OPV cell is of indium-tin oxide （ITO）/copper phthalocyanine （CuPc）/DCJTB/fullerene （C60）/bathophenantbroline （Bphen）/Ag. The results show that open circuit voltage （Voc） increases to 0.57 V as the film thickness of DCJTB layer increases from 0.2 to 2.0 nm. By using an equivalent circuit model, the enhancement of VOC is found to be attributed to the reduced reverse saturation current density （Js） which is due to the lower highest occupied molecular orbital （HOMO） level in DCJTB than that in CuPc. Also, the short circuit current density （JSC） is affected when the DCJTB layer becomes thicker, resulting from the high series resistance RsA due to the low charge carrier mobility of fluorescent red dye.
基金Project supported by the National Natural Science Foundation of China (NSFC) (Grant Nos. 60736005 and 60425101-1)the Foundation for Innovative Research Groups of the NSFC (Grant No. 60721001),Provincial Project (Grant No. 9140A02060609DZ0208)+1 种基金Program for New Century Excellent Talents in University (Grant No. NCET-06-0812),SRF for ROCS,SEM (Grant No. GGRYJJ08-05)Young Excellent Project of Sichuan Province (Grant No. 09ZQ026-074)
文摘The performance of an organic photovoltaic （OPV） cell based on copper phthatocyanine CuPc/C60 with a tris- （8-hydroxyquinolinato） aluminum （Alq3） buffer layer has been investigated. It was found that the power conversion efficiency of the device was 1.51% under illumination with an intensity of 100 mW/cm^2, which was limited by a squareroot dependence of the photocurrent on voltage. The photocurrent optical power density characteristics showed that the OPV cell had a significant space-charge limited photocurrent with a varied saturation voltage and a three quarters power dependence on optical power density. Also, the absorption spectrum was measured by a spectrophotometer, and the results showed that the additional Alq3 layer has a minor effect on photocurrent generation.
文摘Neutron dose radiation experiment is designed to study the optocoupler＇s displacement effects and the noise characteristics. The burst noise is introduced in optocouplers on neutron radiation, which is indicated from experiments. With the increasing neutron radiation the displacement defects in space-charge region increase, the scattering enhances and the noise signal mutations increase. All these represent the noise time series mutations, the random pulses and the increasing noise complexity. The burst noise becomes evident, and the power spectrum density, the characteristic frequency and the fractal dimension of time series of noise greatly increase.
基金partially supported by the National Natural Foundation of China under Grant No.61176066 and No.61101031
文摘Abstract--Poly4-vinylphenol （P4VP）/multi-wan carbon nanotubes （MWNTs） multi-layer sensitive films were deposited on interdigitated electrodes by airbrush technology to detect toluene vapor at room temperature. The surface and section morphologies of the multi-layer films were observed by a scanning electron microscope （SEM）. It is found that the resistance of the sensor increases when it is exposed to toluene vapor and the response has a good linearity with the concentration of toluene. The results show that the P4VP/MWNTs three-layer film sensors have better sensing properties compared with the two-layer film sensors. The related sensing mechanism is studied in detail.
