This paper is investigating the use of composite armour reinforced by nanomaterials, for the protection of light armoured(LAV) and medium armoured military vehicles(MAV), and the interaction between the composite mate...This paper is investigating the use of composite armour reinforced by nanomaterials, for the protection of light armoured(LAV) and medium armoured military vehicles(MAV), and the interaction between the composite materials and high-performance ballistic projectiles. Four armour materials, consisted of front hybrid fibre reinforced polymer cover layer, ceramic strike-face, fibre reinforced polymer intermediate layer and the metal matrix composite reinforced backplate, were manufactured and assembled by adhesive technology. The proposed laminated protection system is suitable for armoured ground vehicles;however, it could be used as armour on ground, air and naval platforms. The design of the protection system, including material selection and thickness, was elaborated depending on the performance requirements of Level 4 + STANAG 4569 military standard(projectile 14.5 mm × 114 mm API B32) and especially on a design philosophy which is analysed with the specifications. The backplate of this new composite is a hybrid material of Metal Matrix Composite(MMC) reinforced with carbon nanotubes(CNTs), manufactured with the use of powder metallurgy technique. The composite backplate material was morphologically, mechanically and chemically analysed. Results show that all plates are presenting high mechanical properties and ballistic characteristics, compared to commonly used armour plates. Real military ballistic tests according to AEP-STANAG 4569 were carried out for the total composite armour systems. After the ballistic tests, AA2024-CNT3 showed the best protection results, compared with the other plates(AA2024-CNT1 and AA2024-CNT2), with the projectile being unable to fully penetrate the composite plate.展开更多
A constructive method was presented to design a global robust and adaptive output feedback controller for dynamic positioning of surface ships under environmental disturbances induced by waves, wind, and ocean current...A constructive method was presented to design a global robust and adaptive output feedback controller for dynamic positioning of surface ships under environmental disturbances induced by waves, wind, and ocean currents. The ship's parameters were not required to be known. An adaptive observer was first designed to estimate the ship's velocities and parameters. The ship position measurements were also passed through the adaptive observer to reduce high frequency measurement noise from entering the control system. Using these estimate signals, the control was then designed based on Lyapunov's direct method to force the ship's position and orientation to globally asymptotically converge to desired values. Simulation results illustrate the effectiveness of the proposed control system. In conclusion, the paper presented a new method to design an effective control system for dynamic positioning of surface ships.展开更多
Hexagonal boron nitride(h-BN),with unique structural and properties,has shown enormous potentitoward variety of possible applications.By virtue of partially-ionic character of BN chemical bonds anusually large specifi...Hexagonal boron nitride(h-BN),with unique structural and properties,has shown enormous potentitoward variety of possible applications.By virtue of partially-ionic character of BN chemical bonds anusually large specific surface area,h-BN-related nanostructures exhibit appealing adsorption propertiewhich can be widely applied for separation and purification towards energy and environment treatmenIn this review,recent progress in designing h-BN micro,nano-structure,controlled synthesis,performancoptimizing as well as energy and environment-related adsorption applications are summarized.Strategieto tailor the h-BN can be classified as morphology control,element doping,defect control and surfacmodification,focusing on how to optimize the adsorption performance.In order to insight the intrinsimechanism of tuning strategies for property optimization,the significant adsorption applications of h-Btowards hydrogen storage,CO2 capture,pollutants removal from water and adsorption desulfurization arpresented.展开更多
The torsional characteristics of single walled carbon nanotube(SWCNT) with water interactions are studied in this work using molecular dynamics simulation method. The torsional properties of carbon nanotubes(CNTs) in ...The torsional characteristics of single walled carbon nanotube(SWCNT) with water interactions are studied in this work using molecular dynamics simulation method. The torsional properties of carbon nanotubes(CNTs) in a hydrodynamic environment such as water are critical for its key role in determining the lifetime and stability of CNT based nano-fluidic devices. The effect of chirality, defects and the density of water encapsulation is studied by subjecting the SWCNT to torsion. The findings show that the torsional strength of SWCNT decreases due to interaction of water molecules and presence of defects in the SWCNT. Additionally,for the case of water molecules encapsulated inside SWCNT, the torsional response depends on the density of packing of water molecules. Our findings and conclusions obtained from this paper is expected to further compliment the potential applications of CNTs as promising candidates for applications in nano-biological and nano-fluidic devices.展开更多
Electroreduction of CO_(2)shows great potential for global CO_(2)utilization and uptake when collaborated with renewable electricity.Recent advances have been achieved in fundamental understanding and electrocatalyst ...Electroreduction of CO_(2)shows great potential for global CO_(2)utilization and uptake when collaborated with renewable electricity.Recent advances have been achieved in fundamental understanding and electrocatalyst development for CO_(2)electroreduction.We think this research area has progressed to the stage where significant efforts can focus on translating the obtained knowledge to the development of largescale electrolyzers,which have the potential to accelerate the transition of the current energy system into a sustainable and zero-carbon emission energy structure.In this perspective paper,we first critically evaluate the advancement of vapor-feed devices that use CO_(2)as reactants,from the point of view of industry applications.Then,by carefully comparing their performance to the state-of-the-art water electrolyzers which are well-established technology providing realistic performance targets,we looped back and discussed the remaining challenges including electrode catalysts,reaction conditions,mass transporting,membrane,device durability,operation mode,and so on.Finally,we provide perspectives on the challenges and suggest opportunities for generating fundamental knowledge and achieving technological progress toward the development of practical CO_(2)electrolyzers for the goal of building lowcarbon or/and net carbon-free economies.展开更多
Tomographic particle image velocimetry(TPIV)and static pressure measurements are performed in a wind tunnel on a scaled model of the rotor blade of a 5 kW horizontal-axis wind turbine designed by using the blade eleme...Tomographic particle image velocimetry(TPIV)and static pressure measurements are performed in a wind tunnel on a scaled model of the rotor blade of a 5 kW horizontal-axis wind turbine designed by using the blade element momentum method.This study is to investigate the physics of the stall-delay phenomenon observed for a rotating blade.The TPIV experiments are conducted at several span-wise locations of the blade.The separated flow from the rotating blade is studied and compared with the case of the static stall at similar angles of attack and Reynolds number Re.展开更多
A method for formation flight trajectory optimization was established.This method aims at minimizing fuel consumption of a two-aircraft formation flight,without changing the original trajectory of the leader.Candidate...A method for formation flight trajectory optimization was established.This method aims at minimizing fuel consumption of a two-aircraft formation flight,without changing the original trajectory of the leader.Candidate flight pairs were selected from all international flights arriving at or departing from China in one day according to the requirement of the proposed method.Aircraft performance database Base of Aircraft Data(BADA)was employed in the trajectory computation.By assuming different fuel-saving percentages for the following aircraft,pre-flight plan trajectories of formation flight were optimized.The fuel consumption optimization effect under the influence of different trajectory optimization parameters was also analyzed.The results showed that the higher the fuel savings percentage,the longer the flight distance of formation flight,but the smaller the number of formation combinations that can be realized,which is limited by the aircraft performance.The following aircraft flying along the approximate actual flight trajectory can be benefited as well,and the optimal fuel-saving efficiency is related to the expected fuelsaving efficiency of formation flight.展开更多
We conceptualize bioresource upgrade for sustainable energy,environment,and biomedicine with a focus on circular economy,sustainability,and carbon neutrality using high availability and low utilization biomass(HALUB)....We conceptualize bioresource upgrade for sustainable energy,environment,and biomedicine with a focus on circular economy,sustainability,and carbon neutrality using high availability and low utilization biomass(HALUB).We acme energy-efficient technologies for sustainable energy and material recovery and applications.The technologies of thermochemical conversion(TC),biochemical conversion(BC),electrochemical conversion(EC),and photochemical conversion(PTC)are summarized for HALUB.Microalgal biomass could contribute to a biofuel HHV of 35.72 MJ Kg^(-1)and total benefit of 749$/ton biomass via TC.Specific surface area of biochar reached 3000 m^(2)g^(-1)via pyrolytic carbonization of waste bean dregs.Lignocellulosic biomass can be effectively converted into bio-stimulants and biofertilizers via BC with a high conversion efficiency of more than 90%.Besides,lignocellulosic biomass can contribute to a current density of 672 mA m^(-2)via EC.Bioresource can be 100%selectively synthesized via electrocatalysis through EC and PTC.Machine learning,techno-economic analysis,and life cycle analysis are essential to various upgrading approaches of HALUB.Sustainable biomaterials,sustainable living materials and technologies for biomedical and multifunctional applications like nano-catalysis,microfluidic and micro/nanomotors beyond are also highlighted.New techniques and systems for the complete conversion and utilization of HALUB for new energy and materials are further discussed.展开更多
Electric field distribution is an important parameter for nanostructure arrays in nanobiosensing appfications. It can influence the sensitivity and the resolution of nanobiosensors. We focus on the effect of media on ...Electric field distribution is an important parameter for nanostructure arrays in nanobiosensing appfications. It can influence the sensitivity and the resolution of nanobiosensors. We focus on the effect of media on the electric field distribution of a rhombic silver nanostructure array. The finite-difference time-domain algorithm- based numerical calculation method is used to monitor the electric field distribution of the silver nanostructures when the refractive index of the medium around the nanostructure array is changed. The calculated results show that tuning the refractive index of the medium around silver can have a considerable influence on the electric field distribution in the reflection and transmission directions. This effect can be used to increase the extinction efficiency and to improve the resolution of the spectra for nanobiosensing.展开更多
The interface wave propagating along an imperfect interface between two piezoelectric half spaces is derived firstly. The wave equations based on the interface modeled, called ＂spring model＂, are presented. The micr...The interface wave propagating along an imperfect interface between two piezoelectric half spaces is derived firstly. The wave equations based on the interface modeled, called ＂spring model＂, are presented. The micro-scale structures of the interface for connecting the spring constant with the interface micro-structures are examined. For some simple interface micro-structure, exact dynamic solution is available, and the spring constant is obtained by comparing solutions. For the complex micro structures, it remains as a challenge of micro-mechanics modeling to connect the ＂spring constant＂ and micro-structure.展开更多
The fuel consumption of a ship has always been an important research topic,but nowadays its importance has even increased as it is directly related to a ship’s greenhouse gas(GHG)emissions,which is now tightly regula...The fuel consumption of a ship has always been an important research topic,but nowadays its importance has even increased as it is directly related to a ship’s greenhouse gas(GHG)emissions,which is now tightly regulated.In this paper,such a dynamic model is presented.The ship’s resistance in calm water and propeller’s performance in open water are required as input.The hull efficiency is estimated empirically.The diesel engine is modelled by a first-order transfer function with a delayed response and its performance is calibrated with the data from the manufacturer’s catalogue.A governor is applied to maintain the pre-set engine’s rotational speed and to control the engine fuel rate.A slope limiter is employed to approximate the actual engine operation during engine transients.The default values can be obtained from the manufacturer engine load acceptance diagram.The developed model is implemented in MATLAB SIMULINK environment.After validation against third-party published results,the influence of using different types of governors on ship speed and fuel consumption is investigated.The model is also applied to simulate the fuel consumption of a ship during a typical acceleration manoeuvre and the scenario of a real ship encountering harsh weather conditions.展开更多
Two-dimensional(2D) materials have exhibited great potential for replacing costly Pt for oxygen reduction reaction(ORR) because of their distinctive structural features and high pre-site activity.However,their perform...Two-dimensional(2D) materials have exhibited great potential for replacing costly Pt for oxygen reduction reaction(ORR) because of their distinctive structural features and high pre-site activity.However,their performance is generally hindered by the limited density of active sites(e.g.,at the layer edges).Although they feature a high exposure of surface sites,these sites are typically inert for ORR.Herein,through density functional theory calculations,we propose a promising ORR catalyst candidate,a 2D TaTe_(2) nanosheet,which has an intrinsic high basal-plane activity.Both of the thermodynamic and kinetic processes are explored,which demonstrates that the basal-plane Te sites of the TaTe_(2) nanosheet have great potential for facilitating ORR.Specifically,we construct a microkinetic model of ORR proceeding on TaTe_(2),which unveils its dynamic intermediate coverage under different electrode potentials and identifies the dominating associative pathway.The theoretical half-wave potential of TaTe_(2) is predicted to be 0.87 V,which exceeds those of the well-established Pt(111) and Fe–N–C single-atom catalysts computed at the same level.This study not only presents the first 2D,non-Pt ORR catalyst candidate with an intrinsic basal-plane activity but also offers a rational methodology for unveiling the mechanism/activity of ORR and other electrochemical reactions.展开更多
There is a pressing need in very small scale threedimensional(3 D) inkjet printing to control and reduce agglomeration,as agglomeration often leads to nozzle clogging.While agglomeration within ultraviolet ink has bee...There is a pressing need in very small scale threedimensional(3 D) inkjet printing to control and reduce agglomeration,as agglomeration often leads to nozzle clogging.While agglomeration within ultraviolet ink has been studied,there has been,to our knowledge,no extensive studies conducted for surface agglomeration of the ink on nozzle's wall.This numerical study therefore focuses on investigating if surfactants can effectively control surface agglomeration during nanodroplet formation.Many-body dissipative particle dynamics is the numerical method of choice here.We found that small amount of surfactant of about 1 wt % is sufficient to effectively reduce ink deposition on the nozzle's wall.However,by using the properties of a commercially available surfactant,sodium dodecyl sulfate,it was found that the maximum reduction achieved by its addition is only 60%.Thus,further physical or chemical deagglomeration techniques are required,and we show that by considering these other techniques,reduction of surface agglomeration to nearly 92% can be achieved.Finally,we found that adding surfactants has the additional benefit of improving total kinetic energy of the ink compositions,lowering possibility of agglomerations within the ink.It also raises the nanodroplet velocity while reducing nanodroplet breakup time,which can help speed up the process of 3 D printing process.展开更多
基金the Research and Development department of EODH SA and has been co-financed by the European Regional Development Fund of the European Union and Greek national funds through the Operational Program Competitiveness,Entrepreneurship and Innovation,under the call RESEARCH-CREATE-INNOVATE(project code:T1EDK-04429).
文摘This paper is investigating the use of composite armour reinforced by nanomaterials, for the protection of light armoured(LAV) and medium armoured military vehicles(MAV), and the interaction between the composite materials and high-performance ballistic projectiles. Four armour materials, consisted of front hybrid fibre reinforced polymer cover layer, ceramic strike-face, fibre reinforced polymer intermediate layer and the metal matrix composite reinforced backplate, were manufactured and assembled by adhesive technology. The proposed laminated protection system is suitable for armoured ground vehicles;however, it could be used as armour on ground, air and naval platforms. The design of the protection system, including material selection and thickness, was elaborated depending on the performance requirements of Level 4 + STANAG 4569 military standard(projectile 14.5 mm × 114 mm API B32) and especially on a design philosophy which is analysed with the specifications. The backplate of this new composite is a hybrid material of Metal Matrix Composite(MMC) reinforced with carbon nanotubes(CNTs), manufactured with the use of powder metallurgy technique. The composite backplate material was morphologically, mechanically and chemically analysed. Results show that all plates are presenting high mechanical properties and ballistic characteristics, compared to commonly used armour plates. Real military ballistic tests according to AEP-STANAG 4569 were carried out for the total composite armour systems. After the ballistic tests, AA2024-CNT3 showed the best protection results, compared with the other plates(AA2024-CNT1 and AA2024-CNT2), with the projectile being unable to fully penetrate the composite plate.
文摘A constructive method was presented to design a global robust and adaptive output feedback controller for dynamic positioning of surface ships under environmental disturbances induced by waves, wind, and ocean currents. The ship's parameters were not required to be known. An adaptive observer was first designed to estimate the ship's velocities and parameters. The ship position measurements were also passed through the adaptive observer to reduce high frequency measurement noise from entering the control system. Using these estimate signals, the control was then designed based on Lyapunov's direct method to force the ship's position and orientation to globally asymptotically converge to desired values. Simulation results illustrate the effectiveness of the proposed control system. In conclusion, the paper presented a new method to design an effective control system for dynamic positioning of surface ships.
基金financially supported by the National Natural Science Foundation of China (Nos. 21606113, 21676128, and 21722604)the International Postdoctoral Exchange Fellowship by China Postdoctoral Science Foundation (No. 20170055)
文摘Hexagonal boron nitride(h-BN),with unique structural and properties,has shown enormous potentitoward variety of possible applications.By virtue of partially-ionic character of BN chemical bonds anusually large specific surface area,h-BN-related nanostructures exhibit appealing adsorption propertiewhich can be widely applied for separation and purification towards energy and environment treatmenIn this review,recent progress in designing h-BN micro,nano-structure,controlled synthesis,performancoptimizing as well as energy and environment-related adsorption applications are summarized.Strategieto tailor the h-BN can be classified as morphology control,element doping,defect control and surfacmodification,focusing on how to optimize the adsorption performance.In order to insight the intrinsimechanism of tuning strategies for property optimization,the significant adsorption applications of h-Btowards hydrogen storage,CO2 capture,pollutants removal from water and adsorption desulfurization arpresented.
文摘The torsional characteristics of single walled carbon nanotube(SWCNT) with water interactions are studied in this work using molecular dynamics simulation method. The torsional properties of carbon nanotubes(CNTs) in a hydrodynamic environment such as water are critical for its key role in determining the lifetime and stability of CNT based nano-fluidic devices. The effect of chirality, defects and the density of water encapsulation is studied by subjecting the SWCNT to torsion. The findings show that the torsional strength of SWCNT decreases due to interaction of water molecules and presence of defects in the SWCNT. Additionally,for the case of water molecules encapsulated inside SWCNT, the torsional response depends on the density of packing of water molecules. Our findings and conclusions obtained from this paper is expected to further compliment the potential applications of CNTs as promising candidates for applications in nano-biological and nano-fluidic devices.
基金financially supported by the Zhejiang Energy Group Co.,Ltd.(ZNKJ-2021-111)Zhejiang Province key research and development program(2022C03040)。
文摘Electroreduction of CO_(2)shows great potential for global CO_(2)utilization and uptake when collaborated with renewable electricity.Recent advances have been achieved in fundamental understanding and electrocatalyst development for CO_(2)electroreduction.We think this research area has progressed to the stage where significant efforts can focus on translating the obtained knowledge to the development of largescale electrolyzers,which have the potential to accelerate the transition of the current energy system into a sustainable and zero-carbon emission energy structure.In this perspective paper,we first critically evaluate the advancement of vapor-feed devices that use CO_(2)as reactants,from the point of view of industry applications.Then,by carefully comparing their performance to the state-of-the-art water electrolyzers which are well-established technology providing realistic performance targets,we looped back and discussed the remaining challenges including electrode catalysts,reaction conditions,mass transporting,membrane,device durability,operation mode,and so on.Finally,we provide perspectives on the challenges and suggest opportunities for generating fundamental knowledge and achieving technological progress toward the development of practical CO_(2)electrolyzers for the goal of building lowcarbon or/and net carbon-free economies.
基金Supported by the Energy Research Institute at Nanyang Technological University and Ministry of Education in Singapore under Grant No RG 52/11.
文摘Tomographic particle image velocimetry(TPIV)and static pressure measurements are performed in a wind tunnel on a scaled model of the rotor blade of a 5 kW horizontal-axis wind turbine designed by using the blade element momentum method.This study is to investigate the physics of the stall-delay phenomenon observed for a rotating blade.The TPIV experiments are conducted at several span-wise locations of the blade.The separated flow from the rotating blade is studied and compared with the case of the static stall at similar angles of attack and Reynolds number Re.
基金This work was supported by the National Natural Science Foundation of China(No.U1633109)the Fundamental Research Funds for the Central Universities(No.3122016C010).
文摘A method for formation flight trajectory optimization was established.This method aims at minimizing fuel consumption of a two-aircraft formation flight,without changing the original trajectory of the leader.Candidate flight pairs were selected from all international flights arriving at or departing from China in one day according to the requirement of the proposed method.Aircraft performance database Base of Aircraft Data(BADA)was employed in the trajectory computation.By assuming different fuel-saving percentages for the following aircraft,pre-flight plan trajectories of formation flight were optimized.The fuel consumption optimization effect under the influence of different trajectory optimization parameters was also analyzed.The results showed that the higher the fuel savings percentage,the longer the flight distance of formation flight,but the smaller the number of formation combinations that can be realized,which is limited by the aircraft performance.The following aircraft flying along the approximate actual flight trajectory can be benefited as well,and the optimal fuel-saving efficiency is related to the expected fuelsaving efficiency of formation flight.
基金the support from Harvard/MITthe support funded by the National Research Foundation(NRF),Prime Minister’s Office,Singapore,under its Campus for Research Excellence and Technological Enterprise(CREATE)program,Grant Number R-706-001-102-281the funding support from Harbin Institute of Technology,China,Grant Number FRFCU5710053121。
文摘We conceptualize bioresource upgrade for sustainable energy,environment,and biomedicine with a focus on circular economy,sustainability,and carbon neutrality using high availability and low utilization biomass(HALUB).We acme energy-efficient technologies for sustainable energy and material recovery and applications.The technologies of thermochemical conversion(TC),biochemical conversion(BC),electrochemical conversion(EC),and photochemical conversion(PTC)are summarized for HALUB.Microalgal biomass could contribute to a biofuel HHV of 35.72 MJ Kg^(-1)and total benefit of 749$/ton biomass via TC.Specific surface area of biochar reached 3000 m^(2)g^(-1)via pyrolytic carbonization of waste bean dregs.Lignocellulosic biomass can be effectively converted into bio-stimulants and biofertilizers via BC with a high conversion efficiency of more than 90%.Besides,lignocellulosic biomass can contribute to a current density of 672 mA m^(-2)via EC.Bioresource can be 100%selectively synthesized via electrocatalysis through EC and PTC.Machine learning,techno-economic analysis,and life cycle analysis are essential to various upgrading approaches of HALUB.Sustainable biomaterials,sustainable living materials and technologies for biomedical and multifunctional applications like nano-catalysis,microfluidic and micro/nanomotors beyond are also highlighted.New techniques and systems for the complete conversion and utilization of HALUB for new energy and materials are further discussed.
文摘Electric field distribution is an important parameter for nanostructure arrays in nanobiosensing appfications. It can influence the sensitivity and the resolution of nanobiosensors. We focus on the effect of media on the electric field distribution of a rhombic silver nanostructure array. The finite-difference time-domain algorithm- based numerical calculation method is used to monitor the electric field distribution of the silver nanostructures when the refractive index of the medium around the nanostructure array is changed. The calculated results show that tuning the refractive index of the medium around silver can have a considerable influence on the electric field distribution in the reflection and transmission directions. This effect can be used to increase the extinction efficiency and to improve the resolution of the spectra for nanobiosensing.
文摘The interface wave propagating along an imperfect interface between two piezoelectric half spaces is derived firstly. The wave equations based on the interface modeled, called ＂spring model＂, are presented. The micro-scale structures of the interface for connecting the spring constant with the interface micro-structures are examined. For some simple interface micro-structure, exact dynamic solution is available, and the spring constant is obtained by comparing solutions. For the complex micro structures, it remains as a challenge of micro-mechanics modeling to connect the ＂spring constant＂ and micro-structure.
文摘The fuel consumption of a ship has always been an important research topic,but nowadays its importance has even increased as it is directly related to a ship’s greenhouse gas(GHG)emissions,which is now tightly regulated.In this paper,such a dynamic model is presented.The ship’s resistance in calm water and propeller’s performance in open water are required as input.The hull efficiency is estimated empirically.The diesel engine is modelled by a first-order transfer function with a delayed response and its performance is calibrated with the data from the manufacturer’s catalogue.A governor is applied to maintain the pre-set engine’s rotational speed and to control the engine fuel rate.A slope limiter is employed to approximate the actual engine operation during engine transients.The default values can be obtained from the manufacturer engine load acceptance diagram.The developed model is implemented in MATLAB SIMULINK environment.After validation against third-party published results,the influence of using different types of governors on ship speed and fuel consumption is investigated.The model is also applied to simulate the fuel consumption of a ship during a typical acceleration manoeuvre and the scenario of a real ship encountering harsh weather conditions.
基金financial support from the Nanyang Environment and Water Research Institute (Core Fund), Nanyang Technological University, Singapore。
文摘Two-dimensional(2D) materials have exhibited great potential for replacing costly Pt for oxygen reduction reaction(ORR) because of their distinctive structural features and high pre-site activity.However,their performance is generally hindered by the limited density of active sites(e.g.,at the layer edges).Although they feature a high exposure of surface sites,these sites are typically inert for ORR.Herein,through density functional theory calculations,we propose a promising ORR catalyst candidate,a 2D TaTe_(2) nanosheet,which has an intrinsic high basal-plane activity.Both of the thermodynamic and kinetic processes are explored,which demonstrates that the basal-plane Te sites of the TaTe_(2) nanosheet have great potential for facilitating ORR.Specifically,we construct a microkinetic model of ORR proceeding on TaTe_(2),which unveils its dynamic intermediate coverage under different electrode potentials and identifies the dominating associative pathway.The theoretical half-wave potential of TaTe_(2) is predicted to be 0.87 V,which exceeds those of the well-established Pt(111) and Fe–N–C single-atom catalysts computed at the same level.This study not only presents the first 2D,non-Pt ORR catalyst candidate with an intrinsic basal-plane activity but also offers a rational methodology for unveiling the mechanism/activity of ORR and other electrochemical reactions.
文摘There is a pressing need in very small scale threedimensional(3 D) inkjet printing to control and reduce agglomeration,as agglomeration often leads to nozzle clogging.While agglomeration within ultraviolet ink has been studied,there has been,to our knowledge,no extensive studies conducted for surface agglomeration of the ink on nozzle's wall.This numerical study therefore focuses on investigating if surfactants can effectively control surface agglomeration during nanodroplet formation.Many-body dissipative particle dynamics is the numerical method of choice here.We found that small amount of surfactant of about 1 wt % is sufficient to effectively reduce ink deposition on the nozzle's wall.However,by using the properties of a commercially available surfactant,sodium dodecyl sulfate,it was found that the maximum reduction achieved by its addition is only 60%.Thus,further physical or chemical deagglomeration techniques are required,and we show that by considering these other techniques,reduction of surface agglomeration to nearly 92% can be achieved.Finally,we found that adding surfactants has the additional benefit of improving total kinetic energy of the ink compositions,lowering possibility of agglomerations within the ink.It also raises the nanodroplet velocity while reducing nanodroplet breakup time,which can help speed up the process of 3 D printing process.
