This work describes thermal decomposition behaviour of plastic bonded explosives(PBXs) based on mixture of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX) and 2,4,6-triamino-1,3,5-trinitrobenzene(TATB)with Viton A as poly...This work describes thermal decomposition behaviour of plastic bonded explosives(PBXs) based on mixture of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX) and 2,4,6-triamino-1,3,5-trinitrobenzene(TATB)with Viton A as polymer binder. Thermal decomposition of PBXs was undertaken by applying simultaneous thermal analysis(STA) and differential scanning calorimetry(DSC) to investigate influence of the HMX amount on thermal behavior and its kinetics. Thermogravimetric analysis(TGA) indicated that the thermal decomposition of PBXs based on mixture of HMX and TATB was occurred in a three-steps. The first step was mainly due to decomposition of HMX. The second step was ascribed due to decomposition of TATB, while the third step was occurred due to decomposition of the polymer matrices. The thermal decomposition % was increased with increasing HMX amount. The kinetics related to thermal decomposition were investigated under non-isothermal for a single heating rate measurement. The variation in the activation energy of PBXs based on mixture of HMX and TATB was observed with varying the HMX amount. The kinetics from the results of TGA data at various heating rates under non-isothermal conditions were also calculated by Flynn—Wall—Ozawa(FWO) and Kissinger-Akahira-Sunose(KAS)methods. The activation energies calculated by employing FWO method were very close to those obtained by KAS method. The mean activation energy calculated by FWO and KAS methods was also a good agreement with the activation energy obtained from single heating rate measurement in the first step decomposition.展开更多
Xylanase is a hemicellulase that can hydrolyses the complex polysaccharides.Hemicelluloses are main components of cell walls of cereal grains.Moreover,hemicelluloses are considered as potential sources of mono-and oli...Xylanase is a hemicellulase that can hydrolyses the complex polysaccharides.Hemicelluloses are main components of cell walls of cereal grains.Moreover,hemicelluloses are considered as potential sources of mono-and oligosaccharides.In this study,influence of xylanase on the physicochemical properties and sensory qualities of the whole wheat bread during storage was investigated.Studies of whole wheat bread on microstructure,texture,thermotics,Scanning Electron Microscopic(SEM),X-Ray Diffraction(XRD)were conducted at ambient temperature of 25 and 4◦C respectively.During storage at different temperatures,bread containing xylanase exhibited less firmness but larger volume with whiter crumb color and longer shelf life as compared to control bread.Results of firmness,enthalpy,Fourier Transformation Infra Red(FTIR)and X-Ray Diffraction(XRD)studies suggested a lower staling rate of bread containing xylanase as compared to control one.Bread containing xylanase showed a smoother surface and more uniform pore size than the control.Significant differences in microstructure of control and bread containing xylanase were observed which might be attributed due to the change in water starch gluten interaction.These differences were also found to be interrelated to the textural properties of bread.Better sensory features were achieved in bread containing xylanase.展开更多
Sub-10-nm bulk n-MOSFET （metal-oxide -semiconductor field effect transistor） direct source-to- drain tunneling current density using Wentzel- Krammers-Brillouin 0NKB） transmission tunneling theory has been simulate...Sub-10-nm bulk n-MOSFET （metal-oxide -semiconductor field effect transistor） direct source-to- drain tunneling current density using Wentzel- Krammers-Brillouin 0NKB） transmission tunneling theory has been simulated. The dependence of the source-to-drain tunneling current on channel length and barrier height is examined. Inversion layer quantization, band-gap narrowing, and drain induced barrier lowering effects have been included in the model. It has been observed that the leakage current density increases severely below 4 nm channel lengths, thus putting a limit to the scaling down of the MOSFETs. The results match closely with the numerical results already reported in literatures.展开更多
By using a suitable set of the surface energy coefficient, nuclear radius, and universal function, the original proximity potential 1977 is modified. The overestimate of the data by 4% reported in the literature is si...By using a suitable set of the surface energy coefficient, nuclear radius, and universal function, the original proximity potential 1977 is modified. The overestimate of the data by 4% reported in the literature is significantly reduced. Our modified proximity potential reproduces the experimental data nicely compared to its older versions.展开更多
A study was conducted on high-density young plantations of three native trees （Albizia lebbeck, Albizia. procera and Tectona grandis） and one native woody grass species （Dendrocalamus strictus） to examine their in...A study was conducted on high-density young plantations of three native trees （Albizia lebbeck, Albizia. procera and Tectona grandis） and one native woody grass species （Dendrocalamus strictus） to examine their influence on total nutrient concentrations of coal mine spoil during early phase of plantation establishment. Soil samples were analyzed for total organic carbon （SOC）, Kjeldahl nitrogen （TKN） and phosphorus （TP） at spoil depths of 0-10 and 10-20 cm under 4- and 5-year-old plantations of all species. A significant effect on concentrations of total SOC, TKN and TP were observed due to plantation age, species and soil depth. However, corresponding con- centrations （SOC, TKN and TP） were substantially lower at spoil profile of 10-20 cm. In comparison, plantation ofA. lebbeck showed greater SOC and nutrient concentrations followed by D. strictus, A. procera and T. grandis, respectively. Therefore, present study clearly indicates attributing qualities of plantation towards improving redeveloping soil of mine spoil varied with species.展开更多
We study the effect of pressure on electronic and thermoelectric properties of Mg_2Si using the density functional theory and Boltzmann transport equations. The variation of lattice constant, band gap, bulk modulus wi...We study the effect of pressure on electronic and thermoelectric properties of Mg_2Si using the density functional theory and Boltzmann transport equations. The variation of lattice constant, band gap, bulk modulus with pressure is also analyzed. Further, the thermoelectric properties（Seebeck coefficient, electrical conductivity, electronic thermal conductivity） have been studied as a function of temperature and pressure up to 1200 K. The results show that Mg_2Si is an n-type semiconductor with a band gap of 0.21 eV. The negative value of the Seebeck coefficient at all pressures indicates that the conduction is due to electrons. With the increase in pressure, the Seebeck coefficient decreases and electrical conductivity increases. It is also seen that, there is practically no effect of pressure on the electronic contribution of thermal conductivity.The paper describes the calculation of the lattice thermal conductivity and figure of merit of Mg_2Si at zero pressure. The maximum value of figure of merit is attained 1.83 × 10^（-3） at 1000 K. The obtained results are in good agreement with the available experimental and theoretical results.展开更多
Therapeutic agents used to treat glaucoma are designed to decrease the intra-ocular pressure (IOP) either by decreasing the aqueous humor production in the ciliary body and/or by enhancing the aqueous humor drainage f...Therapeutic agents used to treat glaucoma are designed to decrease the intra-ocular pressure (IOP) either by decreasing the aqueous humor production in the ciliary body and/or by enhancing the aqueous humor drainage from the eye. Oral carbonic an-hydrase inhibitors (CAIs) were the mainstay in the glaucoma therapy but of late, these agents have become less popular due展开更多
A simple analytical model has been developed to study quantum mechanical effects （QME） in a germanium substrate MOSFET （metal oxide semiconductor field effect transistor）, which includes gate oxide tunneling consi...A simple analytical model has been developed to study quantum mechanical effects （QME） in a germanium substrate MOSFET （metal oxide semiconductor field effect transistor）, which includes gate oxide tunneling considering the energy quantization effects in the substrate. Some alternate high dielectric constant materials to reduce the tunneling have also been studied. By comparing with the numerically reported results, the results match well with the existing reported work.展开更多
Diffusive dynamics of fluid forming layers of high and low density regions in a nanochannel has been investigated.Diffusion coefficient in direction parallel and perpendicular to the confining wall has been found to s...Diffusive dynamics of fluid forming layers of high and low density regions in a nanochannel has been investigated.Diffusion coefficient in direction parallel and perpendicular to the confining wall has been found to show behaviour which is not observed in micro channel or bulk systems.The behaviour of diffusion is found to be controlled by the width of layers formed in nanochannel due to wall and particle interactions.This is an important result as width of layers and hence flow of fluid inside nano pores/tube can be controlled by an external source.展开更多
An analytical model has been developed to study inversion layer quantization in the ultra thin oxide MOS （metal oxide semiconductor） structures using variation and triangular well approaches.Accurate modeling of the...An analytical model has been developed to study inversion layer quantization in the ultra thin oxide MOS （metal oxide semiconductor） structures using variation and triangular well approaches.Accurate modeling of the inversion charge density using the continuous surface potential equations has been done.No approximation has been taken to model the inversion layer quantization process.The results show that the variation approach describes inversion layer quantization process accurately as it matches well with the BSIM 5 （Berkeley short channel insulated gate field effect transistor model 5） results more closely compared with triangular well approach.展开更多
In 2018,the STAR collaboration collected data from^(96)_(44)Ru+^(96)_(44)Ru and^(96)_(40)Zr+^(96)_(40)Zr at√^(S)NN=200 Ge V to search for the presence of the chiral magnetic effect in collisions of nuclei.The isobar ...In 2018,the STAR collaboration collected data from^(96)_(44)Ru+^(96)_(44)Ru and^(96)_(40)Zr+^(96)_(40)Zr at√^(S)NN=200 Ge V to search for the presence of the chiral magnetic effect in collisions of nuclei.The isobar collision species alternated frequently between 9644 Ru+^(96)_(44)Ru and^(96)_(40)Zr+^(96)_(40)Zr.In order to conduct blind analyses of studies related to the chiral magnetic effect in these isobar data,STAR developed a three-step blind analysis procedure.Analysts are initially provided a"reference sample"of data,comprised of a mix of events from the two species,the order of which respects time-dependent changes in run conditions.After tuning analysis codes and performing time-dependent quality assurance on the reference sample,analysts are provided a species-blind sample suitable for calculating efficiencies and corrections for individual≈30-min data-taking runs.For this sample,species-specific information is disguised,but individual output files contain data from a single isobar species.Only run-by-run corrections and code alteration subsequent to these corrections are allowed at this stage.Following these modifications,the"frozen"code is passed over the fully un-blind data,completing the blind analysis.As a check of the feasibility of the blind analysis procedure,analysts completed a"mock data challenge,"analyzing data from Au+Au collisions at√^(S)NN=27 Ge V,collected in 2018.The Au+Au data were prepared in the same manner intended for the isobar blind data.The details of the blind analysis procedure and results from the mock data challenge are presented.展开更多
基金DRDO(TBR-1251)for funding and awarding the Project
文摘This work describes thermal decomposition behaviour of plastic bonded explosives(PBXs) based on mixture of 1,3,5,7-tetranitro-1,3,5,7-tetrazocane(HMX) and 2,4,6-triamino-1,3,5-trinitrobenzene(TATB)with Viton A as polymer binder. Thermal decomposition of PBXs was undertaken by applying simultaneous thermal analysis(STA) and differential scanning calorimetry(DSC) to investigate influence of the HMX amount on thermal behavior and its kinetics. Thermogravimetric analysis(TGA) indicated that the thermal decomposition of PBXs based on mixture of HMX and TATB was occurred in a three-steps. The first step was mainly due to decomposition of HMX. The second step was ascribed due to decomposition of TATB, while the third step was occurred due to decomposition of the polymer matrices. The thermal decomposition % was increased with increasing HMX amount. The kinetics related to thermal decomposition were investigated under non-isothermal for a single heating rate measurement. The variation in the activation energy of PBXs based on mixture of HMX and TATB was observed with varying the HMX amount. The kinetics from the results of TGA data at various heating rates under non-isothermal conditions were also calculated by Flynn—Wall—Ozawa(FWO) and Kissinger-Akahira-Sunose(KAS)methods. The activation energies calculated by employing FWO method were very close to those obtained by KAS method. The mean activation energy calculated by FWO and KAS methods was also a good agreement with the activation energy obtained from single heating rate measurement in the first step decomposition.
文摘Xylanase is a hemicellulase that can hydrolyses the complex polysaccharides.Hemicelluloses are main components of cell walls of cereal grains.Moreover,hemicelluloses are considered as potential sources of mono-and oligosaccharides.In this study,influence of xylanase on the physicochemical properties and sensory qualities of the whole wheat bread during storage was investigated.Studies of whole wheat bread on microstructure,texture,thermotics,Scanning Electron Microscopic(SEM),X-Ray Diffraction(XRD)were conducted at ambient temperature of 25 and 4◦C respectively.During storage at different temperatures,bread containing xylanase exhibited less firmness but larger volume with whiter crumb color and longer shelf life as compared to control bread.Results of firmness,enthalpy,Fourier Transformation Infra Red(FTIR)and X-Ray Diffraction(XRD)studies suggested a lower staling rate of bread containing xylanase as compared to control one.Bread containing xylanase showed a smoother surface and more uniform pore size than the control.Significant differences in microstructure of control and bread containing xylanase were observed which might be attributed due to the change in water starch gluten interaction.These differences were also found to be interrelated to the textural properties of bread.Better sensory features were achieved in bread containing xylanase.
文摘Sub-10-nm bulk n-MOSFET （metal-oxide -semiconductor field effect transistor） direct source-to- drain tunneling current density using Wentzel- Krammers-Brillouin 0NKB） transmission tunneling theory has been simulated. The dependence of the source-to-drain tunneling current on channel length and barrier height is examined. Inversion layer quantization, band-gap narrowing, and drain induced barrier lowering effects have been included in the model. It has been observed that the leakage current density increases severely below 4 nm channel lengths, thus putting a limit to the scaling down of the MOSFETs. The results match closely with the numerical results already reported in literatures.
文摘By using a suitable set of the surface energy coefficient, nuclear radius, and universal function, the original proximity potential 1977 is modified. The overestimate of the data by 4% reported in the literature is significantly reduced. Our modified proximity potential reproduces the experimental data nicely compared to its older versions.
文摘A study was conducted on high-density young plantations of three native trees （Albizia lebbeck, Albizia. procera and Tectona grandis） and one native woody grass species （Dendrocalamus strictus） to examine their influence on total nutrient concentrations of coal mine spoil during early phase of plantation establishment. Soil samples were analyzed for total organic carbon （SOC）, Kjeldahl nitrogen （TKN） and phosphorus （TP） at spoil depths of 0-10 and 10-20 cm under 4- and 5-year-old plantations of all species. A significant effect on concentrations of total SOC, TKN and TP were observed due to plantation age, species and soil depth. However, corresponding con- centrations （SOC, TKN and TP） were substantially lower at spoil profile of 10-20 cm. In comparison, plantation ofA. lebbeck showed greater SOC and nutrient concentrations followed by D. strictus, A. procera and T. grandis, respectively. Therefore, present study clearly indicates attributing qualities of plantation towards improving redeveloping soil of mine spoil varied with species.
基金Project supported by the Council of Scientific&Industrial Research(CSIR),India
文摘We study the effect of pressure on electronic and thermoelectric properties of Mg_2Si using the density functional theory and Boltzmann transport equations. The variation of lattice constant, band gap, bulk modulus with pressure is also analyzed. Further, the thermoelectric properties（Seebeck coefficient, electrical conductivity, electronic thermal conductivity） have been studied as a function of temperature and pressure up to 1200 K. The results show that Mg_2Si is an n-type semiconductor with a band gap of 0.21 eV. The negative value of the Seebeck coefficient at all pressures indicates that the conduction is due to electrons. With the increase in pressure, the Seebeck coefficient decreases and electrical conductivity increases. It is also seen that, there is practically no effect of pressure on the electronic contribution of thermal conductivity.The paper describes the calculation of the lattice thermal conductivity and figure of merit of Mg_2Si at zero pressure. The maximum value of figure of merit is attained 1.83 × 10^（-3） at 1000 K. The obtained results are in good agreement with the available experimental and theoretical results.
文摘Therapeutic agents used to treat glaucoma are designed to decrease the intra-ocular pressure (IOP) either by decreasing the aqueous humor production in the ciliary body and/or by enhancing the aqueous humor drainage from the eye. Oral carbonic an-hydrase inhibitors (CAIs) were the mainstay in the glaucoma therapy but of late, these agents have become less popular due
文摘A simple analytical model has been developed to study quantum mechanical effects （QME） in a germanium substrate MOSFET （metal oxide semiconductor field effect transistor）, which includes gate oxide tunneling considering the energy quantization effects in the substrate. Some alternate high dielectric constant materials to reduce the tunneling have also been studied. By comparing with the numerically reported results, the results match well with the existing reported work.
文摘Diffusive dynamics of fluid forming layers of high and low density regions in a nanochannel has been investigated.Diffusion coefficient in direction parallel and perpendicular to the confining wall has been found to show behaviour which is not observed in micro channel or bulk systems.The behaviour of diffusion is found to be controlled by the width of layers formed in nanochannel due to wall and particle interactions.This is an important result as width of layers and hence flow of fluid inside nano pores/tube can be controlled by an external source.
文摘An analytical model has been developed to study inversion layer quantization in the ultra thin oxide MOS （metal oxide semiconductor） structures using variation and triangular well approaches.Accurate modeling of the inversion charge density using the continuous surface potential equations has been done.No approximation has been taken to model the inversion layer quantization process.The results show that the variation approach describes inversion layer quantization process accurately as it matches well with the BSIM 5 （Berkeley short channel insulated gate field effect transistor model 5） results more closely compared with triangular well approach.
文摘In 2018,the STAR collaboration collected data from^(96)_(44)Ru+^(96)_(44)Ru and^(96)_(40)Zr+^(96)_(40)Zr at√^(S)NN=200 Ge V to search for the presence of the chiral magnetic effect in collisions of nuclei.The isobar collision species alternated frequently between 9644 Ru+^(96)_(44)Ru and^(96)_(40)Zr+^(96)_(40)Zr.In order to conduct blind analyses of studies related to the chiral magnetic effect in these isobar data,STAR developed a three-step blind analysis procedure.Analysts are initially provided a"reference sample"of data,comprised of a mix of events from the two species,the order of which respects time-dependent changes in run conditions.After tuning analysis codes and performing time-dependent quality assurance on the reference sample,analysts are provided a species-blind sample suitable for calculating efficiencies and corrections for individual≈30-min data-taking runs.For this sample,species-specific information is disguised,but individual output files contain data from a single isobar species.Only run-by-run corrections and code alteration subsequent to these corrections are allowed at this stage.Following these modifications,the"frozen"code is passed over the fully un-blind data,completing the blind analysis.As a check of the feasibility of the blind analysis procedure,analysts completed a"mock data challenge,"analyzing data from Au+Au collisions at√^(S)NN=27 Ge V,collected in 2018.The Au+Au data were prepared in the same manner intended for the isobar blind data.The details of the blind analysis procedure and results from the mock data challenge are presented.
