NOx storage and reduction(NSR)technology has been regarded as one of the most promising strategies for the removal of nitric oxides(NOx)from lean-burn engines,and the potential of the plasma catalysis method for NOx r...NOx storage and reduction(NSR)technology has been regarded as one of the most promising strategies for the removal of nitric oxides(NOx)from lean-burn engines,and the potential of the plasma catalysis method for NOx reduction has been confirmed in the past few decades.This work reports the NSR of nitric oxide(NO)by combining non-thermal plasma(NTP)and Co/Pt/Ba/γ-Al2O3(Co/PBA)catalyst using methane as a reductant.The experimental results reveal that the NOx conversion of NSR assisted by NTP is notably enhanced compared to the catalytic efficiency obtained from NSR in the range of 150°C–350°C,and NOx conversion of the 8%Co/PBA catalyst reaches 96.8%at 350°C.Oxygen(O_(2))has a significant effect on the removal of NOx,and the NOx conversion increases firstly and then decreases when the O_(2)concentration ranges from 2%to 10%.Water vapor reduces the NOx storage capacity of Co/PBA catalysts on account of the competition for adsorption sites on the surface of Co/PBA catalysts.There is a negative correlation between sulfur dioxide(SO_(2))and NOx conversion in the NTP system,and the 8%Co/PBA catalyst exhibits higher NOx conversion compared to other catalysts,which shows that Co has a certain SO_(2)resistance.展开更多
The presented work reports the selective catalytic reduction(SCR)of NO_(x) assisted by dielectric barrier discharge plasma via simulating marine diesel engine exhaust,and the experimental results demonstrate that the ...The presented work reports the selective catalytic reduction(SCR)of NO_(x) assisted by dielectric barrier discharge plasma via simulating marine diesel engine exhaust,and the experimental results demonstrate that the low-temperature activity of NH_(3)-SCR assisted by non-thermal plasma is enhanced significantly,particularly in the presence of a C_(3)H_(6) additive.Simultaneously,CeMnZrO_(x)@TiO_(2) exhibits strong tolerance to SO_(2) poisoning and superior catalytic stability.It is worthwhile to explore a new approach to remove NO_(x) from marine diesel engine exhaust,which is of vital significance for both academic research and practical applications.展开更多
基金by the National Engineering Laboratory for Mobile Source Emission Control Technology(No.NELMS2019A13)the National Key Research and Development Project of China(No.2019YFC1805505)+2 种基金the Shanxi Province Bidding Project(No.20191101007)the Major Science and Technology Projects of Shanxi Province(No.20181102017)State Key Laboratory of Organic Geochemistry(No.SKLOG-201909)。
文摘NOx storage and reduction(NSR)technology has been regarded as one of the most promising strategies for the removal of nitric oxides(NOx)from lean-burn engines,and the potential of the plasma catalysis method for NOx reduction has been confirmed in the past few decades.This work reports the NSR of nitric oxide(NO)by combining non-thermal plasma(NTP)and Co/Pt/Ba/γ-Al2O3(Co/PBA)catalyst using methane as a reductant.The experimental results reveal that the NOx conversion of NSR assisted by NTP is notably enhanced compared to the catalytic efficiency obtained from NSR in the range of 150°C–350°C,and NOx conversion of the 8%Co/PBA catalyst reaches 96.8%at 350°C.Oxygen(O_(2))has a significant effect on the removal of NOx,and the NOx conversion increases firstly and then decreases when the O_(2)concentration ranges from 2%to 10%.Water vapor reduces the NOx storage capacity of Co/PBA catalysts on account of the competition for adsorption sites on the surface of Co/PBA catalysts.There is a negative correlation between sulfur dioxide(SO_(2))and NOx conversion in the NTP system,and the 8%Co/PBA catalyst exhibits higher NOx conversion compared to other catalysts,which shows that Co has a certain SO_(2)resistance.
基金supported by National Key Research and Development Project of China(No.2019YFC1805503)National Engineering Laboratory for Mobile Source Emission Control Technology(No.NELMS2019A13)+1 种基金the Open Project Program of the State Key Laboratory of Petroleum Pollution Control(No.PPC2019013)Major Science and Technology Projects of Shanxi Province(No.20181102017)。
文摘The presented work reports the selective catalytic reduction(SCR)of NO_(x) assisted by dielectric barrier discharge plasma via simulating marine diesel engine exhaust,and the experimental results demonstrate that the low-temperature activity of NH_(3)-SCR assisted by non-thermal plasma is enhanced significantly,particularly in the presence of a C_(3)H_(6) additive.Simultaneously,CeMnZrO_(x)@TiO_(2) exhibits strong tolerance to SO_(2) poisoning and superior catalytic stability.It is worthwhile to explore a new approach to remove NO_(x) from marine diesel engine exhaust,which is of vital significance for both academic research and practical applications.
