First-principles calculations based on the density-functional theory were employed to study the crystal structure of vanadium phosphide compounds,such as V3P,V2P,VP,VP2 and VP4. Cohesive energy of five types of vanadi...First-principles calculations based on the density-functional theory were employed to study the crystal structure of vanadium phosphide compounds,such as V3P,V2P,VP,VP2 and VP4. Cohesive energy of five types of vanadium phosphide compounds was calculated to assess their structural stability. The charge density distribution and densities of states of vanadium phosphides were discussed to study further their electronic structures. The results show that the structure of metal-rich compounds is considerably more stable than the phosphorus-rich compositions,and covalent bond exists between the V and P atoms of V3P,V2P,VP,VP2 and VP4.展开更多
The effects of stress,ageing time and ageing temperature on creep behavior of poly(methyl methacrylate) were studied.After annealing above its glass transition temperature for a period of time to eliminate the stress ...The effects of stress,ageing time and ageing temperature on creep behavior of poly(methyl methacrylate) were studied.After annealing above its glass transition temperature for a period of time to eliminate the stress and thermal history,the specimens were quenched and aged at various ageing temperatures for different ageing time,and then the short-term creep tests under different stress levels were carried out at room temperature.The creep strains were modeled by means of time-ageing time equivalence and time-stress equivalence,and the master creep curves were constructed via ageing time shift factors and stress shift factors.The results indicate that the creep rate increases with stress,while decreases with ageing time,and the ageing temperature history obviously affects the creep rate.For linear viscoelastic material,the ageing shift rate is independent on imposed stress,while for nonlinear viscoelastic material,the ageing shift rate decreases with increasing stress.The unified master creep curve up to 540 d at reference state was constructed by shifting the creep curves horizontally along the logarithmic time axis to overlap each other.It is demonstrated that the time-stress equivalence,united with the time-ageing time equivalence,provides an effective accelerated characterization technique in the laboratory to evaluate the long-term creep behavior of physical ageing polymers.展开更多
The effect of strain rate on fracture behavior of poly(methyl methacrylate) was investigated.The uniaxial tensile rupture tests for the poly(methyl methacrylate) samples were carried out at different strain rates at a...The effect of strain rate on fracture behavior of poly(methyl methacrylate) was investigated.The uniaxial tensile rupture tests for the poly(methyl methacrylate) samples were carried out at different strain rates at ambient temperature.It is found that the elastic modulus of the material increases with increasing strain rate,while the elongation is reversal with strain rate.Simultaneously,there exists a critical strain rate within which the stress-strain curves overlap one another,and beyond which the curves depart from each other.The amount of energy added to the system due to work done by the imposed load was calculated,and the strain energy stored in the material at each strain rate was calculated by the current stress integral with respect to strain.The complementary strain energy,which is the difference between the work and the strain energy,was obtained and was considered to supply the surface energy to create a new crack surface in the polymeric material.It is found that the work done by the imposed load,which is needed for the fracture of poly(methyl methacrylate) sample,decreases with increasing strain rate,and the strain energy decreases with strain rate as well,which demonstrates that the polymeric material at high strain rate is easier to fracture than that at low strain rate.As the strain rate increases,the fracture mode changes from ductile,semi-ductile to brittle mode.The complementary strain energy almost sustains a constant at any strain rate.The density of surface energy,which characterizes the energy per unit area needed for creating crack surface,is a strain rate-independent material constant.展开更多
基金Project(20871101)supported by the National Natural Science Foundation of ChinaProject(09C945)supported by the Scientific Research Fund of Hunan Provincial Education Department,China
文摘First-principles calculations based on the density-functional theory were employed to study the crystal structure of vanadium phosphide compounds,such as V3P,V2P,VP,VP2 and VP4. Cohesive energy of five types of vanadium phosphide compounds was calculated to assess their structural stability. The charge density distribution and densities of states of vanadium phosphides were discussed to study further their electronic structures. The results show that the structure of metal-rich compounds is considerably more stable than the phosphorus-rich compositions,and covalent bond exists between the V and P atoms of V3P,V2P,VP,VP2 and VP4.
基金Projects(10772156, 10672136) supported by the National Natural Science Foundation of ChinaProject(05C100) supported by the Scientific Research Fund of Education Department of Hunan Province,China
文摘The effects of stress,ageing time and ageing temperature on creep behavior of poly(methyl methacrylate) were studied.After annealing above its glass transition temperature for a period of time to eliminate the stress and thermal history,the specimens were quenched and aged at various ageing temperatures for different ageing time,and then the short-term creep tests under different stress levels were carried out at room temperature.The creep strains were modeled by means of time-ageing time equivalence and time-stress equivalence,and the master creep curves were constructed via ageing time shift factors and stress shift factors.The results indicate that the creep rate increases with stress,while decreases with ageing time,and the ageing temperature history obviously affects the creep rate.For linear viscoelastic material,the ageing shift rate is independent on imposed stress,while for nonlinear viscoelastic material,the ageing shift rate decreases with increasing stress.The unified master creep curve up to 540 d at reference state was constructed by shifting the creep curves horizontally along the logarithmic time axis to overlap each other.It is demonstrated that the time-stress equivalence,united with the time-ageing time equivalence,provides an effective accelerated characterization technique in the laboratory to evaluate the long-term creep behavior of physical ageing polymers.
基金Projects(10772156,10672136) supported by the National Natural Science Foundation of China
文摘The effect of strain rate on fracture behavior of poly(methyl methacrylate) was investigated.The uniaxial tensile rupture tests for the poly(methyl methacrylate) samples were carried out at different strain rates at ambient temperature.It is found that the elastic modulus of the material increases with increasing strain rate,while the elongation is reversal with strain rate.Simultaneously,there exists a critical strain rate within which the stress-strain curves overlap one another,and beyond which the curves depart from each other.The amount of energy added to the system due to work done by the imposed load was calculated,and the strain energy stored in the material at each strain rate was calculated by the current stress integral with respect to strain.The complementary strain energy,which is the difference between the work and the strain energy,was obtained and was considered to supply the surface energy to create a new crack surface in the polymeric material.It is found that the work done by the imposed load,which is needed for the fracture of poly(methyl methacrylate) sample,decreases with increasing strain rate,and the strain energy decreases with strain rate as well,which demonstrates that the polymeric material at high strain rate is easier to fracture than that at low strain rate.As the strain rate increases,the fracture mode changes from ductile,semi-ductile to brittle mode.The complementary strain energy almost sustains a constant at any strain rate.The density of surface energy,which characterizes the energy per unit area needed for creating crack surface,is a strain rate-independent material constant.
基金Project(2018RS3091) supported by the Hunan Innovation Team,ChinaProjects(52202308, 12105097) supported by the National Natural Science Foundation of ChinaProject(2021RC2092) supported by the Science and Technology Innovation Program of Hunan Province,China。
基金Project(SKL-SPM-202003) supported by the State Key Laboratory of Advanced Technologies for Comprehensive Utilization of Platinum Metals,ChinaProject(1920001004360) supported by the Foshan Science and Technology Innovation Program,China。
