Catalytic oxidation represents a pivotal technology for the valorization of light hydrocarbons,where oxidative dehydrogenation(ODH)and epoxidation reactions using molecular oxygen have garnered substantial interest ow...Catalytic oxidation represents a pivotal technology for the valorization of light hydrocarbons,where oxidative dehydrogenation(ODH)and epoxidation reactions using molecular oxygen have garnered substantial interest owing to their high atom economy and environmental friendliness.This review systematically summarizes recent advances in the oxidative dehydrogenation of light alkanes(ethane,propane)and the aerobic epoxidation of light olefins(ethylene,propylene).In terms of rational catalyst design,this review elaborates on performance regulation strategies for metal oxide catalysts such as MoVNbTeO_(x)mixed oxides,NiO-based,and V-based systems,as well as carbon/boron-based non-metal catalysts in alkane oxidative dehydrogenation,along with silver-based and copper-based catalysts in alkene epoxidation.These strategies include regulating the oxidation state of active sites,strong metal-support interactions,particle size and crystal facet engineering,and promoter modification.At the mechanistic level,combining density functional theory calculations with in situ characterization techniques,this review delves into the C-H bond activation and alkene desorption pathways in oxidative dehydrogenation,along with the oxygen insertion routes and competing side reactions in epoxidation.Special attention is given to the dynamic evolution of electrophilic and nucleophilic oxygen species and their decisive role in reaction selectivity.Finally,the review outlines persistent challenges in the field,including suppressing over-oxidation and overcoming the trade-off between conversion and selectivity and proposes future research directions such as the precise design of active centers,development of inherently safer processes,and in-depth analysis of complex reaction networks,aiming to support the green transition of the chemical industry.展开更多
In the present study,the mechanical and ballistic properties of friction stir welded(FSW)aluminum alloy(AA5754)samples were investigated,both untreated and cryogenically treated,when impacted by a 7.62 mm armour-pierc...In the present study,the mechanical and ballistic properties of friction stir welded(FSW)aluminum alloy(AA5754)samples were investigated,both untreated and cryogenically treated,when impacted by a 7.62 mm armour-piercing(AP)bullet at an impact velocity of 682±20 m/s.The FSW technique was used to prepare the welded samples for AA5754,with an axial force of 7 kN,a feed rate of 20 mm/min,and a speed of 1200 rpm.The cryogenic treatments performed after welding,including deep cryogenic treatment(DCT)at196℃ and shallow cryogenic treatment(SCT)at80℃,for 6 and 72 h,respectively.The microstructure and mechanical characteristics of cryogenically treated and untreated joints were examined.The cryogenic treatment refined the grain size(1.05 μm)and enhanced the microhardness(93 Hv).Moreover,DCT-FSW significantly improved the tensile strength(13.93%)and impact strength(8.45%)compared to untreated FSW sample.Additionally,in untreated FSW samples,the fracture behaviour varied:the impact fracture mode primarily exhibited ductile failure,while the tensile fracture exhibited a mixed fracture mode.In contrast,the tensile and impact fracture modes of the DCT-FSWwere dominated by a ductile failure mode.The DCT-FSW target demonstrated a lower depth of penetration(DOP)of 31 mm compared to the SCT-FSWand untreated FSW targets.Post-ballistic SEM analysis in the crater region of all three zones revealed the formation of frictional grooves,small cracks,and adiabatic shear bands(ASBs).展开更多
Research and development of green oxidizers and green fuels as a possible replacement for ammonium perchlorate(NH4ClO4,AP) and hydrazine(N2H4) respectively has been increased considerably in the recent years.AP and hy...Research and development of green oxidizers and green fuels as a possible replacement for ammonium perchlorate(NH4ClO4,AP) and hydrazine(N2H4) respectively has been increased considerably in the recent years.AP and hydrazine are the oxidizer and fuel entities,and used in solid and liquid rocket motors respectively.AP is highly toxic and led to adverse health effects,while hydrazine is carcinogenic in nature.AP is in use from the last several decades for rocket and space shuttle propulsion,while hydrazine is used in upper stage liquid propelled rocket motors.It’s a tough task to replace AP with the currently available green oxidizers;since their ballistic properties are weaker when compared to AP and also they can’t be successfully deployed in a solid rocket motor at present Some important available solid green oxidizers are ammonium nitrate(AN),ammonium dinitramide(ADN),hydroxyl ammonium nitrate(HAN),and hydrazinium nitroformate(HNF).However,AN is one of the cheap and readily available oxidizer,and has great potential to use in solid/liquid rocket motors.Tremendous progress has been envisaged till now,and more progress will be there in the coming future over the development of AN based green energetic materials(GEM’s).A concise overview has been presented over the development of phase stabilized ammonium nitrate(PSAN) and AN/KDN based green oxidizers in the present review paper.展开更多
Corrosion behaviors of P110 and N80 tubular steels in CO_(2) gas phase and supercritical(S-CO_(2))phase in a saturated water vapor environment were explored in corrosion weight loss experiments by SEM,EDS,XRD,XPS and ...Corrosion behaviors of P110 and N80 tubular steels in CO_(2) gas phase and supercritical(S-CO_(2))phase in a saturated water vapor environment were explored in corrosion weight loss experiments by SEM,EDS,XRD,XPS and cross-section analysis techniques.With the increase in CO_(2) partial pressure,the average corrosion rate increased first and then decreased.The average corrosion rate reached the maximum value under the near-critical pressure.When CO_(2) partial pressure further increased to be above the critical pressure,the average corrosion rate gradually decreased and local aggregation of molecules was weakened.展开更多
To simulate explosion fragments, it is necessary to predict many variables such as fragment velocity, size distribution and projection angle. For active protection systems these predictions need to be made very quickl...To simulate explosion fragments, it is necessary to predict many variables such as fragment velocity, size distribution and projection angle. For active protection systems these predictions need to be made very quickly, before the weapon hits the target. Fast predictions also need to be made in real time simulations when the impact of many different computer models need to be assessed. The research presented in this paper focuses on creating a fast and accurate estimate of one of these variables - the initial fragment velocity. The Gurney equation was the first equation to calculate initial fragment velocity. This equation, sometimes with modifications, is still used today where finite element analysis or complex mathematical approaches are considered too computationally expensive. This paper enhances and improves Breech’s two-dimensional Gurney equation using available empirical data and the principals of conservation of momentum and energy. The results are computationally quick, providing improved accuracy for estimating initial fragment velocity. This will allow the developed model to be available for real-time simulation and fast computation, with improved accuracy when compared to existing approaches.展开更多
Explosive cladding of Al 5052–Al 1100 plate, interfaced with a stainless steel wire mesh interlayer, is attempted. Loading ratio and standoff distance were varied. An increase in loading ratio (R) and standoff distan...Explosive cladding of Al 5052–Al 1100 plate, interfaced with a stainless steel wire mesh interlayer, is attempted. Loading ratio and standoff distance were varied. An increase in loading ratio (R) and standoff distance (S) enhances the plate velocity (Vp), dynamic bend angle (β) and pressure developed (P). The interface morphology of the explosive clads confirms strong metallurgical bond between the wire mesh and aluminum plates. Further, a smooth transition from straight to undulating interlayered topography is witnessed. The introduction of a wire mesh, as interlayer, leads to an improvement in mechanical strength with a slender reduction in overall corrosion resistance of the “explosive clads”.展开更多
This paper reports a novel micro-blast driven manufacturing process for micro-forming of Aluminum foils. The micro-blast is realized by using a nanoenergetic material system comprising of Bi_2O_3 microrods and aluminu...This paper reports a novel micro-blast driven manufacturing process for micro-forming of Aluminum foils. The micro-blast is realized by using a nanoenergetic material system comprising of Bi_2O_3 microrods and aluminum particles. There is an enhanced need of forming of thin aluminum foil structures in small regions from point of view of drug packaging etc. The process developed caters to this need by using a single shot forming process using a micro-blast source. The micro-blast that is generated from an energetic composite system is made highly tunable by modulating the peak pressure generated through the blasting process and their impact in micro-forming of thin aluminum foils is observed through parametric studies. The engineering challenge involved in these experiments is to tune the blast pressure properties in order to address the forming of thin metal sheets with limiting boundary values as defined by the failure criteria. A variety of characterization techniques related to a thorough analysis of the synthesized material viz. X-ray diffraction(XRD), Scanning Electron Microscopy(SEM) etc, are used to tune the functional properties like gauge blast pressure etc, of material system. We have found a material system that can generate a maximum peak pressure of 73.8 MPa with pressurization rate of 2460 GPas^(-1) and that is able to accomplish micro-forming on thin metal foils(around 0.3 mm thickness). Experimental investigations demonstrate that tunabilty aspect of the energetic composites when exercised can enable variant processes such as embossing, coining, drilling etc. which may be of significant utility to drug packaging industries. A proper mathematical modeling of the forming process and critical process parameters therein have also been detailed.展开更多
The study focused on investigating the effect of Deep Cryogenic Treatment(DCT)on the mechanical and ballistic properties of AA7075-T6 aluminum alloy.The microstructure,microhardness,tensile strength,and impact strengt...The study focused on investigating the effect of Deep Cryogenic Treatment(DCT)on the mechanical and ballistic properties of AA7075-T6 aluminum alloy.The microstructure,microhardness,tensile strength,and impact strength of the Base Material(BM)and DCT-treated 7075 samples were analyzed through metallographic analysis and mechanical tests.The microstructure of the DCT-treated 7075 samples revealed fine grains and a distribution of secondary phase particles.The tensile strength,impact strength,and microhardness of DCT-treated samples increased by 7.41%,4%,and 9.68%,respectively,compared to the BM samples.The fractography analysis of the tensile samples showed cleavage facets,microvoids,and dimples in both the samples.The ballistic behavior of the BM and DCT target plates were studied by impacting hard steel core projectiles at a velocity of 750±10 m/s.The target plates failed due to petaling and ductile hole enlargement,and the depth of penetration(DOP)of the DCT target was less than that of the BM target,indicating a higher ballistic resistance.The post-ballistic microstructure examination of the target plates showed the formation of an Adiabatic Shear Band(ASB)without any cracks.It was concluded that the DCT treatment improved the mechanical and ballistic properties of the aluminum alloy due to grain refinement and high dislocation density.展开更多
The high entropy alloys(HEAs)are the newly developed high-performance materials that have gained significant importance in defence,nuclear and aerospace sector due to their superior mechanical properties,heat resistan...The high entropy alloys(HEAs)are the newly developed high-performance materials that have gained significant importance in defence,nuclear and aerospace sector due to their superior mechanical properties,heat resistance,high temperature strength and corrosion resistance.These alloys are manufactured by the equal mixing or larger proportions of five or more alloying elements.HEAs exhibit superior mechanical performance compared to traditional engineering alloys because of the extensive alloying composition and higher entropy of mixing.Solid state welding(SSW)techniques such as friction stir welding(FSW),rotary friction welding(RFW),diffusion bonding(DB)and explosive welding(EW)have been efficiently deployed for improving the microstructural integrity and mechanical properties of welded HEA joints.The HEA interlayers revealed greater potential in supressing the formation of deleterious intermetallic phases and maximizing the mechanical properties of HEAs joints.The similar and dissimilar joining of HEAs has been manifested to be viable for HEA systems which further expands their industrial applications.Thus,the main objective of this review paper is to present a critical review of current state of research,challenges and opportunities and main directions in SSW of HEAs mainly CoCrFeNiMn and Al_xCoCrFeNi alloys.The state of the art of problems,progress and future outlook in SSW of HEAs are critically reviewed by considering the formation of phases,microstructural evolution and mechanical properties of HEAs joints.展开更多
The use of asbestos material is being avoided to manufacture the brake pads as it is harmful and toxic in nature. Further it leads to various health issues like asbestosis, mesothelioma and lung cancers. These brake p...The use of asbestos material is being avoided to manufacture the brake pads as it is harmful and toxic in nature. Further it leads to various health issues like asbestosis, mesothelioma and lung cancers. These brake pads can be replaced by natural fibers like Palm kernel (0-50%), Nile roses (0-15%) and Wheat (0-10%) with additives like aluminum oxide (5%-20%) and graphite powder (10%-35%). Phenolic resin of 35% is utilized as a binder. Particulated Nile roses are used to increase the friction coefficient and wheat powder is used to reduce the wear rate. Aluminum oxide and graphite are abrasive in nature. This helps to make brake pads with high friction co-efficient and less wear rate with low noise pollution. The wear of the proposed composites have been investigated at different speeds. Various tests like wear on pin-ondisc apparatus, hardness on the Rockwell hardness apparatus and oil absorption test have been conducted. Phenolic resin produces good bonding nature to fiber. Thus, Fibers found to have performed palatably among all commercial brake pads. The objective of the research indicates that Palm kernal shell could be a conceivable alternative for asbestos in friction coating materials.展开更多
Variations between earthquakes result in many factors that influence post-earthquake building damage(e.g.,ground motion parameters,building structure,site information,and quality of construction).Consequently,it is ne...Variations between earthquakes result in many factors that influence post-earthquake building damage(e.g.,ground motion parameters,building structure,site information,and quality of construction).Consequently,it is necessary to develop an appropriate building damage-rate estimation model.The building damage survey data were recorded and constructed into files by the Architecture and Building Research Institute(ABRI),Taiwan for the 1999 Chi-Chi earthquake in the Nantou region as a basis for developing a building damage rate estimation model by applying fuzzy theory to express the fragility curves of buildings as a membership function.Empirical verification was performed using post-earthquake building damage data in the Taichung city that suffered relatively severe damage.Results indicate that fuzzy theory can be applied to predict building damage rates and that the estimated results are similar to actual disaster figures.Prediction of disaster damage using building damage rates can provide a reference for immediate disaster response during earthquakes and for regular disaster prevention and rescue planning.展开更多
The cellulosic bast fibers are recognized as a justifiable and biodegradable substitute for producing moderate strength polymer composite materials because of their characteristics of renewability,ecofriendliness,and ...The cellulosic bast fibers are recognized as a justifiable and biodegradable substitute for producing moderate strength polymer composite materials because of their characteristics of renewability,ecofriendliness,and higher specific strength.Hence the aim of this research work is to fabricate Himalayan bast fibers(Nettle fiber(NF)/bauhinia vahlii fiber(BF)) based mono/hybrid epoxy composites at varying weight percentage of 2-6 wt% and evaluate the physical(void fraction and water absorption),mechanical(tensile strength,flexural strength,hardness) and sliding wear properties of as-fabricated composites.The 6 wt% NBF reinforced composites exhibited higher mechanical properties as compared to NF and BF composites with tensile strength of 34.04 MPa,flexural strength of 42.45 MPa,and hardness of 37.01 Hv respectively.The influence of various control factors(sliding velocity,NF/BF/NBF contents,normal load and sliding distance) on specific sliding wear rate of composites was evaluated by Taguchi(three factors at three levels) experimental design and the percentage contribution of these selected parameters on sliding wear performance was examined by Analysis of variance(ANOVA).The sliding wear property of as-developed composites was found to be greatly influenced by sliding velocity and the wear resistance was observed to be improved with the NF/BF/NBF contents.The wear mechanism of the as-fabricated composites has been elucidated by scanning electron microscopy analysis.The research outcomes demonstrated that the hybridization of Bauhinia vahlii fiber with Nettle fiber led to improve the mechanical and wear properties of epoxy composites.展开更多
The evolution in communication techniques has created wide threats for crucial information transfer through a communication channel. Covert communication with steganography is a skill of concealing secret information ...The evolution in communication techniques has created wide threats for crucial information transfer through a communication channel. Covert communication with steganography is a skill of concealing secret information within cover object and hence shields the data theft over rapidly growing network.Recently, diverse steganography techniques using edge identification have been proposed in literature.Numerous methods however utilize certain pixels in the cover image for inserting edge information,resulting in significant deformation. The conventional edge detection method limits the deployment of edge detection in steganography as concealing the information would introduce some variations to the cover image. Hence inserting data in pixel areas recognized by existing conventional edge detection techniques like canny cannot ensure the recognition of the exact edge locations for the cover and stego images. In this paper, an Adaptive steganography method based on novel fuzzy edge identification is proposed. The method proposed is proficient of estimating the precise edge areas of a cover image and also ensures the exact edge location after embedding the secret message. Experimental results reveal that the technique has attained good imperceptibility compared to the Hayat AI-Dmour and Ahmed AIAni Edge XOR method in spatial domain.展开更多
Objective:To detect types of liver disorders through biochemical studies in coastal Andhra Pradesh,India.Methods:Serum level of bilirubin(total and direct),serum glutamate oxaloacetate transaminase(SGOT),serum glutama...Objective:To detect types of liver disorders through biochemical studies in coastal Andhra Pradesh,India.Methods:Serum level of bilirubin(total and direct),serum glutamate oxaloacetate transaminase(SGOT),serum glutamate pyruvate transaminase(SGPT)and alkaline phosphatase(ALP)were measured among the adult men and women from a South Indian district.Standard methodologies were adopted during selection of study participants and collection and analysis of blood samples.Results:It is observed that there is no difference in the levels of bilirubin(total and direct)and ALP in male and female patients.It is observed that there are significant differences in the levels of SGOT and SGPT.Males recorded higher levels than females.Conclusion:A considerable number of patients showed increased levels of total and direct bilirubin,SGOT,SGPY and ALP.The higher levels of SGOT and SGPT among males might be due to their alcoholic habits and among men in this community.The overall liver function abnormalities may be due to dietary habits,mal-absorption,nonalcoholic fatty liver,diabetes mellitus and contaminated drinking water.展开更多
基金Supported by the National Natural Science Foundation of China(22278441,22478452,21808244)。
文摘Catalytic oxidation represents a pivotal technology for the valorization of light hydrocarbons,where oxidative dehydrogenation(ODH)and epoxidation reactions using molecular oxygen have garnered substantial interest owing to their high atom economy and environmental friendliness.This review systematically summarizes recent advances in the oxidative dehydrogenation of light alkanes(ethane,propane)and the aerobic epoxidation of light olefins(ethylene,propylene).In terms of rational catalyst design,this review elaborates on performance regulation strategies for metal oxide catalysts such as MoVNbTeO_(x)mixed oxides,NiO-based,and V-based systems,as well as carbon/boron-based non-metal catalysts in alkane oxidative dehydrogenation,along with silver-based and copper-based catalysts in alkene epoxidation.These strategies include regulating the oxidation state of active sites,strong metal-support interactions,particle size and crystal facet engineering,and promoter modification.At the mechanistic level,combining density functional theory calculations with in situ characterization techniques,this review delves into the C-H bond activation and alkene desorption pathways in oxidative dehydrogenation,along with the oxygen insertion routes and competing side reactions in epoxidation.Special attention is given to the dynamic evolution of electrophilic and nucleophilic oxygen species and their decisive role in reaction selectivity.Finally,the review outlines persistent challenges in the field,including suppressing over-oxidation and overcoming the trade-off between conversion and selectivity and proposes future research directions such as the precise design of active centers,development of inherently safer processes,and in-depth analysis of complex reaction networks,aiming to support the green transition of the chemical industry.
文摘In the present study,the mechanical and ballistic properties of friction stir welded(FSW)aluminum alloy(AA5754)samples were investigated,both untreated and cryogenically treated,when impacted by a 7.62 mm armour-piercing(AP)bullet at an impact velocity of 682±20 m/s.The FSW technique was used to prepare the welded samples for AA5754,with an axial force of 7 kN,a feed rate of 20 mm/min,and a speed of 1200 rpm.The cryogenic treatments performed after welding,including deep cryogenic treatment(DCT)at196℃ and shallow cryogenic treatment(SCT)at80℃,for 6 and 72 h,respectively.The microstructure and mechanical characteristics of cryogenically treated and untreated joints were examined.The cryogenic treatment refined the grain size(1.05 μm)and enhanced the microhardness(93 Hv).Moreover,DCT-FSW significantly improved the tensile strength(13.93%)and impact strength(8.45%)compared to untreated FSW sample.Additionally,in untreated FSW samples,the fracture behaviour varied:the impact fracture mode primarily exhibited ductile failure,while the tensile fracture exhibited a mixed fracture mode.In contrast,the tensile and impact fracture modes of the DCT-FSWwere dominated by a ductile failure mode.The DCT-FSW target demonstrated a lower depth of penetration(DOP)of 31 mm compared to the SCT-FSWand untreated FSW targets.Post-ballistic SEM analysis in the crater region of all three zones revealed the formation of frictional grooves,small cracks,and adiabatic shear bands(ASBs).
文摘Research and development of green oxidizers and green fuels as a possible replacement for ammonium perchlorate(NH4ClO4,AP) and hydrazine(N2H4) respectively has been increased considerably in the recent years.AP and hydrazine are the oxidizer and fuel entities,and used in solid and liquid rocket motors respectively.AP is highly toxic and led to adverse health effects,while hydrazine is carcinogenic in nature.AP is in use from the last several decades for rocket and space shuttle propulsion,while hydrazine is used in upper stage liquid propelled rocket motors.It’s a tough task to replace AP with the currently available green oxidizers;since their ballistic properties are weaker when compared to AP and also they can’t be successfully deployed in a solid rocket motor at present Some important available solid green oxidizers are ammonium nitrate(AN),ammonium dinitramide(ADN),hydroxyl ammonium nitrate(HAN),and hydrazinium nitroformate(HNF).However,AN is one of the cheap and readily available oxidizer,and has great potential to use in solid/liquid rocket motors.Tremendous progress has been envisaged till now,and more progress will be there in the coming future over the development of AN based green energetic materials(GEM’s).A concise overview has been presented over the development of phase stabilized ammonium nitrate(PSAN) and AN/KDN based green oxidizers in the present review paper.
基金Project(21JCQN0066)supported by the Youth Science&Technology Foundation of Sichuan Province,China。
文摘Corrosion behaviors of P110 and N80 tubular steels in CO_(2) gas phase and supercritical(S-CO_(2))phase in a saturated water vapor environment were explored in corrosion weight loss experiments by SEM,EDS,XRD,XPS and cross-section analysis techniques.With the increase in CO_(2) partial pressure,the average corrosion rate increased first and then decreased.The average corrosion rate reached the maximum value under the near-critical pressure.When CO_(2) partial pressure further increased to be above the critical pressure,the average corrosion rate gradually decreased and local aggregation of molecules was weakened.
文摘To simulate explosion fragments, it is necessary to predict many variables such as fragment velocity, size distribution and projection angle. For active protection systems these predictions need to be made very quickly, before the weapon hits the target. Fast predictions also need to be made in real time simulations when the impact of many different computer models need to be assessed. The research presented in this paper focuses on creating a fast and accurate estimate of one of these variables - the initial fragment velocity. The Gurney equation was the first equation to calculate initial fragment velocity. This equation, sometimes with modifications, is still used today where finite element analysis or complex mathematical approaches are considered too computationally expensive. This paper enhances and improves Breech’s two-dimensional Gurney equation using available empirical data and the principals of conservation of momentum and energy. The results are computationally quick, providing improved accuracy for estimating initial fragment velocity. This will allow the developed model to be available for real-time simulation and fast computation, with improved accuracy when compared to existing approaches.
文摘Explosive cladding of Al 5052–Al 1100 plate, interfaced with a stainless steel wire mesh interlayer, is attempted. Loading ratio and standoff distance were varied. An increase in loading ratio (R) and standoff distance (S) enhances the plate velocity (Vp), dynamic bend angle (β) and pressure developed (P). The interface morphology of the explosive clads confirms strong metallurgical bond between the wire mesh and aluminum plates. Further, a smooth transition from straight to undulating interlayered topography is witnessed. The introduction of a wire mesh, as interlayer, leads to an improvement in mechanical strength with a slender reduction in overall corrosion resistance of the “explosive clads”.
基金support provided by Boeing India to Indian Institute of Technology Kanpur,IndiaTEQIP funding from Government of India provided to G.B.Pant Institute of Engineering&Technology Pauri-Garhwal India
文摘This paper reports a novel micro-blast driven manufacturing process for micro-forming of Aluminum foils. The micro-blast is realized by using a nanoenergetic material system comprising of Bi_2O_3 microrods and aluminum particles. There is an enhanced need of forming of thin aluminum foil structures in small regions from point of view of drug packaging etc. The process developed caters to this need by using a single shot forming process using a micro-blast source. The micro-blast that is generated from an energetic composite system is made highly tunable by modulating the peak pressure generated through the blasting process and their impact in micro-forming of thin aluminum foils is observed through parametric studies. The engineering challenge involved in these experiments is to tune the blast pressure properties in order to address the forming of thin metal sheets with limiting boundary values as defined by the failure criteria. A variety of characterization techniques related to a thorough analysis of the synthesized material viz. X-ray diffraction(XRD), Scanning Electron Microscopy(SEM) etc, are used to tune the functional properties like gauge blast pressure etc, of material system. We have found a material system that can generate a maximum peak pressure of 73.8 MPa with pressurization rate of 2460 GPas^(-1) and that is able to accomplish micro-forming on thin metal foils(around 0.3 mm thickness). Experimental investigations demonstrate that tunabilty aspect of the energetic composites when exercised can enable variant processes such as embossing, coining, drilling etc. which may be of significant utility to drug packaging industries. A proper mathematical modeling of the forming process and critical process parameters therein have also been detailed.
文摘The study focused on investigating the effect of Deep Cryogenic Treatment(DCT)on the mechanical and ballistic properties of AA7075-T6 aluminum alloy.The microstructure,microhardness,tensile strength,and impact strength of the Base Material(BM)and DCT-treated 7075 samples were analyzed through metallographic analysis and mechanical tests.The microstructure of the DCT-treated 7075 samples revealed fine grains and a distribution of secondary phase particles.The tensile strength,impact strength,and microhardness of DCT-treated samples increased by 7.41%,4%,and 9.68%,respectively,compared to the BM samples.The fractography analysis of the tensile samples showed cleavage facets,microvoids,and dimples in both the samples.The ballistic behavior of the BM and DCT target plates were studied by impacting hard steel core projectiles at a velocity of 750±10 m/s.The target plates failed due to petaling and ductile hole enlargement,and the depth of penetration(DOP)of the DCT target was less than that of the BM target,indicating a higher ballistic resistance.The post-ballistic microstructure examination of the target plates showed the formation of an Adiabatic Shear Band(ASB)without any cracks.It was concluded that the DCT treatment improved the mechanical and ballistic properties of the aluminum alloy due to grain refinement and high dislocation density.
基金financially supported by Ministry of Science and Higher Education of the Russian Federation(Grant No.FENU-2023-0013)。
文摘The high entropy alloys(HEAs)are the newly developed high-performance materials that have gained significant importance in defence,nuclear and aerospace sector due to their superior mechanical properties,heat resistance,high temperature strength and corrosion resistance.These alloys are manufactured by the equal mixing or larger proportions of five or more alloying elements.HEAs exhibit superior mechanical performance compared to traditional engineering alloys because of the extensive alloying composition and higher entropy of mixing.Solid state welding(SSW)techniques such as friction stir welding(FSW),rotary friction welding(RFW),diffusion bonding(DB)and explosive welding(EW)have been efficiently deployed for improving the microstructural integrity and mechanical properties of welded HEA joints.The HEA interlayers revealed greater potential in supressing the formation of deleterious intermetallic phases and maximizing the mechanical properties of HEAs joints.The similar and dissimilar joining of HEAs has been manifested to be viable for HEA systems which further expands their industrial applications.Thus,the main objective of this review paper is to present a critical review of current state of research,challenges and opportunities and main directions in SSW of HEAs mainly CoCrFeNiMn and Al_xCoCrFeNi alloys.The state of the art of problems,progress and future outlook in SSW of HEAs are critically reviewed by considering the formation of phases,microstructural evolution and mechanical properties of HEAs joints.
文摘The use of asbestos material is being avoided to manufacture the brake pads as it is harmful and toxic in nature. Further it leads to various health issues like asbestosis, mesothelioma and lung cancers. These brake pads can be replaced by natural fibers like Palm kernel (0-50%), Nile roses (0-15%) and Wheat (0-10%) with additives like aluminum oxide (5%-20%) and graphite powder (10%-35%). Phenolic resin of 35% is utilized as a binder. Particulated Nile roses are used to increase the friction coefficient and wheat powder is used to reduce the wear rate. Aluminum oxide and graphite are abrasive in nature. This helps to make brake pads with high friction co-efficient and less wear rate with low noise pollution. The wear of the proposed composites have been investigated at different speeds. Various tests like wear on pin-ondisc apparatus, hardness on the Rockwell hardness apparatus and oil absorption test have been conducted. Phenolic resin produces good bonding nature to fiber. Thus, Fibers found to have performed palatably among all commercial brake pads. The objective of the research indicates that Palm kernal shell could be a conceivable alternative for asbestos in friction coating materials.
基金Project(93-2625-Z-027-006)supported by the National Science Council of Taipei,China
文摘Variations between earthquakes result in many factors that influence post-earthquake building damage(e.g.,ground motion parameters,building structure,site information,and quality of construction).Consequently,it is necessary to develop an appropriate building damage-rate estimation model.The building damage survey data were recorded and constructed into files by the Architecture and Building Research Institute(ABRI),Taiwan for the 1999 Chi-Chi earthquake in the Nantou region as a basis for developing a building damage rate estimation model by applying fuzzy theory to express the fragility curves of buildings as a membership function.Empirical verification was performed using post-earthquake building damage data in the Taichung city that suffered relatively severe damage.Results indicate that fuzzy theory can be applied to predict building damage rates and that the estimated results are similar to actual disaster figures.Prediction of disaster damage using building damage rates can provide a reference for immediate disaster response during earthquakes and for regular disaster prevention and rescue planning.
文摘The cellulosic bast fibers are recognized as a justifiable and biodegradable substitute for producing moderate strength polymer composite materials because of their characteristics of renewability,ecofriendliness,and higher specific strength.Hence the aim of this research work is to fabricate Himalayan bast fibers(Nettle fiber(NF)/bauhinia vahlii fiber(BF)) based mono/hybrid epoxy composites at varying weight percentage of 2-6 wt% and evaluate the physical(void fraction and water absorption),mechanical(tensile strength,flexural strength,hardness) and sliding wear properties of as-fabricated composites.The 6 wt% NBF reinforced composites exhibited higher mechanical properties as compared to NF and BF composites with tensile strength of 34.04 MPa,flexural strength of 42.45 MPa,and hardness of 37.01 Hv respectively.The influence of various control factors(sliding velocity,NF/BF/NBF contents,normal load and sliding distance) on specific sliding wear rate of composites was evaluated by Taguchi(three factors at three levels) experimental design and the percentage contribution of these selected parameters on sliding wear performance was examined by Analysis of variance(ANOVA).The sliding wear property of as-developed composites was found to be greatly influenced by sliding velocity and the wear resistance was observed to be improved with the NF/BF/NBF contents.The wear mechanism of the as-fabricated composites has been elucidated by scanning electron microscopy analysis.The research outcomes demonstrated that the hybridization of Bauhinia vahlii fiber with Nettle fiber led to improve the mechanical and wear properties of epoxy composites.
文摘The evolution in communication techniques has created wide threats for crucial information transfer through a communication channel. Covert communication with steganography is a skill of concealing secret information within cover object and hence shields the data theft over rapidly growing network.Recently, diverse steganography techniques using edge identification have been proposed in literature.Numerous methods however utilize certain pixels in the cover image for inserting edge information,resulting in significant deformation. The conventional edge detection method limits the deployment of edge detection in steganography as concealing the information would introduce some variations to the cover image. Hence inserting data in pixel areas recognized by existing conventional edge detection techniques like canny cannot ensure the recognition of the exact edge locations for the cover and stego images. In this paper, an Adaptive steganography method based on novel fuzzy edge identification is proposed. The method proposed is proficient of estimating the precise edge areas of a cover image and also ensures the exact edge location after embedding the secret message. Experimental results reveal that the technique has attained good imperceptibility compared to the Hayat AI-Dmour and Ahmed AIAni Edge XOR method in spatial domain.
文摘Objective:To detect types of liver disorders through biochemical studies in coastal Andhra Pradesh,India.Methods:Serum level of bilirubin(total and direct),serum glutamate oxaloacetate transaminase(SGOT),serum glutamate pyruvate transaminase(SGPT)and alkaline phosphatase(ALP)were measured among the adult men and women from a South Indian district.Standard methodologies were adopted during selection of study participants and collection and analysis of blood samples.Results:It is observed that there is no difference in the levels of bilirubin(total and direct)and ALP in male and female patients.It is observed that there are significant differences in the levels of SGOT and SGPT.Males recorded higher levels than females.Conclusion:A considerable number of patients showed increased levels of total and direct bilirubin,SGOT,SGPY and ALP.The higher levels of SGOT and SGPT among males might be due to their alcoholic habits and among men in this community.The overall liver function abnormalities may be due to dietary habits,mal-absorption,nonalcoholic fatty liver,diabetes mellitus and contaminated drinking water.
