The melt stirring in a large copper smelting oxygen bottom-blown furnace is caused by the large amount of gas movement blown in by two rows of oxygen lances.At present,the two rows of oxygen lances provide oxygen of e...The melt stirring in a large copper smelting oxygen bottom-blown furnace is caused by the large amount of gas movement blown in by two rows of oxygen lances.At present,the two rows of oxygen lances provide oxygen of equal strength,and the stirring in the central area of the melt is insufficient,which restricts the efficient progress of the smelting reaction.This study proposes a strong-weak coupling oxygen supply method and establishes an equivalent model based on a large bottom-blown furnace(LBBF)of an enterprise to simulate the bubble characteristics and flow characteristics of the molten pool.The results show that adjusting the flow ratio between the two rows of oxygen lances can create a“strong”and a“weak”coexisting source of disturbance in an LBBF.It is worth noting that when the flow rate ratio of the two rows of oxygen lances is 1.6,the peak velocity generated by the“strong”distur bance source in the molten pool increases by 18.92%,and the disturbance range increases.This method effectively strengthens the stirring in the central area of the molten pool,improves smelting efficiency,and does not produce harmful melt splashes.It provides important guidance for optimizing production practice.展开更多
Ti-6Al-4V alloy powder was prepared through a two-step reduction of a mixture of TiO_(2),V_(2)O_(5) and Al_(2)O_(3) in this study.The oxide mixture was first reduced by Mg in MgCl_(2) at 750℃ in argon,where oxygen wa...Ti-6Al-4V alloy powder was prepared through a two-step reduction of a mixture of TiO_(2),V_(2)O_(5) and Al_(2)O_(3) in this study.The oxide mixture was first reduced by Mg in MgCl_(2) at 750℃ in argon,where oxygen was reduced to 2.47 wt%from 40.02 wt%.The oxygen content in the final powder was eventually reduced to an extremely low level(0.055 wt%)using calcium at 900℃ in argon,and the final powder had the composition of 90.12 wt%Ti,5.57 wt%Al,and 3.87 wt%V,which meets the standard specification of Ti-6Al-4V(ASTM F1108-09).Between the two reductions,a heat treatment step was designed to help controlling the specific surface area and particle size.The effect of the heat treatment temperature on the morphology,and composition uniformity of the powder was investigated in detail.Heat treatment above 1300℃ attributed to a dense powder with a controlled specific surface area.Thermodynamic modeling and experimental results indicated that onlyα-Ti enriched with Al andβ-Ti enriched with V exist in the final powder,and other possible phases including Al-Mg and Al-V were excluded.This study also offers a triple-step thermochemical process for producing high-purity Ti-based alloy powder.展开更多
基金Project(2022YFC3901501)supported by the National Key R&D Program of ChinaProject(U20A20273)supported by the National Natural Science Foundation of China+1 种基金Project(2022JJ10078)supported by the Natural Science Foundation for Distinguished Young Scholars of Hunan Province,ChinaProject(2021RC3005)supported by the Science and Technology Innovation Program of Hunan Province,China。
文摘The melt stirring in a large copper smelting oxygen bottom-blown furnace is caused by the large amount of gas movement blown in by two rows of oxygen lances.At present,the two rows of oxygen lances provide oxygen of equal strength,and the stirring in the central area of the melt is insufficient,which restricts the efficient progress of the smelting reaction.This study proposes a strong-weak coupling oxygen supply method and establishes an equivalent model based on a large bottom-blown furnace(LBBF)of an enterprise to simulate the bubble characteristics and flow characteristics of the molten pool.The results show that adjusting the flow ratio between the two rows of oxygen lances can create a“strong”and a“weak”coexisting source of disturbance in an LBBF.It is worth noting that when the flow rate ratio of the two rows of oxygen lances is 1.6,the peak velocity generated by the“strong”distur bance source in the molten pool increases by 18.92%,and the disturbance range increases.This method effectively strengthens the stirring in the central area of the molten pool,improves smelting efficiency,and does not produce harmful melt splashes.It provides important guidance for optimizing production practice.
基金Project(52004342) supported by the National Natural Science Foundation of ChinaProject(150240015) supported by the Innovation-Driven Project of Central South University,ChinaProject(2021JJ20065) supported by the Natural Science Fund for Outstanding Young Scholar of Hunan Province,China。
文摘Ti-6Al-4V alloy powder was prepared through a two-step reduction of a mixture of TiO_(2),V_(2)O_(5) and Al_(2)O_(3) in this study.The oxide mixture was first reduced by Mg in MgCl_(2) at 750℃ in argon,where oxygen was reduced to 2.47 wt%from 40.02 wt%.The oxygen content in the final powder was eventually reduced to an extremely low level(0.055 wt%)using calcium at 900℃ in argon,and the final powder had the composition of 90.12 wt%Ti,5.57 wt%Al,and 3.87 wt%V,which meets the standard specification of Ti-6Al-4V(ASTM F1108-09).Between the two reductions,a heat treatment step was designed to help controlling the specific surface area and particle size.The effect of the heat treatment temperature on the morphology,and composition uniformity of the powder was investigated in detail.Heat treatment above 1300℃ attributed to a dense powder with a controlled specific surface area.Thermodynamic modeling and experimental results indicated that onlyα-Ti enriched with Al andβ-Ti enriched with V exist in the final powder,and other possible phases including Al-Mg and Al-V were excluded.This study also offers a triple-step thermochemical process for producing high-purity Ti-based alloy powder.
基金Project(52004342)supported by the National Natural Science Foundation of ChinaProject(150240015)supported by the Innovation-driven Project of Central South University,ChinaProject(2021JJ20065)supported by the Natural Science Fund for Outstanding Young Scholar of Hunan Province,China。
