Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composi...Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composition of some beneficial groups. In this work, carbonized leaf powder was evaluated for its adsorption performance towards Ni（II）. According to the results, adsorbent component, dosage, initial solute concentration, solution pH, temperature and contact time can significantly affect the efficiency of Ni（II） removal. Sips model fits the test results best, and the adsorption capacity towards Ni（II） is determined around 37.62 mg/g. The thermodynamic behaviors reveal the endothermic and spontaneous nature of the adsorption. The free adsorption energy （fluctuate around 8 kJ/mol） predicted by D-R model indicates that the adsorption capacity originated from both physical and chemical adsorption. Room temperature （15-25 ℃） is suitable for Ni（II） removal as well as low energy consumption for temperature enhancement. Further conclusions about the mechanism of chemical adsorption are obtained through analysis of the FT-IR test and XRD spectra, which indicates that the adsorption process occurs predominantly between amine, carbonate, phosphate and nickel ions.展开更多
To investigate the mechanical properties of cement mortar in sodium sulfate and sodium chloride solutions, uniaxial compression test and ultrasonic test were performed. Test results show that the relative dynamic elas...To investigate the mechanical properties of cement mortar in sodium sulfate and sodium chloride solutions, uniaxial compression test and ultrasonic test were performed. Test results show that the relative dynamic elastic modulus, the mass variation,and the compressive strength of cement mortar increase first, and then decrease with increasing erosion time in sodium sulfate and sodium chloride solutions. The relative dynamic elastic moduli and the compressive strengths of cement mortars with water/cement ratios of 0.55 and 0.65 in sodium sulfate solution are lower than those in sodium chloride solution with the same concentration at the420 th day of immersion. The compressive strength of cement mortar with water/cement ratio of 0.65 is more sensitive to strain rate than that with water/cement ratio of 0.55. In addition, the strain-rate sensitivity of compressive strength of cement mortar will increase under attacks of sodium sulfate or sodium chloride solution.展开更多
The hydration characteristics of pre-cast concrete considering the effects of effective initial steam-curing and water-curing duration were measured and analyzed with XRD, TG, X-ray CT, SEM-BSE and MIP techniques. The...The hydration characteristics of pre-cast concrete considering the effects of effective initial steam-curing and water-curing duration were measured and analyzed with XRD, TG, X-ray CT, SEM-BSE and MIP techniques. The results show that the effective initial steam-curing duration for pre-cast concrete with lower water-binder ratio was 10 14 h at 50 °C and the initial water-curing duration was 7 14 d. And the hydration evolution of cement, fly ash and slag in pre-cast concrete was obtained respectively by combining the hydrochlorides and EDTA selecting dissolution methods, based on which the contents of hydrated and anhydrate in concrete were calculated and the corresponding dynamic capillary porosity was also determined. Moreover, the comparison between calculated results and experimental ones indicates that the proposed evolution models of microscopic characteristics corresponding to hydration kinetics of cemented materials could be adopted to predict the developing trend of capillary porosity and hydration-products content in pre-cast concrete with fly ash and slag under certain curing conditions.展开更多
Nickel is a toxic heavy metal among trace elements which has a detrimental impact on living organisms. There is growing need of finding an economic and effective solution for Ni(Ⅱ) immobilization in environments. Chi...Nickel is a toxic heavy metal among trace elements which has a detrimental impact on living organisms. There is growing need of finding an economic and effective solution for Ni(Ⅱ) immobilization in environments. Chinese loess was selected as adsorbent to remove Ni(Ⅱ) from aqueous solution. Adsorbent dosage, reaction time, solute concentration, temperature, and solution p H also have influences on efficiency of Ni(Ⅱ) removal. The monolayer adsorption capacity of loess towards Ni(Ⅱ) is determined to be about 15.61 mg/g. High temperature and p H favor the removal of Ni(Ⅱ) using Chinese loess soil and the optimal dosage of loess is determined to be 10 g/L. The kinetics and adsorption isotherms of the adsorption process can be best-fitted with the pseudo second order kinetics and Langmuir isothermal model, respectively. The thermodynamic analysis reveals that the adsorption process is spontaneous, endothermic and the system disorder increases with duration. Nickel ions can be removed with the removal efficiency of 98.5% at p H greater than or equal to 9.7. Further studies on loess and Ni(Ⅱ) laden loess(using X-Ray diffraction, Fourier transform infrared spectroscopy) and Ni(Ⅱ) species distribution at various p H have been conducted to discuss the adsorption mechanism. Loess soils in China have proven to be a potential adsorbent for Ni(Ⅱ) removal from aqueous solutions.展开更多
When an expanded-base pile is installed into ground, the cavity expansion associated with penetration of the enlarged pile base is followed by cavity contraction along the smaller-diameter pile shaft. In order to acco...When an expanded-base pile is installed into ground, the cavity expansion associated with penetration of the enlarged pile base is followed by cavity contraction along the smaller-diameter pile shaft. In order to account for the influence of cavity contraction on the change of bearing capacity of expanded-base pile, a theoretical calculation methodology, predicting the setup of expanded-base pile, was established by employing the cavity contraction theory to estimate the shaft resistance of expanded-base pile, and horizontal consolidation theory to predict the dissipation of excess pore pressure. Finally, the numerical solutions for the setup of expanded-base pile were obtained. The parametric study about the influence of cavity contraction on setup of expanded-base pile was carried out, while a field test was introduced. The parametric study shows that the decrements in radial pressure and the maximum pore water pressure after considering cavity contraction are increased as the expanded ratio(base diameter/shaft diameter) and rigidity index of soil are raised. The comparison between calculated and measured values shows that the calculated results of ultimate bearing capacity for expanded-base pile considering cavity contraction agree well with the measured values; however, the computations ignoring cavity contraction are 2.5-3.0 times the measured values.展开更多
A local improvement procedure based on tabu search(TS) was incorporated into a basic genetic algorithm(GA) and a global optimal algorithm,i.e.,hybrid genetic algorithm(HGA) approach was used to search the circular and...A local improvement procedure based on tabu search(TS) was incorporated into a basic genetic algorithm(GA) and a global optimal algorithm,i.e.,hybrid genetic algorithm(HGA) approach was used to search the circular and noncircular slip surfaces associated with their minimum safety factors.The slope safety factors of circular and noncircular critical slip surfaces were calculated by the simplified Bishop method and an improved Morgenstern-Price method which can be conveniently programmed,respectively.Comparisons with other methods were made which indicate the high efficiency and accuracy of the HGA approach.The HGA approach was used to calculate one case example and the results demonstrated its applicability to practical engineering.展开更多
The theoretical formulations of Coulomb and Rankine still remain as the fundamental approaches to the analysis of most gravity-type retaining wall,with the assumption that sufficient lateral yield will occur to mobili...The theoretical formulations of Coulomb and Rankine still remain as the fundamental approaches to the analysis of most gravity-type retaining wall,with the assumption that sufficient lateral yield will occur to mobilize fully limited conditions behind the wall.The effects of the magnitude of wall movements and different wall-movement modes are not taken into consideration.The disturbance of backfill is considered to be related to the wall movement under translation mode.On the basis of disturbed state concept(DSC),a general disturbance function was proposed which ranged from-1 to 1.The disturbance variables could be determined from the measured wall movements.A novel approach that related to disturbed degree and the mobilized internal frictional angle of the backfill was also derived.A calculation method benefited from Rankine's theory and the proposed approach was established to predict the magnitude and distribution of earth pressure from the cohesionless backfill under translation mode.The predicted results,including the magnitude and distribution of earth pressure,show good agreement with those of the model test and the finite element method.In addition,the disturbance parameter b was also discussed.展开更多
基金Projects(5117916851308310)supported by the National Natural Science Foundation of China+1 种基金Project(LQ13E080007)supported by Zhejiang Provincial Natural Science Foundation,ChinaProject supported by the Scientific Research Foundation for the Returned Overseas Chinese Scholars of Jiangsu Province,China
文摘Nickel is a heavy metal which has the potential threaten to human＇s health and attracts public concern recently. The carbonized leaf powder is expected as suitable adsorbent for Ni（II） removal became of the composition of some beneficial groups. In this work, carbonized leaf powder was evaluated for its adsorption performance towards Ni（II）. According to the results, adsorbent component, dosage, initial solute concentration, solution pH, temperature and contact time can significantly affect the efficiency of Ni（II） removal. Sips model fits the test results best, and the adsorption capacity towards Ni（II） is determined around 37.62 mg/g. The thermodynamic behaviors reveal the endothermic and spontaneous nature of the adsorption. The free adsorption energy （fluctuate around 8 kJ/mol） predicted by D-R model indicates that the adsorption capacity originated from both physical and chemical adsorption. Room temperature （15-25 ℃） is suitable for Ni（II） removal as well as low energy consumption for temperature enhancement. Further conclusions about the mechanism of chemical adsorption are obtained through analysis of the FT-IR test and XRD spectra, which indicates that the adsorption process occurs predominantly between amine, carbonate, phosphate and nickel ions.
基金Project(LY13E080021) supported by the Natural Science Foundation of Zhejiang Province,ChinaProject(2011A610072) supported by the Ningbo Municipal Natural Science Foundation,ChinaProject(XKL14D2063) supported by Subject Program of Ningbo University,China
文摘To investigate the mechanical properties of cement mortar in sodium sulfate and sodium chloride solutions, uniaxial compression test and ultrasonic test were performed. Test results show that the relative dynamic elastic modulus, the mass variation,and the compressive strength of cement mortar increase first, and then decrease with increasing erosion time in sodium sulfate and sodium chloride solutions. The relative dynamic elastic moduli and the compressive strengths of cement mortars with water/cement ratios of 0.55 and 0.65 in sodium sulfate solution are lower than those in sodium chloride solution with the same concentration at the420 th day of immersion. The compressive strength of cement mortar with water/cement ratio of 0.65 is more sensitive to strain rate than that with water/cement ratio of 0.55. In addition, the strain-rate sensitivity of compressive strength of cement mortar will increase under attacks of sodium sulfate or sodium chloride solution.
基金Project(51308308) supported by the National Natural Science Foundation of ChinaProject(LQ12E08002) supported by the Natural Science Foundation of Zhejiang Province,China+3 种基金Project(2012A610159) supported by the Natural Science Foundation of Ningbo City,ChinaProjects(XKL11D2081,zj1113) Subject Program of Ningbo University,ChinaProject(2010R50034) supported by the Key Science and Technology Innovation Team Program of Zhejiang Province,ChinaProject supported by K.C Wong Magna Fund in Ningbo University
文摘The hydration characteristics of pre-cast concrete considering the effects of effective initial steam-curing and water-curing duration were measured and analyzed with XRD, TG, X-ray CT, SEM-BSE and MIP techniques. The results show that the effective initial steam-curing duration for pre-cast concrete with lower water-binder ratio was 10 14 h at 50 °C and the initial water-curing duration was 7 14 d. And the hydration evolution of cement, fly ash and slag in pre-cast concrete was obtained respectively by combining the hydrochlorides and EDTA selecting dissolution methods, based on which the contents of hydrated and anhydrate in concrete were calculated and the corresponding dynamic capillary porosity was also determined. Moreover, the comparison between calculated results and experimental ones indicates that the proposed evolution models of microscopic characteristics corresponding to hydration kinetics of cemented materials could be adopted to predict the developing trend of capillary porosity and hydration-products content in pre-cast concrete with fly ash and slag under certain curing conditions.
基金Projects(5117916851308310)supported by the National Natural Science Foundation of ChinaProject(LQ13E080007)supported by Zhejiang Provincial Natural Science Foundation of China
文摘Nickel is a toxic heavy metal among trace elements which has a detrimental impact on living organisms. There is growing need of finding an economic and effective solution for Ni(Ⅱ) immobilization in environments. Chinese loess was selected as adsorbent to remove Ni(Ⅱ) from aqueous solution. Adsorbent dosage, reaction time, solute concentration, temperature, and solution p H also have influences on efficiency of Ni(Ⅱ) removal. The monolayer adsorption capacity of loess towards Ni(Ⅱ) is determined to be about 15.61 mg/g. High temperature and p H favor the removal of Ni(Ⅱ) using Chinese loess soil and the optimal dosage of loess is determined to be 10 g/L. The kinetics and adsorption isotherms of the adsorption process can be best-fitted with the pseudo second order kinetics and Langmuir isothermal model, respectively. The thermodynamic analysis reveals that the adsorption process is spontaneous, endothermic and the system disorder increases with duration. Nickel ions can be removed with the removal efficiency of 98.5% at p H greater than or equal to 9.7. Further studies on loess and Ni(Ⅱ) laden loess(using X-Ray diffraction, Fourier transform infrared spectroscopy) and Ni(Ⅱ) species distribution at various p H have been conducted to discuss the adsorption mechanism. Loess soils in China have proven to be a potential adsorbent for Ni(Ⅱ) removal from aqueous solutions.
基金Project(LQ15E080002)supported by Zhejiang Provincial Natural Science Foundation of ChinaProjects(5150828251478228)supported by the National Natural Science Foundation of China
文摘When an expanded-base pile is installed into ground, the cavity expansion associated with penetration of the enlarged pile base is followed by cavity contraction along the smaller-diameter pile shaft. In order to account for the influence of cavity contraction on the change of bearing capacity of expanded-base pile, a theoretical calculation methodology, predicting the setup of expanded-base pile, was established by employing the cavity contraction theory to estimate the shaft resistance of expanded-base pile, and horizontal consolidation theory to predict the dissipation of excess pore pressure. Finally, the numerical solutions for the setup of expanded-base pile were obtained. The parametric study about the influence of cavity contraction on setup of expanded-base pile was carried out, while a field test was introduced. The parametric study shows that the decrements in radial pressure and the maximum pore water pressure after considering cavity contraction are increased as the expanded ratio(base diameter/shaft diameter) and rigidity index of soil are raised. The comparison between calculated and measured values shows that the calculated results of ultimate bearing capacity for expanded-base pile considering cavity contraction agree well with the measured values; however, the computations ignoring cavity contraction are 2.5-3.0 times the measured values.
基金Project(50878082)supported by the National Natural Science Foundation of ChinaProject(2012C21058)supported by the Public Welfare Technology Application Research of Zhejiang Province,China
文摘A local improvement procedure based on tabu search(TS) was incorporated into a basic genetic algorithm(GA) and a global optimal algorithm,i.e.,hybrid genetic algorithm(HGA) approach was used to search the circular and noncircular slip surfaces associated with their minimum safety factors.The slope safety factors of circular and noncircular critical slip surfaces were calculated by the simplified Bishop method and an improved Morgenstern-Price method which can be conveniently programmed,respectively.Comparisons with other methods were made which indicate the high efficiency and accuracy of the HGA approach.The HGA approach was used to calculate one case example and the results demonstrated its applicability to practical engineering.
基金Project(50678158) supported by the National Natural Science Foundation of China
文摘The theoretical formulations of Coulomb and Rankine still remain as the fundamental approaches to the analysis of most gravity-type retaining wall,with the assumption that sufficient lateral yield will occur to mobilize fully limited conditions behind the wall.The effects of the magnitude of wall movements and different wall-movement modes are not taken into consideration.The disturbance of backfill is considered to be related to the wall movement under translation mode.On the basis of disturbed state concept(DSC),a general disturbance function was proposed which ranged from-1 to 1.The disturbance variables could be determined from the measured wall movements.A novel approach that related to disturbed degree and the mobilized internal frictional angle of the backfill was also derived.A calculation method benefited from Rankine's theory and the proposed approach was established to predict the magnitude and distribution of earth pressure from the cohesionless backfill under translation mode.The predicted results,including the magnitude and distribution of earth pressure,show good agreement with those of the model test and the finite element method.In addition,the disturbance parameter b was also discussed.
