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Thermochemical analysis and field performance of small arms propellants from 1953(30-06 M2 AP) and 2012(M855A1) ammunition
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作者 Benjamin Streifel Amy Courtney Michael Courtney 《Defence Technology(防务技术)》 2025年第6期26-33,共8页
When older stocks of ammunition are fielded for use, propellant degradation may be of concern.Degraded propellants may result in either increased or decreased chamber pressures, depending on formulation(thus deviating... When older stocks of ammunition are fielded for use, propellant degradation may be of concern.Degraded propellants may result in either increased or decreased chamber pressures, depending on formulation(thus deviating from expected performance), or in the worst-case scenario, auto-ignition.Data is sparse regarding propellants aged naturally in manufactured ammunition. Propellant harvested from 1953 U S. military 30-06 M2 AP rifle cartridges and from 2012 U S. military M855A1 rifle cartridgs was evaluated using thermochemical techniques and field testing. Thermochemical results were also compared with two 2022-era ball propellants(Winchester 748 and Hodgdon BL-C(2)). Thermal analysis demonstrated similar energy densities between the 1953, 2012, and ca. 2022-era propellants,with minor changes in activation energy, suggesting slightly decreased propellant thermal stability in the1953 propellant. Chemical analysis supported this observation, with slightly decreased levels of stabilizer(still above accepted minimums) and increased levels of stabilizer byproducts in the 1953 propellant. For field testing, 0.223 Remington rifle cartridges were prepared for the 1953 and 2012 propellants utilizing the same match-grade components and a volume of the respective propellant to result in a muzzle velocity around 800 m/s. Accuracy characteristics and variation in projectile velocity were evaluated in a standardized competition course of fire. For each propellant, 20 rounds were shot from one bolt action rifle with a 1 in 8 inches twist, and 20 rounds were shot from another with a 1 in 7 inches twist. Results showed that the 1953-era propellant demonstrated comparable standard deviations in velocity and ontarget precision to the 2012-era propellant, and both resulted in comparable standard deviations in velocity and on-target performance to a modern extruded commercial reloading propellant. 展开更多
关键词 Propellant aging Propellant degradation m TGA GC-MS DSC
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基于反演模型的焦炉无组织苯并[a]芘排放因子研究 被引量:8
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作者 伯鑫 李时蓓 +4 位作者 吴忠祥 李重阳 商国栋 任昊 周北海 《中国环境科学》 EI CAS CSCD 北大核心 2016年第5期1340-1344,共5页
由于焦炉无组织苯并[a]芘排放因子难以测量,导致了焦炉苯并[a]芘大气污染研究存在一定的不确定性.针对上述问题,本研究根据1999年~2003年上海某焦化厂的产量、空气质量监测等数据,建立了基于AERMOD(AMS/EPA REGULATORY MODEL)模型反演苯... 由于焦炉无组织苯并[a]芘排放因子难以测量,导致了焦炉苯并[a]芘大气污染研究存在一定的不确定性.针对上述问题,本研究根据1999年~2003年上海某焦化厂的产量、空气质量监测等数据,建立了基于AERMOD(AMS/EPA REGULATORY MODEL)模型反演苯并[a]芘排放因子的方法.结果显示,企业周边3个监测点年平均浓度结果分别为0.033,0.0024,0.0031μg/m^3,均超过了2012年颁布的环境空气质量标准,通过AERMOD模型反演得到该焦化厂苯并[a]芘平均排放因子为14.71mg/t焦煤,苯并[a]芘预测浓度超标面积125km^2,超标区域主要集中在焦化厂周围,超标焦炉苯并[a]芘防护距离为6300m. 展开更多
关键词 排放因子 苯并[A]芘 焦炉 反演模型 AERMOD
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Shock tube design for high intensity blast waves for laboratory testing of armor and combat materiel 被引量:7
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作者 Elijah COURTNEY Amy COURTNEY Michael COURTNEY 《Defence Technology(防务技术)》 SCIE EI CAS 2014年第2期245-250,共6页
Shock tubes create simulated blast waves which can be directed and measured lo study blast wave effects under laboratory conditions.It is desirable to increase available peak pressure from ~1 MPa to ~5 MPa to simulate... Shock tubes create simulated blast waves which can be directed and measured lo study blast wave effects under laboratory conditions.It is desirable to increase available peak pressure from ~1 MPa to ~5 MPa to simulate closer blast sources and facilitate development and testing of personal and vehicle armors.Three methods are experimentally investigated to increase peak simulated blast pressure produced by an oxyacetylene driven shock tube while maintaining suitability for laboratory studies.The first method is the addition of a Shchelkin spiral priming section which supports a deflagration to detonation transition.This approach increases the average peak pressure from 1.17 MPa to 5.33 MPa while maintaining a relevant pressure-time curve(near Friedlander waveform).The second method is a bottleneck between the driving and driven sections.Coupling a 79 mm diameter driving section to a 53 mm driven section increases the peak pressure from 1.17 MPa to 2.25 MPa.A 103 mm driving section is used to increase peak pressure to 2.64 MPa.The third method,adding solid fuel to the driving section with the oxyacetylene,results in a peak pressure increasing to 1.70 MPa. 展开更多
关键词 实验室测试 激波管 冲击波 装甲 高强度 峰值压力 设计 物资
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