Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effecti...Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.展开更多
Many researchers have focused on the behavior of fiber-reinforced concrete(FRC)in the construction of various defensive structures to resist against impact forces resulting from explosions and projectiles.However,the ...Many researchers have focused on the behavior of fiber-reinforced concrete(FRC)in the construction of various defensive structures to resist against impact forces resulting from explosions and projectiles.However,the lack of sufficient research regarding the resistance of functionally graded fiber-reinforced concrete against projectile impacts has resulted in a limited understanding of the performance of this concrete type,which is necessary for the design and construction of structures requiring great resistance against external threats.Here,the performance of functionally graded fiber-reinforced concrete against projectile impacts was investigated experimentally using a(two-stage light)gas gun and a drop weight testing machine.For this objective,12 mix designs,with which 35 cylindrical specimens and 30 slab specimens were made,were prepared,and the main variables were the magnetite aggregate vol%(55%)replacing natural coarse aggregate,steel fiber vol%,and steel fiber type(3D and 5D).The fibers were added at six vol%of 0%,0.5%,0.75%,1%,1.25%,and 1.5%in 10 specimen series(three identical specimens per each series)with dimensions of 40×40×7.5 cm and functional grading(three layers),and the manufactured specimens were subjected to the drop weight impact and projectile penetration tests by the drop weight testing machine and gas gun,respectively,to assess their performance.Parameters under study included the compressive strength,destruction level,and penetration depth.The experimental results demonstrate that using the magnetite aggregate instead of the natural coarse aggregate elevated the compressive strength of the concrete by 61%.In the tests by the drop weight machine,it was observed that by increasing the total vol%of the fibers,especially by increasing the fiber content in the outer layers(impact surface),the cracking resistance and energy absorption increased by around 100%.Note that the fiber geometry had little effect on the energy absorption in the drop weight test.Investigating the optimum specimens showed that using 3D steel fibers at a total fiber content of 1 vol%,consisting of a layered grading of 1.5 vol%,0 vol%,and 1.5 vol%,improved the penetration depth by 76%and lowered the destruction level by 85%.In addition,incorporating the 5D steel fibers at a total fiber content of 1 vol%,consisting of the layered fiber contents of 1.5%,0%,and 1.5%,improved the projectile penetration depth by 50%and lowered the damage level by 61%compared with the case of using the 3D fibers.展开更多
Selective laser melting(SLM)is a cost-effective 3 D metal additive manufacturing(AM)process.However,AM 316 L stainless steel(SS)has different surface and microstructure properties as compared to conventional ones.Bori...Selective laser melting(SLM)is a cost-effective 3 D metal additive manufacturing(AM)process.However,AM 316 L stainless steel(SS)has different surface and microstructure properties as compared to conventional ones.Boriding process is one of the ways to modify and increase the surface properties.The aim of this study is to predict and understand the growth kinetic of iron boride layers on AM 316 L SS.In this study,the growth kinetic mechanism was evaluated for AM 316 L SS.Pack boriding was applied at 850,900 and 950℃,each for 2,4 and 6 h.The thickness of the boride layers ranged from(1.8±0.3)μm to(27.7±2.2)μm.A diffusion model based on error function solutions in Fick’s second law was proposed to quantitatively predict and elucidate the growth rate of FeB and Fe_(2)B phase layers.The activation energy(Q)values for boron diffusion in FeB layer,Fe_(2)B layer,and dual FeB+Fe_(2)B layer were found to be 256.56,161.61 and 209.014 kJ/mol,respectively,which were higher than the conventional 316 L SS.The findings might provide and open new directions and approaches for applications of additively manufactured steels.展开更多
This research addresses the growing demand for high-performance protective materials against high-velocity projectile impacts.The performance of multi-layered steel fiber-reinforced mortar(SFRM)panels with varying thi...This research addresses the growing demand for high-performance protective materials against high-velocity projectile impacts.The performance of multi-layered steel fiber-reinforced mortar(SFRM)panels with varying thicknesses and air gaps,was experimentally investigated under single and repeated impacts of 7.62×51 mm bullets fired from a distance of 50 m.The impact events were recorded using a high-speed camera at 40000 fps.Panel performance was assessed in terms of failure modes,kinetic energy absorption,spalling diameter,and percentage of back-face damage area,and weight loss.Results showed that panel configuration significantly influenced performance.Panel P10,with 70 mm SFRM thickness and 20 mm air gaps,provided the highest resistance,dissipating 5223 J of kinetic energy and preventing back-face damage.In contrast,P7,which absorbed 4476 J,presented a back damage area percentage of 8.93%after three impacts.Weight loss analysis further confirmed durability improvements,with P10 showing only 1.53%cumulative loss compared to 3.26%in P7.The inclusion of wider air gaps enhanced energy dissipation and reduced damage.Comparison between single and repeated impacts demonstrated the sustained resistance of high-performance panels,with P10 maintaining minimal degradation across three consecutive impacts.These findings highlight the potential of multi-layer SFRM panels to enhance ballistic resistance,making them suitable for military,security,and civilian protective applications requiring long-term durability.展开更多
The design of unmanned aerial vehicles(UAVs)revolves around the careful selection of materials that are both lightweight and robust.Carbon fiber-reinforced polymer(CFRP)emerged as an ideal option for wing construction...The design of unmanned aerial vehicles(UAVs)revolves around the careful selection of materials that are both lightweight and robust.Carbon fiber-reinforced polymer(CFRP)emerged as an ideal option for wing construction,with its mechanical qualities thoroughly investigated.In this study,we developed and optimized a conceptual UAV wing to withstand structural loads by establishing progressive composite stacking sequences,and we conducted a series of experimental characterizations on the resulting material.In the optimization phase,the objective was defined as weight reduction,while the Hashin damage criterion was established as the constraint for the optimization process.The optimization algorithm adaptively monitors regional damage criterion values,implementing necessary adjustments to facilitate the mitigation process in a cost-effective manner.Optimization of the analytical model using Simulia Abaqus~(TM)and a Python-based user-defined sub-routine resulted in a 34.7%reduction in the wing's structural weight after 45 iterative rounds.Then,the custom-developed optimization algorithm was compared with a genetic algorithm optimization.This comparison has demonstrated that,although the genetic algorithm explores numerous possibilities through hybridization,the custom-developed algorithm is more result-oriented and achieves optimization in a reduced number of steps.To validate the structural analysis,test specimens were fabricated from the wing's most critically loaded segment,utilizing the identical stacking sequence employed in the optimization studies.Rigorous mechanical testing revealed unexpectedly high compressive strength,while tensile and bending strengths fell within expected ranges.All observed failure loads remained within the established safety margins,thereby confirming the reliability of the analytical predictions.展开更多
Functionally graded composite/hybrid materials(FGCM/FGHCM)were produced by adding B_(4)C,TiO_(2),and B_(4)C+TiO_(2)ceramic materials at various ratios(0-50%)into the AA6082 matrix.The analysis of the damage caused by^...Functionally graded composite/hybrid materials(FGCM/FGHCM)were produced by adding B_(4)C,TiO_(2),and B_(4)C+TiO_(2)ceramic materials at various ratios(0-50%)into the AA6082 matrix.The analysis of the damage caused by^(60) ions'(1.173-1.1332 MeV)on the material was examined using the SRIM/TRIM Monte Carlo simulation software.In the simulation,the following data regarding the atoms of the target materials were obtained:ion distribution,target ionization,total displacements,surface binding energy,lattice binding energy,and displacement energy.Among the studied four materials,the one with the highest ion range value was found to be AA6082 with 8550A.TiO_(2)was found to be the reinforcement material that reduced the ion range the most in the material.Due to its high binding energy,B_(4)C reinforced AA6082+(0-50%)B_(4)C FGCM was found to have the least vacancy with 4782/ion.展开更多
Because of an unfortunate mistake during the production of this article,the Acknowledgements have been omitted.The Acknowledgements are added as follows:Sasan YAZDANI would like to thank the Scientific and Technologic...Because of an unfortunate mistake during the production of this article,the Acknowledgements have been omitted.The Acknowledgements are added as follows:Sasan YAZDANI would like to thank the Scientific and Technological Research Council of Turkey(TÜB˙ITAK)for receiving financial support for this work through the 2221 Fellowship Program for Visiting Scientists and Scientists on Sabbatical Leave(Grant ID:E 21514107-115.02-228864).Sasan YAZDANI also expresses his gratitude to Sahand University of Technology for granting him sabbatical leave to facilitate the completion of this research.展开更多
Detection of target analytes at low concentrations is significant in various fields,including pharmaceuticals,healthcare,and environmental protection.Theophylline(TP),a natural alkaloid used as a bronchodilator to tre...Detection of target analytes at low concentrations is significant in various fields,including pharmaceuticals,healthcare,and environmental protection.Theophylline(TP),a natural alkaloid used as a bronchodilator to treat respiratory disorders such as asthma,bronchitis,and emphysema,has a narrow therapeutic window with a safe plasma concentration ranging from 55.5-111.0μmol·L^(-1)in adults.Accurate monitoring of TP levels is essential because too low or too high can cause se-rious side effects.In this regard,non-enzymatic electrochemical sensors offer a practical solution with rapidity,portability,and high sensitivity.This article aims to provide a comprehensive review of the recent developments of non-enzymatic electrochemical sensors for TP detection,highlighting the basic principles,electro-oxidation mechanisms,catalytic effects,and the role of modifying materials on electrode performance.Carbon-based electrodes such as glassy carbon electrodes(GCEs),carbon paste electrodes(CPEs),and carbon screen-printed electrodes(SPCEs)have become the primary choices for non-enzymatic sensors due to their chemical stability,low cost,and flexibility in modification.This article identifies the sig-nificant contribution of various modifying materials,including nanomaterials such as carbon nanotubes(CNTs),graphene,metal oxides,and multi-element nanocomposites.These modifications enhance sensors’electron transfer,sensitivity,and selectivity in detecting TP at low concentrations in complex media such as blood plasma and pharmaceutical samples.The electro-oxidation mechanism of TP is also discussed in depth,emphasizing the hydroxyl and carbonyl reaction pathways strongly influenced by pH and electrode materials.These mechanisms guide the selection of the appropriate electrode ma-terial for a particular application.The main contribution of this article is to identify superior modifying materials that can improve the performance of non-enzymatic electrochemical sensors.In a recent study,the combination of multi-element nanocomposites based on titanium dioxide(TiO_(2)),CNTs,and gold nanoparticles(AuNPs)resulted in the lowest detection limit of 3×10^(-5)μmol·L^(-1),reflecting the great potential of these materials for developing high-performance electrochemical sensors.The main conclusion of this article is the importance of a multidisciplinary approach in electrode material design to support the sensitivity and selectivity of TP detection.In addition,there is still a research gap in understanding TP’s more detailed oxidation mechanism,especially under pH variations and complex environments.Therefore,further research on electrode modification and analysis of the TP oxidation mechanism are urgently needed to improve the accuracy and sta-bility of the sensor while expanding its applications in pharmaceutical monitoring and medical diagnostics.By integrating various innovative materials and technical approaches,this review is expected to be an essential reference for developing efficient and affordable non-enzymatic electrochemical sensors.展开更多
文摘Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.
文摘Many researchers have focused on the behavior of fiber-reinforced concrete(FRC)in the construction of various defensive structures to resist against impact forces resulting from explosions and projectiles.However,the lack of sufficient research regarding the resistance of functionally graded fiber-reinforced concrete against projectile impacts has resulted in a limited understanding of the performance of this concrete type,which is necessary for the design and construction of structures requiring great resistance against external threats.Here,the performance of functionally graded fiber-reinforced concrete against projectile impacts was investigated experimentally using a(two-stage light)gas gun and a drop weight testing machine.For this objective,12 mix designs,with which 35 cylindrical specimens and 30 slab specimens were made,were prepared,and the main variables were the magnetite aggregate vol%(55%)replacing natural coarse aggregate,steel fiber vol%,and steel fiber type(3D and 5D).The fibers were added at six vol%of 0%,0.5%,0.75%,1%,1.25%,and 1.5%in 10 specimen series(three identical specimens per each series)with dimensions of 40×40×7.5 cm and functional grading(three layers),and the manufactured specimens were subjected to the drop weight impact and projectile penetration tests by the drop weight testing machine and gas gun,respectively,to assess their performance.Parameters under study included the compressive strength,destruction level,and penetration depth.The experimental results demonstrate that using the magnetite aggregate instead of the natural coarse aggregate elevated the compressive strength of the concrete by 61%.In the tests by the drop weight machine,it was observed that by increasing the total vol%of the fibers,especially by increasing the fiber content in the outer layers(impact surface),the cracking resistance and energy absorption increased by around 100%.Note that the fiber geometry had little effect on the energy absorption in the drop weight test.Investigating the optimum specimens showed that using 3D steel fibers at a total fiber content of 1 vol%,consisting of a layered grading of 1.5 vol%,0 vol%,and 1.5 vol%,improved the penetration depth by 76%and lowered the destruction level by 85%.In addition,incorporating the 5D steel fibers at a total fiber content of 1 vol%,consisting of the layered fiber contents of 1.5%,0%,and 1.5%,improved the projectile penetration depth by 50%and lowered the damage level by 61%compared with the case of using the 3D fibers.
文摘Selective laser melting(SLM)is a cost-effective 3 D metal additive manufacturing(AM)process.However,AM 316 L stainless steel(SS)has different surface and microstructure properties as compared to conventional ones.Boriding process is one of the ways to modify and increase the surface properties.The aim of this study is to predict and understand the growth kinetic of iron boride layers on AM 316 L SS.In this study,the growth kinetic mechanism was evaluated for AM 316 L SS.Pack boriding was applied at 850,900 and 950℃,each for 2,4 and 6 h.The thickness of the boride layers ranged from(1.8±0.3)μm to(27.7±2.2)μm.A diffusion model based on error function solutions in Fick’s second law was proposed to quantitatively predict and elucidate the growth rate of FeB and Fe_(2)B phase layers.The activation energy(Q)values for boron diffusion in FeB layer,Fe_(2)B layer,and dual FeB+Fe_(2)B layer were found to be 256.56,161.61 and 209.014 kJ/mol,respectively,which were higher than the conventional 316 L SS.The findings might provide and open new directions and approaches for applications of additively manufactured steels.
基金funded by Thailand Research Fund under Research and Researchers for Industries (contract no. MSD62I0063)
文摘This research addresses the growing demand for high-performance protective materials against high-velocity projectile impacts.The performance of multi-layered steel fiber-reinforced mortar(SFRM)panels with varying thicknesses and air gaps,was experimentally investigated under single and repeated impacts of 7.62×51 mm bullets fired from a distance of 50 m.The impact events were recorded using a high-speed camera at 40000 fps.Panel performance was assessed in terms of failure modes,kinetic energy absorption,spalling diameter,and percentage of back-face damage area,and weight loss.Results showed that panel configuration significantly influenced performance.Panel P10,with 70 mm SFRM thickness and 20 mm air gaps,provided the highest resistance,dissipating 5223 J of kinetic energy and preventing back-face damage.In contrast,P7,which absorbed 4476 J,presented a back damage area percentage of 8.93%after three impacts.Weight loss analysis further confirmed durability improvements,with P10 showing only 1.53%cumulative loss compared to 3.26%in P7.The inclusion of wider air gaps enhanced energy dissipation and reduced damage.Comparison between single and repeated impacts demonstrated the sustained resistance of high-performance panels,with P10 maintaining minimal degradation across three consecutive impacts.These findings highlight the potential of multi-layer SFRM panels to enhance ballistic resistance,making them suitable for military,security,and civilian protective applications requiring long-term durability.
基金supported by the Istanbul Technical University Office of Scientific Research Projects(ITUBAPSIS),under grant MYL-2022-43776。
文摘The design of unmanned aerial vehicles(UAVs)revolves around the careful selection of materials that are both lightweight and robust.Carbon fiber-reinforced polymer(CFRP)emerged as an ideal option for wing construction,with its mechanical qualities thoroughly investigated.In this study,we developed and optimized a conceptual UAV wing to withstand structural loads by establishing progressive composite stacking sequences,and we conducted a series of experimental characterizations on the resulting material.In the optimization phase,the objective was defined as weight reduction,while the Hashin damage criterion was established as the constraint for the optimization process.The optimization algorithm adaptively monitors regional damage criterion values,implementing necessary adjustments to facilitate the mitigation process in a cost-effective manner.Optimization of the analytical model using Simulia Abaqus~(TM)and a Python-based user-defined sub-routine resulted in a 34.7%reduction in the wing's structural weight after 45 iterative rounds.Then,the custom-developed optimization algorithm was compared with a genetic algorithm optimization.This comparison has demonstrated that,although the genetic algorithm explores numerous possibilities through hybridization,the custom-developed algorithm is more result-oriented and achieves optimization in a reduced number of steps.To validate the structural analysis,test specimens were fabricated from the wing's most critically loaded segment,utilizing the identical stacking sequence employed in the optimization studies.Rigorous mechanical testing revealed unexpectedly high compressive strength,while tensile and bending strengths fell within expected ranges.All observed failure loads remained within the established safety margins,thereby confirming the reliability of the analytical predictions.
基金the Scientific Research Projects Office of Gazi University,Turkiye(Grant Nos.FGA-2022-7521 and FKA-2023-8617)the financial support of TUBITAK 2211-C and YOK 100/2000 programs。
文摘Functionally graded composite/hybrid materials(FGCM/FGHCM)were produced by adding B_(4)C,TiO_(2),and B_(4)C+TiO_(2)ceramic materials at various ratios(0-50%)into the AA6082 matrix.The analysis of the damage caused by^(60) ions'(1.173-1.1332 MeV)on the material was examined using the SRIM/TRIM Monte Carlo simulation software.In the simulation,the following data regarding the atoms of the target materials were obtained:ion distribution,target ionization,total displacements,surface binding energy,lattice binding energy,and displacement energy.Among the studied four materials,the one with the highest ion range value was found to be AA6082 with 8550A.TiO_(2)was found to be the reinforcement material that reduced the ion range the most in the material.Due to its high binding energy,B_(4)C reinforced AA6082+(0-50%)B_(4)C FGCM was found to have the least vacancy with 4782/ion.
文摘Because of an unfortunate mistake during the production of this article,the Acknowledgements have been omitted.The Acknowledgements are added as follows:Sasan YAZDANI would like to thank the Scientific and Technological Research Council of Turkey(TÜB˙ITAK)for receiving financial support for this work through the 2221 Fellowship Program for Visiting Scientists and Scientists on Sabbatical Leave(Grant ID:E 21514107-115.02-228864).Sasan YAZDANI also expresses his gratitude to Sahand University of Technology for granting him sabbatical leave to facilitate the completion of this research.
基金the funding from Lembaga Penelitian dan Pengabdian Masyarakat(LPPM)Universitas Indonesia,by Riset Kolaborasi Indonesia(RKI)-World Class University(WCU)Program with grant number NKB-1067/UN2-RST/HKP.05.00/2023 and NKB-781/UN2.RST/HKP.05.00/2024.
文摘Detection of target analytes at low concentrations is significant in various fields,including pharmaceuticals,healthcare,and environmental protection.Theophylline(TP),a natural alkaloid used as a bronchodilator to treat respiratory disorders such as asthma,bronchitis,and emphysema,has a narrow therapeutic window with a safe plasma concentration ranging from 55.5-111.0μmol·L^(-1)in adults.Accurate monitoring of TP levels is essential because too low or too high can cause se-rious side effects.In this regard,non-enzymatic electrochemical sensors offer a practical solution with rapidity,portability,and high sensitivity.This article aims to provide a comprehensive review of the recent developments of non-enzymatic electrochemical sensors for TP detection,highlighting the basic principles,electro-oxidation mechanisms,catalytic effects,and the role of modifying materials on electrode performance.Carbon-based electrodes such as glassy carbon electrodes(GCEs),carbon paste electrodes(CPEs),and carbon screen-printed electrodes(SPCEs)have become the primary choices for non-enzymatic sensors due to their chemical stability,low cost,and flexibility in modification.This article identifies the sig-nificant contribution of various modifying materials,including nanomaterials such as carbon nanotubes(CNTs),graphene,metal oxides,and multi-element nanocomposites.These modifications enhance sensors’electron transfer,sensitivity,and selectivity in detecting TP at low concentrations in complex media such as blood plasma and pharmaceutical samples.The electro-oxidation mechanism of TP is also discussed in depth,emphasizing the hydroxyl and carbonyl reaction pathways strongly influenced by pH and electrode materials.These mechanisms guide the selection of the appropriate electrode ma-terial for a particular application.The main contribution of this article is to identify superior modifying materials that can improve the performance of non-enzymatic electrochemical sensors.In a recent study,the combination of multi-element nanocomposites based on titanium dioxide(TiO_(2)),CNTs,and gold nanoparticles(AuNPs)resulted in the lowest detection limit of 3×10^(-5)μmol·L^(-1),reflecting the great potential of these materials for developing high-performance electrochemical sensors.The main conclusion of this article is the importance of a multidisciplinary approach in electrode material design to support the sensitivity and selectivity of TP detection.In addition,there is still a research gap in understanding TP’s more detailed oxidation mechanism,especially under pH variations and complex environments.Therefore,further research on electrode modification and analysis of the TP oxidation mechanism are urgently needed to improve the accuracy and sta-bility of the sensor while expanding its applications in pharmaceutical monitoring and medical diagnostics.By integrating various innovative materials and technical approaches,this review is expected to be an essential reference for developing efficient and affordable non-enzymatic electrochemical sensors.
