This paper reports statistical results of Seismo-Ionospheric Anomalies(SIAs) of the Total Electron Content(TEC) in the Global Ionosphere Map(GIM) associated with 56 M≥6.0 earthquakes in China during 1998—2012.To det...This paper reports statistical results of Seismo-Ionospheric Anomalies(SIAs) of the Total Electron Content(TEC) in the Global Ionosphere Map(GIM) associated with 56 M≥6.0 earthquakes in China during 1998—2012.To detect SIA,a quartile-based(i.e.median-based) process is performed.TEC anomalies for the period of earthquakes without being led by magnetic storms about 10 days are further isolated and examined to confirm the SIP existence.Results show that SIA is the TEC significantly decrease in the afternoon period 2—9 days before the earthquakes in China,which is in a good agreement with the SIA appearing before the 12 May 2008 M 8.0 Wenchuan earthquake.展开更多
In order to examine the factors which affect the range of heat transfer in earth surrounding subways, FLAC3D was adopted in this study to analyze these factors, under different conditions, in a systematic manner. When...In order to examine the factors which affect the range of heat transfer in earth surrounding subways, FLAC3D was adopted in this study to analyze these factors, under different conditions, in a systematic manner. When we compare these numerical tests, the results show that the main factors, affecting the heat transfer range are the thermal properties of the surrounding earth, the initial ground temperature and the temperature in the tunnel. The heat transfer coefficient between air and linings has little effect on the temperature distribution around the tunnel. The current results can provide a reference for improving the thermal environment in subways and optimizing the design of subwav ventilation and air conditioning.展开更多
The development of passive NO_(x)adsorbers with cost-benefit and high NO_(x)storage capacity remains an on-going challenge to after-treatment technologies at lower temperatures associated with cold-start NO_(x)emissio...The development of passive NO_(x)adsorbers with cost-benefit and high NO_(x)storage capacity remains an on-going challenge to after-treatment technologies at lower temperatures associated with cold-start NO_(x)emissions.Herein,Cs_(1)Mg_(3)Al catalyst prepared by sol-gel method was cyclic tested in NO_(x)storage under 5 vol%water.At 100°C,the NO_(x)storage capacity(1219 μmol g^(-1))was much higher than that of Pt/BaO/Al_(2)O_(3)(610 μmol g^(-1)).This provided new insights for non-noble metal catalysts in low-temperature passive NO_(x)adsorption.The addition of Cs improved the mobility of oxygen species and thus improved the NO_(x)storage capacity.The XRD,XPS,IR spectra and in situ DRIFTs with NH3 probe showed an interaction between CsO_(x)and AlO_(x)sites via oxygen species formed on Cs_(1)Mg_(3)Al catalyst.The improved mobility of oxygen species inferred from O2-TPD was consistent with high NO_(x)storage capacity related to enhanced formation of nitrate and additional nitrite species by NO_(x)oxidation.Moreover,the addition of Mg might improve the stability of Cs_(1)Mg_(3)Al by stabilizing surface active oxygen species in cyclic experiments.展开更多
Our research is centered on the Gandhar oil field, which was discovered in 1983, where daily oil production has declined significantly over the years. The primary objective was to evaluate the feasibility of carbon di...Our research is centered on the Gandhar oil field, which was discovered in 1983, where daily oil production has declined significantly over the years. The primary objective was to evaluate the feasibility of carbon dioxide(CO_(2)) storage through its injection into the siliciclastic reservoirs of Ankleshwar Formation. We aimed to obtain high-resolution acoustic impedance data to estimate porosity employing model-based poststack seismic inversion. We conducted an analysis of the density and effective porosity in the target zone through geostatistical techniques and probabilistic neural networks. Simultaneously, the work also involved geomechanical analysis through the computation of pore pressure and fracture gradient using well-log data, geological information, and drilling events in the Gandhar field. Our investigation unveiled spatial variations in effective porosity within the Hazad Member of the Ankleshwar Formation, with an effective porosity exceeding 25% observed in several areas, which indicates the presence of well-connected pore spaces conducive to efficient CO_(2) migration. Geomechanical analysis showed that the vertical stress(Sv) ranged from 55 MPa to 57 MPa in Telwa and from 63.7 MPa to 67.7 MPa in Hazad Member. The pore pressure profile displayed variations along the stratigraphic sequence, with the shale zone, particularly in the Kanwa Formation, attaining the maximum pressure gradient(approximately 36 MPa). However, consistently low pore pressure values(30-34 MPa) considerably below the fracture gradient curves were observed in Hazad Member due to depletion. The results from our analysis provide valuable insights into shaping future field development strategies and exploration of the feasibility of CO_(2) sequestration in Gandhar Field.展开更多
Geophysical surveys are frequently applied in mining prospection to detect the presence and volume of ore bodies of different nature.Particularly,in gypsum ore bodies exploitation,electrical resistivity measurements a...Geophysical surveys are frequently applied in mining prospection to detect the presence and volume of ore bodies of different nature.Particularly,in gypsum ore bodies exploitation,electrical resistivity measurements are usually the most used methodology.However,it has been observed that different electrical resistivity values can be obtained depending on geometrical features and composition of gypsum.Indeed,electrical resistivity of gypsum rocks depends on several parameters,such as gypsum purity,nature of secondary minerals,porosity,saturation and interstitial fluid properties.Saturation and hydrogeological setting,in particular,were recognized as the most influencing parameters.Hydrogeological conditions of gypsum rock masses are also very relevant for exploitability,safety conditions and economic feasibility and should be accurately known during the prospection and planning phases of the quarries.In this work,a relationship between electrical resistivity and saturation degree of gypsum is proposed.The possibility to estimate gypsum porosity with the use of this relationship is also investigated.The reliability of laboratory measurements is finally verified in comparison with field and modelled resistivity data.The reported results underline the potentiality of the proposed approach to obtain a reliable characterization of the studied ore body.展开更多
The oolitic shoal reservoirs of the Lower Triassic Feixianguan Formation carbonates in the Sichuan Basin of southwest China are an important target for gas exploration in the basin.Their occurrence,like other cases wo...The oolitic shoal reservoirs of the Lower Triassic Feixianguan Formation carbonates in the Sichuan Basin of southwest China are an important target for gas exploration in the basin.Their occurrence,like other cases worldwide,can be divided into two locations in general,i.e.,platform interior and platform margin locations.Their differences of reservoir features and origins,however,have not been investigated comprehensively due to different exploration degrees.This issue is addressed in this paper,to provide basic data and information for the basin's hydrocarbon exploration and for the study of carbonate platform sedimentology and reservoir geology worldwide.We compared the features of these two types of reservoirs in detail,including the depositional and diagenetic features,pore types and petrophysical features.Based on the comparison,the origin of the reservoirs was further discussed.It is shown that the reservoirs in platform interior and platform margin locations differ significantly.The interior carbonates were deposited in moderate to high energy settings and the dominant lithologic type was limestone,which was weakly compacted and intensely cemented and has undergone meteoric dissolution.Pore types include intragranular dissolution and moldic pores,with low porosities(6%) and low permeabilities(0.1 mD).By contrast,the platform margin carbonates were deposited in relatively high energy settings and mainly consisted of dolostones with some limestones.The rocks were strongly compacted but incompletely cemented.As a result,some primary intergranular pores were preserved.Both meteoric solution and burial solution have taken place.There are various types of pore spaces including intergranular and intercrystalline solution pores and residual intergranular pores.This type of reservoir generally has better petrophysical properties(9% porosity and 0.1 mD permeability) and pore-throat structures than the interior reservoirs.These differences were influenced by both primary depositional features and secondary diagenesis.For the interior carbonate reservoirs,early meteoric dissolution,weak compaction and strong cementation are important controlling factors.By contrast,the factors controlling the formation of the margin carbonate reservoirs mainly include dolomitization,preservation of primary pores and burial dissolution.展开更多
Various orders of sequences were recognized in the Tarim Basin from unconformities. Three mega-sequence groups, six mega-sequences, sixteen super-sequences and forty-two sequences were determined from the Sinian to th...Various orders of sequences were recognized in the Tarim Basin from unconformities. Three mega-sequence groups, six mega-sequences, sixteen super-sequences and forty-two sequences were determined from the Sinian to the Quaternary. The mega-sequences and super-sequences were in accordance with the locally tectonic events occurring in both the north and the south margins of the Tarim plate. The global sea level changes only worked to control formations in the tectonically stable periods or in the low order sequences. The sequences had close relationship to the source rocks, reservoirs and cap rocks, and the tectonic events determined the migration, accumulation, and preservation of the hydrocarbon. The three mega-sequence group cycles, including the early cycle-the Sinian-middle Devonian, the middle cycle-the upper Devonian-Triassic, and the late cycle-the Jurassic-Quaternary, corresponded to three reservoir formation cycles. So, it can be concluded that the local tectonic events controlled both the sequences and the distribution of oil and gas in the Tarim Basin.展开更多
To investigate the resist-decreasing effects of rock bolts on the strength of the rock mass around a roadway, a compara- tive study has been carded out using the numerical analysis code FLAC3D. An unsupported and a ro...To investigate the resist-decreasing effects of rock bolts on the strength of the rock mass around a roadway, a compara- tive study has been carded out using the numerical analysis code FLAC3D. An unsupported and a rock bolt supported model have been built for comparison. Two types of rock mass strength, the uniaxial compressive strength (UCS) and the wiaxial compressive strength (TCS) of rock mass have been obtained from each model, using a prepared Fish based on the Mohr-Coulomb criterion. The results indicate that when a roadway is excavated, both the UCS and TCS in a definite local rock mass around the roadway would inevitably decrease, no matter whether the roadway is supported or not. The major decreasing region did not settle in the middle of the roadway surface, but within a deeper horizon into the rock mass. The resist-decreasing effects of rock bolts both on the UCS and the TCS of rock mass around roadway are significant.展开更多
We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy me...We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy metals (Cr,Cu,Zn,Cd and Pb). The average concentrations of Cr,Cu,Zn,Cd and Pb of the 18 sampling locations were re-spectively 56.1,22.2,70.0,0.17 and 20.4 μg/g. Compared with their background values,the average concentrations of Zn and Cu in sediment samples from the Huaihe River were slightly higher,while the average concentrations of Cr and Pb were slightly lower. The concentration of Cd in all sediment samples was higher than its background value,while the average concentration of Cd in all sediment samples was about twice the amount of the background value. The concen-tration of the five heavy metals was lower than that of the Yangtze River. A correlation analysis revealed that heavy metals have similar geochemical feautures. The geo-accumulation index (Igeo) was used to evaluate the degree of pollu-tion of the Huaihe River sediments. The index reveals that the sediment samples are largely ranked from zero pollution to no to medium pollution.展开更多
In civil and mining operations that involve ground excavation and support, the loads are distributed between the ground and support depending on their relative stiffness. This paper presents the development of concept...In civil and mining operations that involve ground excavation and support, the loads are distributed between the ground and support depending on their relative stiffness. This paper presents the development of conceptual single-degree-of-freedom models, which are used to derive equations for estimating displacements and stresses for ground-support interaction problems encountered in pillars in room-andpillar mining(natural support system), and liners for circular vertical shafts(artificial support systems).For pillar assessment, mine-pillar interaction curves can be constructed using a double spring analogy.Additionally, the effectiveness of different support systems can be evaluated depending on their effect upon the mine-pillar system. For shaft design, an initial estimation of the required lining strength and thickness can be readily made based on a double ring analogue. For both problems, the results from the proposed approach compare well with those obtained by finite element numerical simulations.展开更多
The creep phenomenon of rocks is quite complex and the creep mechanisms are far from being well understood.Although laboratory creep tests have been carried out to determine the creep deformation of various rocks,thes...The creep phenomenon of rocks is quite complex and the creep mechanisms are far from being well understood.Although laboratory creep tests have been carried out to determine the creep deformation of various rocks,these tests are expensive and time-consuming.Nanoindentation creep tests,as an alternative method,can be performed to investigate the mechanical and viscoelastic properties of granite samples.In this study,the reduced Young’s modulus,hardness,fracture toughness,creep strain rate,stress exponent,activation volume and maximum creep displacement of common rock-forming minerals of granite were calculated from nanoindentation results.It was found that the hardness decreases with the increase of holding time and the initial decrease in hardness was swift,and then it decreased slowly.The stress exponent values obtained were in the range from 4.5 to 22.9,which indicates that dislocation climb is the creep deformation mechanism.In addition,fracture toughness of granite’s rock-forming minerals was calculated using energy-based method and homogenization method was adopted to upscale the micro-scale mechanical properties to macro-scale mechanical properties.Last but not least,both three-element Voigt model and Burgers model fit the nanoindentation creep curves well.This study is beneficial to the understanding of the long-term mechanical properties of rock samples from a microscale perspective,which is of great significance to the understanding of localized deformation processes of rocks.展开更多
The new recently demonstrated reserves of oil and gas in the Ordos basin are found at the top of petroliferous basins in China. Gas pools discovered in recent years in the Permian system have become the main natural g...The new recently demonstrated reserves of oil and gas in the Ordos basin are found at the top of petroliferous basins in China. Gas pools discovered in recent years in the Permian system have become the main natural gas resource in the basin. Therefore, synthetic research on fluid inclusions should be done in order to ascertain the pool-forming stage, the maturity of organic matters and the properties of Paleo-fluids. The main types of fluid inclusions in the Permian system in the basin include brine inclusions, carbon dioxide inclusions and organic inclusions. Homogenization temperatures (HT) of brine inclusions can be divided into four intervals: 66-83 ℃, 86-108 ℃, 112-138 ℃ and 142-153℃. The fluid inclusions in the interval of 112-138 ℃ are much more than that of other intervals, indicating that the second stage of hydrocarbon migration associated with the third temperature interval is the most important stage of gas pool formations. The fluid inclusion has extensive applications in the study of gas geology, not only in ascertaining the formation stage of gas pools, but also in estimating the maturity of organic matter and restoring Paleo-fluids. The result of testing the HT of brine inclusions shows that there are two stages of gas pool formations in the Permian system occurring +150 Ma and ±100 Ma. The maturity of organic matter is moderate to high, a conclusion based on the color of fluid inclusions (radiated by fluorescence). The high salinity of Paleo-fluids of the NaCI-H2O and CaCl2-H2O systems shows good preservation conditions of the Paleo-fluids. Two stages of reservoir filling, high maturity of organic matter and good preservation conditions are factors favorable for the formation and preservation of large-scale gas pools in the Permian system in the Ordos basin.展开更多
The advantage of high-resolution sequence stratigraphy, which takes base-levels as reference, is that it can be applied to continental depositional basins controlled by multiple factors and can effectively improve the...The advantage of high-resolution sequence stratigraphy, which takes base-levels as reference, is that it can be applied to continental depositional basins controlled by multiple factors and can effectively improve the accuracy and resolution of sequential stratigraphic analysis. Moreover, the principles of base-level cycles are also suitable for analyzing sequential stratigraphy in continental coal-bearing basins because of their accuracy in forecasting distribution of coal measures. By taking the Dongsheng coalfield in the Ordos basin as an example, the extensive application of base-level cycles in exploration and exploitation of coal is analyzed. The result shows that the Yan’an formation in the Dongsheng area is a long-term base-level cycle which is bordered by nonconformities and made up of five mid-term cycles and 13 short-term cycles. The long-term cycle and the mid-term cycles are obvious in comparison with a transverse profile. The episodic coal accumulation in the Mesozoic Ordos basin means that the deposition of primary matter (peat bogs) of coalification is discontinuous, periodical and cyclical in the evolution of the basin. The episodic accumulation of coal measures in the Yan’an stage is controlled by ascending-descending changes of a long-term cycle and middle-term cycles. Coal measures formed during the early and late periods of the long-term cycle are characterized by multiple layers, big cumulative thickness and poor continuity. Coal measures formed in the mid-term of the long cycle are dominated by good continuity, fewer layers and a small additive thickness, which is favorable for the accumulation of thick and continuous coal measures in the transition stage of mid term base-level cycles.展开更多
The Late Cretaceous tectonic upheaval was an important event during the evolution of the Qaidam Basin, resulting in the omission of the Upper Cretaceous in the whole basin and unconformities between the Paleogene sequ...The Late Cretaceous tectonic upheaval was an important event during the evolution of the Qaidam Basin, resulting in the omission of the Upper Cretaceous in the whole basin and unconformities between the Paleogene sequence and pre-K2 strata. Inte-grating geological and geophysical data, two different groups of Late Cretaceous faults were recognized in the study area, one group consisting of E-W extending strike-slip faults (e.g., the Maxian and Yema-Jinan faults in the Mahai area, which caused an E-W omission zone of Mesozoic), while the other one has NW-SE thrust faults, resulting in NW-SE fold-and-thrust belts. Considering the different strikes and scale of these two groups, a simple-shear model has been employed to explain this structural phenomenon. The NW-SE thrust faults were thought to be subsidiary to the E-W strike-slip faults. Putting this into the framework of the Cretaceous paleogeographic environment of central Asia, it is inferred that this tectonic event of the Qaidam Basin is a response to the continuous northward drifting of the India plate.展开更多
The characteristics of diffusion are essential to the transport of radionuclides through buffer/backfill materials, such as bentonite, which are commonly found in waste repositories. This study used through-diffusion ...The characteristics of diffusion are essential to the transport of radionuclides through buffer/backfill materials, such as bentonite, which are commonly found in waste repositories. This study used through-diffusion techniques to investigate the diffusion behavior of HTO and ^(99)TcO_4^- on GMZ bentonite of various densities. Diffusion rates were calculated by measuring the diffusion coefficients(De, Da), plotting breakthrough curves and interpreting experiment data. The apparent and effective diffusion coefficients of HTO ranged from(1.68 ± 0.40) 9 × 10^(-11) to(2.80 ± 0.62) 9 × 10^(-11) m^2/s and from(4.61 ±1.28) 9 × 10^(-12) to (16.2 ± 2.50) 9 × 10^(-12) m^2/s, respectively.The apparent and effective diffusion coefficients of^(99)TcO_4^-ranged from(5.26 ± 0.16) 9 × 10^-12to(7.78 ± 0.43) 9× 10^-12m^2/s and from(1.49 ± 0.002) 9 × 10^(-12) to(4.16 ±0.07) 9 × 10^(-12) m^2/s, respectively. The distribution coefficients of HTO and^(99)TcO_4^-ranged from(0.70 ± 0.12) 9× 10^(-2) to(1.36 ± 0.53) 9 × 10^(-2) mL/g and from(1.12 ±0.06) 9 × 10^(-2) to(5.79 ± 2.22) 9 × 10^(-2) mL/g, respectively.The Deand Kdvalues were shown to decrease with an increase in the bulk dry density of compacted bentonite. Our results show that HTO and ^(99)Tc could be considered nonsorbent radionuclides. The data obtained in this studyprovide a valuable reference for the safety assessment of waste repositories.展开更多
We analyze the excess area and depth to detachment method developed by Epard and Groshong (1993), and apply it to the sand box model of Ge et al (2004) to illustrate that inadequate consideration will affect the c...We analyze the excess area and depth to detachment method developed by Epard and Groshong (1993), and apply it to the sand box model of Ge et al (2004) to illustrate that inadequate consideration will affect the calculation of true depth to detachment. Using the data of Yu et al (2006) to fit linear regression lines, we obtain the depths to detachment of Kela-2, Misikantage anticline and Dongqiu-8 structures, 115.74km, 14.17km, and 75.48km below the reference level (Cretaceous bottom) respectively with the excess area intercept equal to zero. However, the calculation results of depth to detachment in Yu et al (2006) are based on excess area intercept unequal to zero.展开更多
Carbonaceous shale exposures of the Late Cretaceous Mamu Formation along Ifon-Uzebba road in western arm(Benin Flank) of Anambra Basin, southwestern Nigeria, were analyzed for bulk organic geochemical, molecular biolo...Carbonaceous shale exposures of the Late Cretaceous Mamu Formation along Ifon-Uzebba road in western arm(Benin Flank) of Anambra Basin, southwestern Nigeria, were analyzed for bulk organic geochemical, molecular biological and poly-aromatic hydrocarbon(PAH) compositions to investigate the organic matter source, paleo-depositional condition, thermal maturity and petroleum potential of the unit. The bulk organic geochemistry was determined using Leco and Rock-Eval pyrolysis analyses while the biomarkers and PAH compositions were investigated using gas chromatography-mass spectrometer(GC-MS).The bulk organic geochemical parameters of the shale samples showed total organic carbon(TOC)(1.11-6.03 wt%), S2(0.49-11.73 mg HC/g Rock), HI(38-242 mg HC/g TOC) and Tmax(425-435 C) indicating good to excellent hydrocarbon source-rock. Typical HI-Tmax diagram revealed the shale samples mostly in the gas-prone Type Ⅲ kerogen region with few gas and oil-prone Type Ⅱ-Ⅲ kerogen. The investigated biomarkers(n-alkane, isoprenoid, terpane, hopane, sterane) and PAH(alkylnaphthalene, methylphenanthrene and dibenzothiophene) indicated that the carbonaceous shales contain mix contributions of terrestrial and marine organic matter inputs that were deposited in a deltaic to shallow marine settings and preserved under relatively anoxic to suboxic conditions.Thermal maturity parameters computed from Rock-Eval pyrolysis, biomarkers(hopane, sterane) and PAH(alkylnaphthalene, alkylphenanthrene, alkyldibenzothiophene) suggested that these carbonaceous shales in Anambra Basin have entered an early-mature stage for hydrocarbon generation. This is also supported by fluoranthene/pyrene(0.27-1.12), fluoranthene/(fluoranthene + pyrene)(0.21-0.53) ratios and calculated vitrinite reflectance values(0.49-0.63% Ro) indicative that these shales have mostly reached early oil window maturity, thereby having low hydrocarbon source potential.展开更多
The spacing–burden(S/B) ratio plays significant role on rock fragmentation and proper utilization of explosive energy to minimize the undesirable damage.Low S/B ratio generates fine fragments due to pressure rings co...The spacing–burden(S/B) ratio plays significant role on rock fragmentation and proper utilization of explosive energy to minimize the undesirable damage.Low S/B ratio generates fine fragments due to pressure rings coalescence of two blast holes,whereas boulder generations were observed above optimum S/B ratio.Both conditions are not acceptable because of wastage of explosive energy.Therefore,to resolve this issue,a numerical model study was conducted to optimize the S/B ratio and to envisage its effect on rock fragmentation based on utilization of explosive energy.Finite element simulation tool was used to see the extent of two blast hole influence area variation with varying S/B ratio.The better results were obtained at S/B ratio of 1:2 with optimum utilization of peak explosive energy.The performance was observed based on peak kinetic energy,peak pressure,radial and hoop stresses on centre of the two blast holes,where pressure rings coalescence.展开更多
The Palaeozoic carbonate basement of the Offshore Bohai Bay Basin (OBBB) presents considerable potential for hydrocarbon exploration. However, the multistage tectonism and complex superimposed palaeo-karstification in...The Palaeozoic carbonate basement of the Offshore Bohai Bay Basin (OBBB) presents considerable potential for hydrocarbon exploration. However, the multistage tectonism and complex superimposed palaeo-karstification in the area are unclear, which leads to a lack of understanding on the formation mechanism and distribution of the deep carbonate basement reservoirs. In this study, the occurrence of a fracture-vug network and its fillings in carbonate reservoirs were investigated based on borehole cores, thin sections, and image logs from the southwestern slope of the OBBB's Bozhong Sag. Then the diagenetic fluid properties of the carbonate matrix and fillings were analysed via the data of carbon, oxygen, and strontium isotopes, and major, rare elements from coring intervals. The results revealed that fracture-related karst reservoirs have lithologic selectivity inclined toward dolomite strata. The intersecting relationships, widths, and strikes of the fractures and the regional tectonic background indicate three structural fracture families: NW-, NNE-, and NNW- trending, related to the Indosinian, middle Yanshanian, and late Yanshanian orogeny, respectively. The Indosinian NW- and end-Mesozoic NNE-trending fractures produced by compressional tectonic stress mainly contributed to the formation of the basement reservoirs. The geochemistry of the calcite veins filling these fractures suggests two main types of diagenetic fluids. The fluid of autogenic recharge related to the earlier fills is karstification diffuse flow dominated by internal runoff from rainfall in the highland setting of the Indosinian thrusting orogenic belt. The other fluid of allogenic recharge related to the later fills is the main lateral freshwater flow dominated by external runoff from the catchment in the setting of the horst-lowland within the rifting basin, induced by the Yanshanian destruction of the North China Craton. Finally, the relationship between the three fracture families and two kinds of related fluids is revealed. This allows us to propose a model to understand the polyphase-superimposed fracture-related karst reservoir complexes within the deep carbonate basement of tilting fault blocks that neighbour the Bozhong hydrocarbon kitchen and predict the formation of potential plays with high accuracy.展开更多
Oils in Jinghu sag are abundant with high content of polar compounds and have a low ratio of saturate to aromatic hydrocarbons and a high ratio of resin to asphaltene. The gross composition of oils in the Jinghu sag s...Oils in Jinghu sag are abundant with high content of polar compounds and have a low ratio of saturate to aromatic hydrocarbons and a high ratio of resin to asphaltene. The gross composition of oils in the Jinghu sag suggests typical immature to low mature characteristics. Some compounds with low thermal stability were identified. Light hydrocarbons, a carbon preference index, an odd even index, n-alkane and hopane maturity parameters show mature features and little differences in the maturity level among oils. Sterane isomerization parameters indicate an immature to low mature status of oil. Transfer of the sedimentary center during sedimentation has led to different thermal histories among subsags and thus generated oils with different maturities. On the basis of source analyses, four migration and accumulation patterns with different maturity can be classified. Combined with available information on mergers of source, reservoir and long distance oil lateral migration, mixing conditions were present in the Jinghu sag. Experimental results indicate that maturity variations are caused by mixtures of hydrocarbons with different maturity.展开更多
文摘This paper reports statistical results of Seismo-Ionospheric Anomalies(SIAs) of the Total Electron Content(TEC) in the Global Ionosphere Map(GIM) associated with 56 M≥6.0 earthquakes in China during 1998—2012.To detect SIA,a quartile-based(i.e.median-based) process is performed.TEC anomalies for the period of earthquakes without being led by magnetic storms about 10 days are further isolated and examined to confirm the SIP existence.Results show that SIA is the TEC significantly decrease in the afternoon period 2—9 days before the earthquakes in China,which is in a good agreement with the SIA appearing before the 12 May 2008 M 8.0 Wenchuan earthquake.
基金Projects BK2007145 supported by the Jiangsu Natural Science Foundation of China NCET-04-0454 by the Program for New Century Excellent Talentsin Universities
文摘In order to examine the factors which affect the range of heat transfer in earth surrounding subways, FLAC3D was adopted in this study to analyze these factors, under different conditions, in a systematic manner. When we compare these numerical tests, the results show that the main factors, affecting the heat transfer range are the thermal properties of the surrounding earth, the initial ground temperature and the temperature in the tunnel. The heat transfer coefficient between air and linings has little effect on the temperature distribution around the tunnel. The current results can provide a reference for improving the thermal environment in subways and optimizing the design of subwav ventilation and air conditioning.
基金supported by the National Natural Science Foundation of China(Grant No.51938014,Grant No.22176217,Grant No.22276215)the Fundamental Research Funds for the Central Universities and the Research Funds of Renmin University of China(No.22XNKJ28).
文摘The development of passive NO_(x)adsorbers with cost-benefit and high NO_(x)storage capacity remains an on-going challenge to after-treatment technologies at lower temperatures associated with cold-start NO_(x)emissions.Herein,Cs_(1)Mg_(3)Al catalyst prepared by sol-gel method was cyclic tested in NO_(x)storage under 5 vol%water.At 100°C,the NO_(x)storage capacity(1219 μmol g^(-1))was much higher than that of Pt/BaO/Al_(2)O_(3)(610 μmol g^(-1)).This provided new insights for non-noble metal catalysts in low-temperature passive NO_(x)adsorption.The addition of Cs improved the mobility of oxygen species and thus improved the NO_(x)storage capacity.The XRD,XPS,IR spectra and in situ DRIFTs with NH3 probe showed an interaction between CsO_(x)and AlO_(x)sites via oxygen species formed on Cs_(1)Mg_(3)Al catalyst.The improved mobility of oxygen species inferred from O2-TPD was consistent with high NO_(x)storage capacity related to enhanced formation of nitrate and additional nitrite species by NO_(x)oxidation.Moreover,the addition of Mg might improve the stability of Cs_(1)Mg_(3)Al by stabilizing surface active oxygen species in cyclic experiments.
基金Supported by DST,Ministry of Science and Technology(Reference:DST/TMD/CCUS/Co E/2020/IITB (C))。
文摘Our research is centered on the Gandhar oil field, which was discovered in 1983, where daily oil production has declined significantly over the years. The primary objective was to evaluate the feasibility of carbon dioxide(CO_(2)) storage through its injection into the siliciclastic reservoirs of Ankleshwar Formation. We aimed to obtain high-resolution acoustic impedance data to estimate porosity employing model-based poststack seismic inversion. We conducted an analysis of the density and effective porosity in the target zone through geostatistical techniques and probabilistic neural networks. Simultaneously, the work also involved geomechanical analysis through the computation of pore pressure and fracture gradient using well-log data, geological information, and drilling events in the Gandhar field. Our investigation unveiled spatial variations in effective porosity within the Hazad Member of the Ankleshwar Formation, with an effective porosity exceeding 25% observed in several areas, which indicates the presence of well-connected pore spaces conducive to efficient CO_(2) migration. Geomechanical analysis showed that the vertical stress(Sv) ranged from 55 MPa to 57 MPa in Telwa and from 63.7 MPa to 67.7 MPa in Hazad Member. The pore pressure profile displayed variations along the stratigraphic sequence, with the shale zone, particularly in the Kanwa Formation, attaining the maximum pressure gradient(approximately 36 MPa). However, consistently low pore pressure values(30-34 MPa) considerably below the fracture gradient curves were observed in Hazad Member due to depletion. The results from our analysis provide valuable insights into shaping future field development strategies and exploration of the feasibility of CO_(2) sequestration in Gandhar Field.
文摘Geophysical surveys are frequently applied in mining prospection to detect the presence and volume of ore bodies of different nature.Particularly,in gypsum ore bodies exploitation,electrical resistivity measurements are usually the most used methodology.However,it has been observed that different electrical resistivity values can be obtained depending on geometrical features and composition of gypsum.Indeed,electrical resistivity of gypsum rocks depends on several parameters,such as gypsum purity,nature of secondary minerals,porosity,saturation and interstitial fluid properties.Saturation and hydrogeological setting,in particular,were recognized as the most influencing parameters.Hydrogeological conditions of gypsum rock masses are also very relevant for exploitability,safety conditions and economic feasibility and should be accurately known during the prospection and planning phases of the quarries.In this work,a relationship between electrical resistivity and saturation degree of gypsum is proposed.The possibility to estimate gypsum porosity with the use of this relationship is also investigated.The reliability of laboratory measurements is finally verified in comparison with field and modelled resistivity data.The reported results underline the potentiality of the proposed approach to obtain a reliable characterization of the studied ore body.
基金funded by the National Basic Research Development Program(973 project, Grant No. 2012CB214803)PetroChina Youth Innovation Foundation (Grant No. 2011D-5006-0105)Key Subject Construction Project of Sichuan Province, China(Grant No. SZD 0414)
文摘The oolitic shoal reservoirs of the Lower Triassic Feixianguan Formation carbonates in the Sichuan Basin of southwest China are an important target for gas exploration in the basin.Their occurrence,like other cases worldwide,can be divided into two locations in general,i.e.,platform interior and platform margin locations.Their differences of reservoir features and origins,however,have not been investigated comprehensively due to different exploration degrees.This issue is addressed in this paper,to provide basic data and information for the basin's hydrocarbon exploration and for the study of carbonate platform sedimentology and reservoir geology worldwide.We compared the features of these two types of reservoirs in detail,including the depositional and diagenetic features,pore types and petrophysical features.Based on the comparison,the origin of the reservoirs was further discussed.It is shown that the reservoirs in platform interior and platform margin locations differ significantly.The interior carbonates were deposited in moderate to high energy settings and the dominant lithologic type was limestone,which was weakly compacted and intensely cemented and has undergone meteoric dissolution.Pore types include intragranular dissolution and moldic pores,with low porosities(6%) and low permeabilities(0.1 mD).By contrast,the platform margin carbonates were deposited in relatively high energy settings and mainly consisted of dolostones with some limestones.The rocks were strongly compacted but incompletely cemented.As a result,some primary intergranular pores were preserved.Both meteoric solution and burial solution have taken place.There are various types of pore spaces including intergranular and intercrystalline solution pores and residual intergranular pores.This type of reservoir generally has better petrophysical properties(9% porosity and 0.1 mD permeability) and pore-throat structures than the interior reservoirs.These differences were influenced by both primary depositional features and secondary diagenesis.For the interior carbonate reservoirs,early meteoric dissolution,weak compaction and strong cementation are important controlling factors.By contrast,the factors controlling the formation of the margin carbonate reservoirs mainly include dolomitization,preservation of primary pores and burial dissolution.
文摘Various orders of sequences were recognized in the Tarim Basin from unconformities. Three mega-sequence groups, six mega-sequences, sixteen super-sequences and forty-two sequences were determined from the Sinian to the Quaternary. The mega-sequences and super-sequences were in accordance with the locally tectonic events occurring in both the north and the south margins of the Tarim plate. The global sea level changes only worked to control formations in the tectonically stable periods or in the low order sequences. The sequences had close relationship to the source rocks, reservoirs and cap rocks, and the tectonic events determined the migration, accumulation, and preservation of the hydrocarbon. The three mega-sequence group cycles, including the early cycle-the Sinian-middle Devonian, the middle cycle-the upper Devonian-Triassic, and the late cycle-the Jurassic-Quaternary, corresponded to three reservoir formation cycles. So, it can be concluded that the local tectonic events controlled both the sequences and the distribution of oil and gas in the Tarim Basin.
基金Project 2006BAK04B02 supported by the National Key Technology Research & Development Program of China
文摘To investigate the resist-decreasing effects of rock bolts on the strength of the rock mass around a roadway, a compara- tive study has been carded out using the numerical analysis code FLAC3D. An unsupported and a rock bolt supported model have been built for comparison. Two types of rock mass strength, the uniaxial compressive strength (UCS) and the wiaxial compressive strength (TCS) of rock mass have been obtained from each model, using a prepared Fish based on the Mohr-Coulomb criterion. The results indicate that when a roadway is excavated, both the UCS and TCS in a definite local rock mass around the roadway would inevitably decrease, no matter whether the roadway is supported or not. The major decreasing region did not settle in the middle of the roadway surface, but within a deeper horizon into the rock mass. The resist-decreasing effects of rock bolts both on the UCS and the TCS of rock mass around roadway are significant.
文摘We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy metals (Cr,Cu,Zn,Cd and Pb). The average concentrations of Cr,Cu,Zn,Cd and Pb of the 18 sampling locations were re-spectively 56.1,22.2,70.0,0.17 and 20.4 μg/g. Compared with their background values,the average concentrations of Zn and Cu in sediment samples from the Huaihe River were slightly higher,while the average concentrations of Cr and Pb were slightly lower. The concentration of Cd in all sediment samples was higher than its background value,while the average concentration of Cd in all sediment samples was about twice the amount of the background value. The concen-tration of the five heavy metals was lower than that of the Yangtze River. A correlation analysis revealed that heavy metals have similar geochemical feautures. The geo-accumulation index (Igeo) was used to evaluate the degree of pollu-tion of the Huaihe River sediments. The index reveals that the sediment samples are largely ranked from zero pollution to no to medium pollution.
文摘In civil and mining operations that involve ground excavation and support, the loads are distributed between the ground and support depending on their relative stiffness. This paper presents the development of conceptual single-degree-of-freedom models, which are used to derive equations for estimating displacements and stresses for ground-support interaction problems encountered in pillars in room-andpillar mining(natural support system), and liners for circular vertical shafts(artificial support systems).For pillar assessment, mine-pillar interaction curves can be constructed using a double spring analogy.Additionally, the effectiveness of different support systems can be evaluated depending on their effect upon the mine-pillar system. For shaft design, an initial estimation of the required lining strength and thickness can be readily made based on a double ring analogue. For both problems, the results from the proposed approach compare well with those obtained by finite element numerical simulations.
基金financial support provided by the China Scholarship Council(No.201706420055)funded by various projects,namely,China Postdoctoral Science Foundation(No.2020M673142)+3 种基金Chongqing Science and Technology Bureau Foundation(No.cstc2020jcyj-bsh0059)Chongqing Human Resources and Social Security Bureau Foundation(No.cx2019100)Chongqing Science and Technology Bureau Foundation(No.cstc2020jcyj-zdxm0122)National Natural Science Foundation of China(No.U19B2009)。
文摘The creep phenomenon of rocks is quite complex and the creep mechanisms are far from being well understood.Although laboratory creep tests have been carried out to determine the creep deformation of various rocks,these tests are expensive and time-consuming.Nanoindentation creep tests,as an alternative method,can be performed to investigate the mechanical and viscoelastic properties of granite samples.In this study,the reduced Young’s modulus,hardness,fracture toughness,creep strain rate,stress exponent,activation volume and maximum creep displacement of common rock-forming minerals of granite were calculated from nanoindentation results.It was found that the hardness decreases with the increase of holding time and the initial decrease in hardness was swift,and then it decreased slowly.The stress exponent values obtained were in the range from 4.5 to 22.9,which indicates that dislocation climb is the creep deformation mechanism.In addition,fracture toughness of granite’s rock-forming minerals was calculated using energy-based method and homogenization method was adopted to upscale the micro-scale mechanical properties to macro-scale mechanical properties.Last but not least,both three-element Voigt model and Burgers model fit the nanoindentation creep curves well.This study is beneficial to the understanding of the long-term mechanical properties of rock samples from a microscale perspective,which is of great significance to the understanding of localized deformation processes of rocks.
基金Project 2003CB214603 supported by the Development Plan of the State Key Fundamental Research, China
文摘The new recently demonstrated reserves of oil and gas in the Ordos basin are found at the top of petroliferous basins in China. Gas pools discovered in recent years in the Permian system have become the main natural gas resource in the basin. Therefore, synthetic research on fluid inclusions should be done in order to ascertain the pool-forming stage, the maturity of organic matters and the properties of Paleo-fluids. The main types of fluid inclusions in the Permian system in the basin include brine inclusions, carbon dioxide inclusions and organic inclusions. Homogenization temperatures (HT) of brine inclusions can be divided into four intervals: 66-83 ℃, 86-108 ℃, 112-138 ℃ and 142-153℃. The fluid inclusions in the interval of 112-138 ℃ are much more than that of other intervals, indicating that the second stage of hydrocarbon migration associated with the third temperature interval is the most important stage of gas pool formations. The fluid inclusion has extensive applications in the study of gas geology, not only in ascertaining the formation stage of gas pools, but also in estimating the maturity of organic matter and restoring Paleo-fluids. The result of testing the HT of brine inclusions shows that there are two stages of gas pool formations in the Permian system occurring +150 Ma and ±100 Ma. The maturity of organic matter is moderate to high, a conclusion based on the color of fluid inclusions (radiated by fluorescence). The high salinity of Paleo-fluids of the NaCI-H2O and CaCl2-H2O systems shows good preservation conditions of the Paleo-fluids. Two stages of reservoir filling, high maturity of organic matter and good preservation conditions are factors favorable for the formation and preservation of large-scale gas pools in the Permian system in the Ordos basin.
基金Project2003CB214603 supported by Development Plan of the State Key Fundamental Research, China
文摘The advantage of high-resolution sequence stratigraphy, which takes base-levels as reference, is that it can be applied to continental depositional basins controlled by multiple factors and can effectively improve the accuracy and resolution of sequential stratigraphic analysis. Moreover, the principles of base-level cycles are also suitable for analyzing sequential stratigraphy in continental coal-bearing basins because of their accuracy in forecasting distribution of coal measures. By taking the Dongsheng coalfield in the Ordos basin as an example, the extensive application of base-level cycles in exploration and exploitation of coal is analyzed. The result shows that the Yan’an formation in the Dongsheng area is a long-term base-level cycle which is bordered by nonconformities and made up of five mid-term cycles and 13 short-term cycles. The long-term cycle and the mid-term cycles are obvious in comparison with a transverse profile. The episodic coal accumulation in the Mesozoic Ordos basin means that the deposition of primary matter (peat bogs) of coalification is discontinuous, periodical and cyclical in the evolution of the basin. The episodic accumulation of coal measures in the Yan’an stage is controlled by ascending-descending changes of a long-term cycle and middle-term cycles. Coal measures formed during the early and late periods of the long-term cycle are characterized by multiple layers, big cumulative thickness and poor continuity. Coal measures formed in the mid-term of the long cycle are dominated by good continuity, fewer layers and a small additive thickness, which is favorable for the accumulation of thick and continuous coal measures in the transition stage of mid term base-level cycles.
文摘The Late Cretaceous tectonic upheaval was an important event during the evolution of the Qaidam Basin, resulting in the omission of the Upper Cretaceous in the whole basin and unconformities between the Paleogene sequence and pre-K2 strata. Inte-grating geological and geophysical data, two different groups of Late Cretaceous faults were recognized in the study area, one group consisting of E-W extending strike-slip faults (e.g., the Maxian and Yema-Jinan faults in the Mahai area, which caused an E-W omission zone of Mesozoic), while the other one has NW-SE thrust faults, resulting in NW-SE fold-and-thrust belts. Considering the different strikes and scale of these two groups, a simple-shear model has been employed to explain this structural phenomenon. The NW-SE thrust faults were thought to be subsidiary to the E-W strike-slip faults. Putting this into the framework of the Cretaceous paleogeographic environment of central Asia, it is inferred that this tectonic event of the Qaidam Basin is a response to the continuous northward drifting of the India plate.
基金the Nuclear Backend Management Department at Taiwan Power Company for financially supporting this research
文摘The characteristics of diffusion are essential to the transport of radionuclides through buffer/backfill materials, such as bentonite, which are commonly found in waste repositories. This study used through-diffusion techniques to investigate the diffusion behavior of HTO and ^(99)TcO_4^- on GMZ bentonite of various densities. Diffusion rates were calculated by measuring the diffusion coefficients(De, Da), plotting breakthrough curves and interpreting experiment data. The apparent and effective diffusion coefficients of HTO ranged from(1.68 ± 0.40) 9 × 10^(-11) to(2.80 ± 0.62) 9 × 10^(-11) m^2/s and from(4.61 ±1.28) 9 × 10^(-12) to (16.2 ± 2.50) 9 × 10^(-12) m^2/s, respectively.The apparent and effective diffusion coefficients of^(99)TcO_4^-ranged from(5.26 ± 0.16) 9 × 10^-12to(7.78 ± 0.43) 9× 10^-12m^2/s and from(1.49 ± 0.002) 9 × 10^(-12) to(4.16 ±0.07) 9 × 10^(-12) m^2/s, respectively. The distribution coefficients of HTO and^(99)TcO_4^-ranged from(0.70 ± 0.12) 9× 10^(-2) to(1.36 ± 0.53) 9 × 10^(-2) mL/g and from(1.12 ±0.06) 9 × 10^(-2) to(5.79 ± 2.22) 9 × 10^(-2) mL/g, respectively.The Deand Kdvalues were shown to decrease with an increase in the bulk dry density of compacted bentonite. Our results show that HTO and ^(99)Tc could be considered nonsorbent radionuclides. The data obtained in this studyprovide a valuable reference for the safety assessment of waste repositories.
文摘We analyze the excess area and depth to detachment method developed by Epard and Groshong (1993), and apply it to the sand box model of Ge et al (2004) to illustrate that inadequate consideration will affect the calculation of true depth to detachment. Using the data of Yu et al (2006) to fit linear regression lines, we obtain the depths to detachment of Kela-2, Misikantage anticline and Dongqiu-8 structures, 115.74km, 14.17km, and 75.48km below the reference level (Cretaceous bottom) respectively with the excess area intercept equal to zero. However, the calculation results of depth to detachment in Yu et al (2006) are based on excess area intercept unequal to zero.
文摘Carbonaceous shale exposures of the Late Cretaceous Mamu Formation along Ifon-Uzebba road in western arm(Benin Flank) of Anambra Basin, southwestern Nigeria, were analyzed for bulk organic geochemical, molecular biological and poly-aromatic hydrocarbon(PAH) compositions to investigate the organic matter source, paleo-depositional condition, thermal maturity and petroleum potential of the unit. The bulk organic geochemistry was determined using Leco and Rock-Eval pyrolysis analyses while the biomarkers and PAH compositions were investigated using gas chromatography-mass spectrometer(GC-MS).The bulk organic geochemical parameters of the shale samples showed total organic carbon(TOC)(1.11-6.03 wt%), S2(0.49-11.73 mg HC/g Rock), HI(38-242 mg HC/g TOC) and Tmax(425-435 C) indicating good to excellent hydrocarbon source-rock. Typical HI-Tmax diagram revealed the shale samples mostly in the gas-prone Type Ⅲ kerogen region with few gas and oil-prone Type Ⅱ-Ⅲ kerogen. The investigated biomarkers(n-alkane, isoprenoid, terpane, hopane, sterane) and PAH(alkylnaphthalene, methylphenanthrene and dibenzothiophene) indicated that the carbonaceous shales contain mix contributions of terrestrial and marine organic matter inputs that were deposited in a deltaic to shallow marine settings and preserved under relatively anoxic to suboxic conditions.Thermal maturity parameters computed from Rock-Eval pyrolysis, biomarkers(hopane, sterane) and PAH(alkylnaphthalene, alkylphenanthrene, alkyldibenzothiophene) suggested that these carbonaceous shales in Anambra Basin have entered an early-mature stage for hydrocarbon generation. This is also supported by fluoranthene/pyrene(0.27-1.12), fluoranthene/(fluoranthene + pyrene)(0.21-0.53) ratios and calculated vitrinite reflectance values(0.49-0.63% Ro) indicative that these shales have mostly reached early oil window maturity, thereby having low hydrocarbon source potential.
文摘The spacing–burden(S/B) ratio plays significant role on rock fragmentation and proper utilization of explosive energy to minimize the undesirable damage.Low S/B ratio generates fine fragments due to pressure rings coalescence of two blast holes,whereas boulder generations were observed above optimum S/B ratio.Both conditions are not acceptable because of wastage of explosive energy.Therefore,to resolve this issue,a numerical model study was conducted to optimize the S/B ratio and to envisage its effect on rock fragmentation based on utilization of explosive energy.Finite element simulation tool was used to see the extent of two blast hole influence area variation with varying S/B ratio.The better results were obtained at S/B ratio of 1:2 with optimum utilization of peak explosive energy.The performance was observed based on peak kinetic energy,peak pressure,radial and hoop stresses on centre of the two blast holes,where pressure rings coalescence.
基金This work was supported by the National Major Science and Technology Project of the Thirteenth Five Year Plan(No.2016zX05024-003-010)National Natural Science Foundation of China(No.42002123)the Open Fund of State Key Laboratory of Oil and Gas Reservoir Geology and Exploitation(Chengdu Univerisity of Technology,No.PLC2020031).
文摘The Palaeozoic carbonate basement of the Offshore Bohai Bay Basin (OBBB) presents considerable potential for hydrocarbon exploration. However, the multistage tectonism and complex superimposed palaeo-karstification in the area are unclear, which leads to a lack of understanding on the formation mechanism and distribution of the deep carbonate basement reservoirs. In this study, the occurrence of a fracture-vug network and its fillings in carbonate reservoirs were investigated based on borehole cores, thin sections, and image logs from the southwestern slope of the OBBB's Bozhong Sag. Then the diagenetic fluid properties of the carbonate matrix and fillings were analysed via the data of carbon, oxygen, and strontium isotopes, and major, rare elements from coring intervals. The results revealed that fracture-related karst reservoirs have lithologic selectivity inclined toward dolomite strata. The intersecting relationships, widths, and strikes of the fractures and the regional tectonic background indicate three structural fracture families: NW-, NNE-, and NNW- trending, related to the Indosinian, middle Yanshanian, and late Yanshanian orogeny, respectively. The Indosinian NW- and end-Mesozoic NNE-trending fractures produced by compressional tectonic stress mainly contributed to the formation of the basement reservoirs. The geochemistry of the calcite veins filling these fractures suggests two main types of diagenetic fluids. The fluid of autogenic recharge related to the earlier fills is karstification diffuse flow dominated by internal runoff from rainfall in the highland setting of the Indosinian thrusting orogenic belt. The other fluid of allogenic recharge related to the later fills is the main lateral freshwater flow dominated by external runoff from the catchment in the setting of the horst-lowland within the rifting basin, induced by the Yanshanian destruction of the North China Craton. Finally, the relationship between the three fracture families and two kinds of related fluids is revealed. This allows us to propose a model to understand the polyphase-superimposed fracture-related karst reservoir complexes within the deep carbonate basement of tilting fault blocks that neighbour the Bozhong hydrocarbon kitchen and predict the formation of potential plays with high accuracy.
基金Project 40502013 supported by the National Natural Science Foundation of China
文摘Oils in Jinghu sag are abundant with high content of polar compounds and have a low ratio of saturate to aromatic hydrocarbons and a high ratio of resin to asphaltene. The gross composition of oils in the Jinghu sag suggests typical immature to low mature characteristics. Some compounds with low thermal stability were identified. Light hydrocarbons, a carbon preference index, an odd even index, n-alkane and hopane maturity parameters show mature features and little differences in the maturity level among oils. Sterane isomerization parameters indicate an immature to low mature status of oil. Transfer of the sedimentary center during sedimentation has led to different thermal histories among subsags and thus generated oils with different maturities. On the basis of source analyses, four migration and accumulation patterns with different maturity can be classified. Combined with available information on mergers of source, reservoir and long distance oil lateral migration, mixing conditions were present in the Jinghu sag. Experimental results indicate that maturity variations are caused by mixtures of hydrocarbons with different maturity.