The life of Nitrile Butadiene Rubber(NBR) O-ring seal having shore hardness of A70 and A90 under shock loading conditions was investigated by a specially designed pneumo-hydraulic shock test rig. Shock tests have been...The life of Nitrile Butadiene Rubber(NBR) O-ring seal having shore hardness of A70 and A90 under shock loading conditions was investigated by a specially designed pneumo-hydraulic shock test rig. Shock tests have been carried out on bare seals, seal with conventional polytetrafluoroethylene(PTFE) back-up rings and seal with newly developed carbon composite back-up rings to study its behaviour under different operating conditions until failure. Experiments were conducted by varying annular gap ranging from 0.3 to 0.5 mm, oil temperature from 30 ℃ to 70 ℃ and rate of pressure rise from 600 to 2400 MPa/s. Significant enhancement in seal life was observed with carbon composite back-up ring at reduced annular clearances compared to seal life with conventional PTFE back-up ring and without back-up rings.展开更多
The present day weapon technology demands novel energetic materials that exhibit simultaneous high explosive yield and reduced sensitivity.This article demonstrates application of spray evaporation to prepare reduced ...The present day weapon technology demands novel energetic materials that exhibit simultaneous high explosive yield and reduced sensitivity.This article demonstrates application of spray evaporation to prepare reduced sensitive co-crystals of high performance nitramine explosives like HMX and CL-20 with a relatively less insensitive explosive 1,1-diamino-2,2-dinitroethylene or FOX-7.Stronger intermolecurar hydrogen bonding in FOX-7 is responsible for limited solubility in nost of o rganic solvents.Large solubility differences of FOX-7 with HMX and CL-20 restricts ifs co-crystallization through classical methods that yields thermodynamically favorable product.Spray flash evaporation,a kinetic crystallization method,has been therefore adopted and could successfully produce CL-20/FOX-7(2:1) and HMX/FQX-7(4:1) co-crystals.The fine powdered materials obtained were characterized by SEM,powder XRD,Raman spectro scopy,DSC-TGA etc.Multipoint Raman spectra showed consistent occurrence of spectral features indicating stoichiometric co-existence of ingredients in the crystal lattices.DSC analysis showed absence of all thermally assisted solidsolid phase transformation in the co-crystals as they were observed in pristine materials.The thermal stability calculated in terms of activation barrier fordecomposition,revealed the CL-20/FOX-7 co-crystal to be interlediately stable on comparison to their constituents while,the HMX/FOX-7 co-crystal is more stable.Compared to pure HMX and CL-20,both the co-crystals have shown higher insensitivity to impact force,suggesting them to be suitable for future generation insensitive munitions.展开更多
Nanotechnology has played an influential role in improving the energetic content without subsiding the performance of high energy materials in the current era.In this work,HMX(octahydro-1,3,5,7-tetranitro-1,3,5,7-tetr...Nanotechnology has played an influential role in improving the energetic content without subsiding the performance of high energy materials in the current era.In this work,HMX(octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine)nanoparticles were prepared by sonochemically assisted solvent-antisolvent spray technique focussing the reduction in its size so as to improve its energetic properties.In order to fabricate nano HMX various parameters such as different solvents and temperature were investigated.Sonication is one of the strategies recently explored in this regard;so time dependent study of sonication using probe sonicator was performed.It has been postulated that bubble formed during sonication when collapses generate high temperature and many nucleation sites which leads to the formation of uniform spherical particles with small size and fast transition phase.XRD studies depicted phase transformation from a toβas a result of sonication.The TEM images revealed that the rise in the sonication time resulted into decrease in the particle size from 300 to 10 nm.Differential scanning calorimetry(DSC)was employed to determine the heat release of the samples and enhancement in the heat release with the decrease in the particle size.A decrease in the spark sensitivity was observed from 2 J(regular HMX)to 50 mJ(nano HMX).展开更多
In this article, parametric study of single confined fragment launch device was carried out. The configuration proposed was further studied to derive the empirical relationship for effect of fragment size,charge size,...In this article, parametric study of single confined fragment launch device was carried out. The configuration proposed was further studied to derive the empirical relationship for effect of fragment size,charge size, confinement thickness on fragment velocity. The simulations were carried out using ANSYSAUTODYNE explicit solver. Fragment velocities were estimated as a function of different parametric combinations of explosive quantities, charge length to diameter ratio, fragment height to diameter ratio,confinement thickness, fragment material and fragment mass. The data was further converted to charge to metal ratio under fragment and confinement. It was observed that, increase in confinement thickness,charge quantity and decrease in fragment height increases the fragment velocity. It is also noted that,charge to metal mass ratio under fragment significantly affects the fragment velocity. At the end, an empirical relationship for fragment velocity interms of all these parameters was established. Using these relations, two velocities 1831.92 m/s and 2523.9 m/s required for NATO STANAG 4496 IM test were estimated. The design parameters for these velocities are presented. Also, the results estimated using the empirical relationship has been compared with published experimental data. Error in the predicted velocities is within the acceptable range. The empirical relationship proposed will be useful for finalization of design of the fragment launch device.展开更多
The present work aims to enhance the ballistic resistance of AA7005 alloy by incorporating the TiB2 and B4C ceramic reinforcement particles. Surface composites with different weight fractions of TiB2 and B4C particles...The present work aims to enhance the ballistic resistance of AA7005 alloy by incorporating the TiB2 and B4C ceramic reinforcement particles. Surface composites with different weight fractions of TiB2 and B4C particles were processed by friction stir processing. Micro-hardness and depth of penetration tests were carried out to evaluate the ballistic properties of the surface composites. The surface hardness of the composite was found to be nearly 70 HV higher than base alloy. The depth of penetration of the steel projectile was 20e26mm in the composites as compared to 37mm in the base alloy. Ballistic mass efficiency factor of the surface composite was found to be 1.6 times higher than base alloy. This is mainly attributed to the dispersion strengthening from the reinforcement particles.展开更多
Tactical Ballistic Missile(TBM) class target neutralization by the fragment spray of a Fragment Generator Warhead(FGW) calls for quantification of fragment projection angle scatter to finalize the end game engagement ...Tactical Ballistic Missile(TBM) class target neutralization by the fragment spray of a Fragment Generator Warhead(FGW) calls for quantification of fragment projection angle scatter to finalize the end game engagement logic.For conventional axi-symmetric warhead,dispersion is assumed to be normal with a standard deviation of 3~O.However,such information is not available in case of FGW.Hence,a set of experiments are conducted to determine the dispersion of fragments.The experiments are conducted with a specific configuration of FGW in an identical arena to quantify the scatter and then verified its applicability to other configurations having a range of L/D and C/M ratios,and contoured fragmenting discs.From the experimental study,it is concluded that the scatter in projection angle follows normal distribution with a standard deviation of 0.75° at Chi-square significance level of 0.01(x_(0.99)~2).展开更多
Power Cartridges are pyrotechnic devices where hot combustion gases utilized to do mechanical work for disruption of suspected Improvised Explosive Devices(IEDs). It plays a vital role either in destroying the suspici...Power Cartridges are pyrotechnic devices where hot combustion gases utilized to do mechanical work for disruption of suspected Improvised Explosive Devices(IEDs). It plays a vital role either in destroying the suspicious object or making them non-functional by generating the gas pressure on burning of propellant against the water column inside the barrel, Present work is focused on characterisation,numerical solution such as deformation; strain; stress using FEM(Finite Element Method), design qualification, performance and evaluation of power cartridge for disruptor application. Experimental trials for pressure-time(P-t) measurement in closed vessel(CV), various electrical parameters like all fire current(AFC), no fire current(NFC) and ignition delay have been measured. Further, mechanical properties for brass material have been determined. An attempt has been made to characterise the power cartridge by FEM and carrying out the experiments for water-jet application.展开更多
In this investigation, comparative study of tensile and impact properties of multi-pass SMAW Armox500 T steel joints fabricated by austenitic stainless steel(ASS) and low hydrogen ferritic steel(LHF)consumables vis-a-...In this investigation, comparative study of tensile and impact properties of multi-pass SMAW Armox500 T steel joints fabricated by austenitic stainless steel(ASS) and low hydrogen ferritic steel(LHF)consumables vis-a-vis base metal was carried out. The tensile tests were conducted on computer controlled Walter t Bai Ag UTM at a nominal strain rate of 10à3 sà1. Subsequently, charpy impact tests were carried out on an instrumented Zwick-Roell test setup to obtain load vs. displacement and maximum energy absorbed vs. displacement of the specimen. It was observed that, the joint efficiency of weldment processed by LHF consumable was 41.7% and weldment processed by ASS was 30.6% of its base metal indicating the influence of electrode consumable on tensile properties of the joints. On the contrary, impact toughness of weldment processed by ASS was 20% more and weldment processed by LHF was 12% less than that of base metal. Microstructural studies also revealed that, ASS can be considered as a candidate welding consumable for good strain hardening and toughness of the welding joint in impact applications. However, LHF steel consumable is recommended for welding joints that requires higher joint efficiency under tensile loading conditions.展开更多
Friction stir processing and post process artificial ageing was successfully carried out on AA7075 with and without reinforcement of SiC particles producing defect free processed zone with uniform distribution of fill...Friction stir processing and post process artificial ageing was successfully carried out on AA7075 with and without reinforcement of SiC particles producing defect free processed zone with uniform distribution of filler material.Effect of SiC particle reinforcement and artificial ageing times on the microstructural modifications was characterized using optical and electron microscopy,electron backscattered diffraction and X-Ray diffraction.Hardness,impact and wear tests were carried out to investigate mechanical behaviour before and after processing.Reinforcement of SiC particles during FSP and subsequent age hardening treatment brought about nearly twofold increase in hardness and impact toughness values by the combined effect of grain refinement,Zener pinning,dispersion strengthening and precipitation hardening.Significant improvement in wear resistance in terms of wear loss was also observed after processing compared to the reference material AA7075-T6.Fractured surface of post FSP age hardened AA7075 alloy exhibited features of ductile fracture during Charpy impact test.展开更多
The pheno menon of static electricity is unpredictable,particulariy when an aircraft flying at high altitude that causes the accumulation of static charges beyond a threshold value leading to the failure of its parts ...The pheno menon of static electricity is unpredictable,particulariy when an aircraft flying at high altitude that causes the accumulation of static charges beyond a threshold value leading to the failure of its parts and systems including severe explosion and radio communication failure.The accumulation of static charges on aircraft is generated by the virtue of interaction between the outer surface of aircraft and the external environmental attributes encompasses air particles,ice,hail,dust,volcanic ash in addition to its triboelectric charging.In the recent years,advanced polymer-based composites or nanocomposites are preferred structural constituents for aircrafts due to their light weight and comparable mechanical properties,but such composite systems do not render low impedance path for charge flow and are subsequently vulnerable to effect of lightning strike and precipitation static.In this context,it is essential to develop conductive composite systems from non-co nductive polymer natrix by nano fillerembodime nts.The advent of carbon-based nanocomposite/nano materials have adequately addressed such issues related to the nonco nductive polymer matrix and further turned into an avant-garde genre of materials.The current review envisioned to illustrate the detailed exploitation of various polymer nanocomposites in addition to especially mentioned epoxy composites based on carbon fillers like carbon black,carbon nanotube(single walled carbon nanotube and multi walled carbon nanotube) and graphene the development of antistatic application in aircra ft in addition to the static charge phenomenon and condition for its prevalence in avionic systems.展开更多
In the present study,organically modified Montmorillonite clay with polar moiety,the Cloisite 30B,is used for preparation of Hydroxyl terminated polybutadiene(HTPB)-clay nanocomposites(HCN)by dispersion of nanoclay in...In the present study,organically modified Montmorillonite clay with polar moiety,the Cloisite 30B,is used for preparation of Hydroxyl terminated polybutadiene(HTPB)-clay nanocomposites(HCN)by dispersion of nanoclay in polymer matrix under high shear mixing.The nanocomposites thus prepared are evaluated in composite propellants as inhibitor material for their functional utility.Several inhibition formulations containing 5 wt%-15 wt%of nanoclay,with or without the conventional filler Sb2O3,were prepared.All these formulations were evaluated for their physical,mechanical,thermal,and ablative properties.Ablation rate and density of the compositions containing Cloisite 30B is around 23%and 5%lower respectively in comparison of the base composition.Strain capability of these compositions is twofold higher than that of base composition.These compositions have also been evaluated for their smoke generation tendency by measuring infra red(IR)attenuation in the wavelength range 1.3 mm e5.6 mm and 8 mme13 mm and thereby compared with the base composition.The corresponding results confirmed that the compositions containing Cloisite 30B as filler have much lower IR attenuation than compositions with conventional filler,Sb2O3.Replacement of 5%Sb2O3 by nanoclay showed 8%reduction in IR attenuation rate which further reduced to 16%on replacement of 15%of Sb2O3.Interfacial bonding of HCN based inhibitors is also comparable or even better than conventional inhibitors.Precisely,the nanoclay composites with Cloisite 30B as filler exhibit all desirable properties of an inhibitor.展开更多
文摘The life of Nitrile Butadiene Rubber(NBR) O-ring seal having shore hardness of A70 and A90 under shock loading conditions was investigated by a specially designed pneumo-hydraulic shock test rig. Shock tests have been carried out on bare seals, seal with conventional polytetrafluoroethylene(PTFE) back-up rings and seal with newly developed carbon composite back-up rings to study its behaviour under different operating conditions until failure. Experiments were conducted by varying annular gap ranging from 0.3 to 0.5 mm, oil temperature from 30 ℃ to 70 ℃ and rate of pressure rise from 600 to 2400 MPa/s. Significant enhancement in seal life was observed with carbon composite back-up ring at reduced annular clearances compared to seal life with conventional PTFE back-up ring and without back-up rings.
基金Defense Research&Development Organization(DRDO),India for financial support towards this study。
文摘The present day weapon technology demands novel energetic materials that exhibit simultaneous high explosive yield and reduced sensitivity.This article demonstrates application of spray evaporation to prepare reduced sensitive co-crystals of high performance nitramine explosives like HMX and CL-20 with a relatively less insensitive explosive 1,1-diamino-2,2-dinitroethylene or FOX-7.Stronger intermolecurar hydrogen bonding in FOX-7 is responsible for limited solubility in nost of o rganic solvents.Large solubility differences of FOX-7 with HMX and CL-20 restricts ifs co-crystallization through classical methods that yields thermodynamically favorable product.Spray flash evaporation,a kinetic crystallization method,has been therefore adopted and could successfully produce CL-20/FOX-7(2:1) and HMX/FQX-7(4:1) co-crystals.The fine powdered materials obtained were characterized by SEM,powder XRD,Raman spectro scopy,DSC-TGA etc.Multipoint Raman spectra showed consistent occurrence of spectral features indicating stoichiometric co-existence of ingredients in the crystal lattices.DSC analysis showed absence of all thermally assisted solidsolid phase transformation in the co-crystals as they were observed in pristine materials.The thermal stability calculated in terms of activation barrier fordecomposition,revealed the CL-20/FOX-7 co-crystal to be interlediately stable on comparison to their constituents while,the HMX/FOX-7 co-crystal is more stable.Compared to pure HMX and CL-20,both the co-crystals have shown higher insensitivity to impact force,suggesting them to be suitable for future generation insensitive munitions.
基金ER&IPR,DRDO,New Delhi for funding the project “DRDO-DIAT Programme on Nanomaterials”
文摘Nanotechnology has played an influential role in improving the energetic content without subsiding the performance of high energy materials in the current era.In this work,HMX(octahydro-1,3,5,7-tetranitro-1,3,5,7-tetrazocine)nanoparticles were prepared by sonochemically assisted solvent-antisolvent spray technique focussing the reduction in its size so as to improve its energetic properties.In order to fabricate nano HMX various parameters such as different solvents and temperature were investigated.Sonication is one of the strategies recently explored in this regard;so time dependent study of sonication using probe sonicator was performed.It has been postulated that bubble formed during sonication when collapses generate high temperature and many nucleation sites which leads to the formation of uniform spherical particles with small size and fast transition phase.XRD studies depicted phase transformation from a toβas a result of sonication.The TEM images revealed that the rise in the sonication time resulted into decrease in the particle size from 300 to 10 nm.Differential scanning calorimetry(DSC)was employed to determine the heat release of the samples and enhancement in the heat release with the decrease in the particle size.A decrease in the spark sensitivity was observed from 2 J(regular HMX)to 50 mJ(nano HMX).
文摘In this article, parametric study of single confined fragment launch device was carried out. The configuration proposed was further studied to derive the empirical relationship for effect of fragment size,charge size, confinement thickness on fragment velocity. The simulations were carried out using ANSYSAUTODYNE explicit solver. Fragment velocities were estimated as a function of different parametric combinations of explosive quantities, charge length to diameter ratio, fragment height to diameter ratio,confinement thickness, fragment material and fragment mass. The data was further converted to charge to metal ratio under fragment and confinement. It was observed that, increase in confinement thickness,charge quantity and decrease in fragment height increases the fragment velocity. It is also noted that,charge to metal mass ratio under fragment significantly affects the fragment velocity. At the end, an empirical relationship for fragment velocity interms of all these parameters was established. Using these relations, two velocities 1831.92 m/s and 2523.9 m/s required for NATO STANAG 4496 IM test were estimated. The design parameters for these velocities are presented. Also, the results estimated using the empirical relationship has been compared with published experimental data. Error in the predicted velocities is within the acceptable range. The empirical relationship proposed will be useful for finalization of design of the fragment launch device.
基金supported by Defence Institute of Advanced Technology(DIAT),Pune(DIAT-In house Project)
文摘The present work aims to enhance the ballistic resistance of AA7005 alloy by incorporating the TiB2 and B4C ceramic reinforcement particles. Surface composites with different weight fractions of TiB2 and B4C particles were processed by friction stir processing. Micro-hardness and depth of penetration tests were carried out to evaluate the ballistic properties of the surface composites. The surface hardness of the composite was found to be nearly 70 HV higher than base alloy. The depth of penetration of the steel projectile was 20e26mm in the composites as compared to 37mm in the base alloy. Ballistic mass efficiency factor of the surface composite was found to be 1.6 times higher than base alloy. This is mainly attributed to the dispersion strengthening from the reinforcement particles.
文摘Tactical Ballistic Missile(TBM) class target neutralization by the fragment spray of a Fragment Generator Warhead(FGW) calls for quantification of fragment projection angle scatter to finalize the end game engagement logic.For conventional axi-symmetric warhead,dispersion is assumed to be normal with a standard deviation of 3~O.However,such information is not available in case of FGW.Hence,a set of experiments are conducted to determine the dispersion of fragments.The experiments are conducted with a specific configuration of FGW in an identical arena to quantify the scatter and then verified its applicability to other configurations having a range of L/D and C/M ratios,and contoured fragmenting discs.From the experimental study,it is concluded that the scatter in projection angle follows normal distribution with a standard deviation of 0.75° at Chi-square significance level of 0.01(x_(0.99)~2).
文摘Power Cartridges are pyrotechnic devices where hot combustion gases utilized to do mechanical work for disruption of suspected Improvised Explosive Devices(IEDs). It plays a vital role either in destroying the suspicious object or making them non-functional by generating the gas pressure on burning of propellant against the water column inside the barrel, Present work is focused on characterisation,numerical solution such as deformation; strain; stress using FEM(Finite Element Method), design qualification, performance and evaluation of power cartridge for disruptor application. Experimental trials for pressure-time(P-t) measurement in closed vessel(CV), various electrical parameters like all fire current(AFC), no fire current(NFC) and ignition delay have been measured. Further, mechanical properties for brass material have been determined. An attempt has been made to characterise the power cartridge by FEM and carrying out the experiments for water-jet application.
文摘In this investigation, comparative study of tensile and impact properties of multi-pass SMAW Armox500 T steel joints fabricated by austenitic stainless steel(ASS) and low hydrogen ferritic steel(LHF)consumables vis-a-vis base metal was carried out. The tensile tests were conducted on computer controlled Walter t Bai Ag UTM at a nominal strain rate of 10à3 sà1. Subsequently, charpy impact tests were carried out on an instrumented Zwick-Roell test setup to obtain load vs. displacement and maximum energy absorbed vs. displacement of the specimen. It was observed that, the joint efficiency of weldment processed by LHF consumable was 41.7% and weldment processed by ASS was 30.6% of its base metal indicating the influence of electrode consumable on tensile properties of the joints. On the contrary, impact toughness of weldment processed by ASS was 20% more and weldment processed by LHF was 12% less than that of base metal. Microstructural studies also revealed that, ASS can be considered as a candidate welding consumable for good strain hardening and toughness of the welding joint in impact applications. However, LHF steel consumable is recommended for welding joints that requires higher joint efficiency under tensile loading conditions.
基金The authors would like to acknowledge National Facility for Texture and OIM(A DST-IRPHA project),IIT Mumbai for XRD and EBSD measurements.One of the authors VDH would like to acknowledge Science and Engineering Research Board(SERB)for financial assistance(EEQ/2016/000422)to carry out project work.
文摘Friction stir processing and post process artificial ageing was successfully carried out on AA7075 with and without reinforcement of SiC particles producing defect free processed zone with uniform distribution of filler material.Effect of SiC particle reinforcement and artificial ageing times on the microstructural modifications was characterized using optical and electron microscopy,electron backscattered diffraction and X-Ray diffraction.Hardness,impact and wear tests were carried out to investigate mechanical behaviour before and after processing.Reinforcement of SiC particles during FSP and subsequent age hardening treatment brought about nearly twofold increase in hardness and impact toughness values by the combined effect of grain refinement,Zener pinning,dispersion strengthening and precipitation hardening.Significant improvement in wear resistance in terms of wear loss was also observed after processing compared to the reference material AA7075-T6.Fractured surface of post FSP age hardened AA7075 alloy exhibited features of ductile fracture during Charpy impact test.
文摘The pheno menon of static electricity is unpredictable,particulariy when an aircraft flying at high altitude that causes the accumulation of static charges beyond a threshold value leading to the failure of its parts and systems including severe explosion and radio communication failure.The accumulation of static charges on aircraft is generated by the virtue of interaction between the outer surface of aircraft and the external environmental attributes encompasses air particles,ice,hail,dust,volcanic ash in addition to its triboelectric charging.In the recent years,advanced polymer-based composites or nanocomposites are preferred structural constituents for aircrafts due to their light weight and comparable mechanical properties,but such composite systems do not render low impedance path for charge flow and are subsequently vulnerable to effect of lightning strike and precipitation static.In this context,it is essential to develop conductive composite systems from non-co nductive polymer natrix by nano fillerembodime nts.The advent of carbon-based nanocomposite/nano materials have adequately addressed such issues related to the nonco nductive polymer matrix and further turned into an avant-garde genre of materials.The current review envisioned to illustrate the detailed exploitation of various polymer nanocomposites in addition to especially mentioned epoxy composites based on carbon fillers like carbon black,carbon nanotube(single walled carbon nanotube and multi walled carbon nanotube) and graphene the development of antistatic application in aircra ft in addition to the static charge phenomenon and condition for its prevalence in avionic systems.
文摘In the present study,organically modified Montmorillonite clay with polar moiety,the Cloisite 30B,is used for preparation of Hydroxyl terminated polybutadiene(HTPB)-clay nanocomposites(HCN)by dispersion of nanoclay in polymer matrix under high shear mixing.The nanocomposites thus prepared are evaluated in composite propellants as inhibitor material for their functional utility.Several inhibition formulations containing 5 wt%-15 wt%of nanoclay,with or without the conventional filler Sb2O3,were prepared.All these formulations were evaluated for their physical,mechanical,thermal,and ablative properties.Ablation rate and density of the compositions containing Cloisite 30B is around 23%and 5%lower respectively in comparison of the base composition.Strain capability of these compositions is twofold higher than that of base composition.These compositions have also been evaluated for their smoke generation tendency by measuring infra red(IR)attenuation in the wavelength range 1.3 mm e5.6 mm and 8 mme13 mm and thereby compared with the base composition.The corresponding results confirmed that the compositions containing Cloisite 30B as filler have much lower IR attenuation than compositions with conventional filler,Sb2O3.Replacement of 5%Sb2O3 by nanoclay showed 8%reduction in IR attenuation rate which further reduced to 16%on replacement of 15%of Sb2O3.Interfacial bonding of HCN based inhibitors is also comparable or even better than conventional inhibitors.Precisely,the nanoclay composites with Cloisite 30B as filler exhibit all desirable properties of an inhibitor.
