Layered transition-metal compounds(LTMCs)feature stacked architectures,strong magnetic anisotropy,and tunable magnetic order,making them promising material platforms for low-power spintronic technologies and for enabl...Layered transition-metal compounds(LTMCs)feature stacked architectures,strong magnetic anisotropy,and tunable magnetic order,making them promising material platforms for low-power spintronic technologies and for enabling topological functionalities in the post-Moore era.Here we review recent progress on two-dimensional(2D)magnetism in LTMCs,emphasizing material taxonomy,intrinsic magnetic properties,and external-field controls.This review first presents a classification of LTMCs by crystal structure and chemistry—binary halides,chalcogenides,and ternary families(e.g.,MPX_(3),M_(m)X_(n)Te_(k),MnBi_(2)Te_(4))—followed by a summary of their coupling mechanisms,ordering temperatures,and dimensional effects.It then analyzes the modulation of exchange interactions,magnetic anisotropy,and topological states by electric-field gating,strain engineering,and ion intercalation,with representative experimental demonstrations.Notable advances include room-temperature ferromagnetic metals and semiconductors,observation of the quantum anomalous Hall effect(QAHE)in MnBi2Te4,and synergistic control of magnetic-topological states under multiple external stimuli.Persistent challenges involve the limited availability of intrinsic 2D magnetic semiconductors with high Curie temperatures(Tc),incomplete understanding of the microscopic couplings at interfaces and under quantum confinement,and device-level stability.We conclude by outlining opportunities that lie in the integration of multiscale characterization,first-principles theory,and cross-scale fabrication to precisely co-engineer magnetism,topology,and electronic structure,thereby advancing LTMCs toward spintronic and topological-quantum applications.展开更多
In this work,we report a fabrication of recyclable iron oxide decorated MoS_(2)nanosheets via a facile liq-uid exfoliation approach and solvothermal reaction for visible-light photodegradation of tetracycline.The prep...In this work,we report a fabrication of recyclable iron oxide decorated MoS_(2)nanosheets via a facile liq-uid exfoliation approach and solvothermal reaction for visible-light photodegradation of tetracycline.The prepared Fe_(3)O_(4)-MoS_(2)was characterized by X-ray diffraction,transmission electron microscopy,X-ray photoelectron spectros-copy,Raman spectroscopy,magnetic hysteresis,and nitrogen adsorption-desorption isotherms.Experimental results indicate that,successful attachment of Fe_(3)O_(4)nanoparticles to MoS_(2)sheets has been achieved.The enhanced surface area of Fe_(3)O_(4)-MoS_(2)induced high rates of adsorption and the adsorbed tetracycline was degraded to 90%after 150 min of visible exposure,which is better than that from pure MoS_(2).The introduction of Fe_(3)O_(4)not only enhances the photo-catalytic performance of Fe_(3)O_(4)-MoS_(2),but also enables its convenient recovery from water by an external magnetic field.Furthermore,both the photocatalytic activity and composite phase of Fe_(3)O_(4)-MoS_(2)were well-retained over cy-cles.Owing to its efficient photocatalytic activity,good stability and magnetic recyclability,the Fe_(3)O_(4)-MoS_(2)nano-composite is considered to be a promising photocatalyst for wastewater treatment.展开更多
To generate a neutron beam exhibiting a Maxwellian energy distribution with narrow emission angles for measuring the neutron capture reaction rates of the s-process nuclides,a monoenergetic 3.4 MeV proton beam produce...To generate a neutron beam exhibiting a Maxwellian energy distribution with narrow emission angles for measuring the neutron capture reaction rates of the s-process nuclides,a monoenergetic 3.4 MeV proton beam produced by the tandem-accelerator in the China Institute of Atomic Energy was utilized.The proton beam was first transmitted through a 60.5μm aluminum foil and then impinged on a natural LiF target to produce neutron beam via^(7)Li(p,n)7Be reaction.The quasi-Gaussian energy distribution of protons in the LiF target resulted in neutron energy spectra that agreed with a Maxwellian energy distribution at kT=(22±2)keV,which was achieved by integrating neutrons detected within an emission angle of 65.0°±2.6°using a ^(6)Li glass detector positioned at 65°relative to the proton beam direction.The narrow angular spread of the Maxwelliandistributed neutron beam enables direct measurement of neutron capture cross-sections for most s-process nuclides,overcoming previous experimental limitations associated with broad angular distributions.展开更多
Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown tha...Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown that this structure gives it exceptional physical properties that exceed those of cubic diamond,making it highly promising for groundbreaking applications in superhard cutting tools,wide-bandgap semiconductor devices,and materials for extreme environments.As a result,the controllable synthesis of hexagonal diamond has emerged as a cutting-edge research focus in materials science.This review briefly outlines the progress in this area,with a focus on the mechanisms governing its key synthesis conditions,its intrinsic physical properties,and its potential applications in various fields.展开更多
ZnO is a highly significant II-VI semiconductor known for its excellent optoelectronic properties,making it widely applicable and promising for use in light-emitting devices,solar cells,lasers,and photodetectors.The m...ZnO is a highly significant II-VI semiconductor known for its excellent optoelectronic properties,making it widely applicable and promising for use in light-emitting devices,solar cells,lasers,and photodetectors.The methods for preparing ZnO are diverse,and among them,the hydrothermal method is favored for its simplicity,ease of operation,and low cost,making it an optimal choice for ZnO single-crystal growth.Most studies investigating the effects of different hydrothermal experimental parameters on the morphology and performance of ZnO nano-materials typically focus on only 2—3 variable parameters,with few examining the impact of all possible experimental parameter changes on ZnO nano-mate-rials.The principles of the hydrothermal method and its advantages in nano-material preparation were briefly introduced in this article.The detailed discussion on the influence of various experimental parameters on the preparation of ZnO nano-materials was provided,which including reaction materials,Zn^(2+)/OH^(-)ratio,reaction time and temperature,additives,experimental equipment,and annealing conditions.The review co-vers how different experimental parameters affect the morphology and performance of the materials,as well as how different rare earth doping elements influence the performance of ZnO nano-materials.It is hoped that this work will contribute to future research on the hydrothermal synthesis of nano-materials.展开更多
Based on the service characteristics of fuel elements for molten salt reactors,they need to have a high power density,resistance to coolant infiltration,and excellent thermodynamic properties.To solve the problem of t...Based on the service characteristics of fuel elements for molten salt reactors,they need to have a high power density,resistance to coolant infiltration,and excellent thermodynamic properties.To solve the problem of the graphite used in the fuel element for these reactors being susceptible to molten salt infiltration,carbon black(CB)was added to increase the density of the graphite,and a fuel element(TRISO(tri-structural isotropic)fuel particles were randomly distributed in the modified graphite matrix)was prepared by cold isostatic pressing process.An out-of-pile performance study shows that the densification and pore structure of the modified graphite matrix were improved,as was the resistance to molten salt infiltration.The median pore size of the modified graphite was reduced from 673 to 433 nm and the threshold pressure for molten salt(FLiBe,66%(molar fraction)LiF and 34%BeF_(2))infiltration was increased from 0.88 to 1.37 MPa.The isotropic CB made the graphite matrix less anisotropic,while its thermal conductivity and compressive strength were reduced due to the difficult graphitization of CB.Fuel elements containing 20%(volume fraction)TRISO particles were prepared.Numerical simulations show that the power and temperature distribution of the fuel were in line with the design requirements.The modified graphite matrix had a higher density,smaller pores,a lower anisotropy and a greater resistance to FLiBe infiltration.展开更多
In this work,tensile mechanical behavior of 316L steels fabricated by three different processing methods(casting,powder extrusion printing(PEP)and laser powder bed fusion(LPBF))was studied in the presence of liquid le...In this work,tensile mechanical behavior of 316L steels fabricated by three different processing methods(casting,powder extrusion printing(PEP)and laser powder bed fusion(LPBF))was studied in the presence of liquid lead-bismuth eutectic(LBE)and air at 350℃.The results show that all three steels tested in LBE are not subjected to evident degradation of tensile elongation to failure and strength compared to those tested in air,suggesting that LME does not occur regardless of the processing methods.The LPBF 316L steel exhibits the highest yield strength(420-435 MPa),followed by casting 316 L(~242 MPa)and PEP 316L(146-165 MPa).Ultimate tensile strength of three steels is comparable and ranges from 427 to 485 MPa.The PEP and casting 316L steels have similar total elongation to failure(i.e.,40.0%-43.8%),whereas this property decreases markedly to 18.6%-19.5% for the LPBF 316 L steel.The superior strength and relatively low ductility of the LPBF 316L steel can be attributed to nanosized dislocations trapped at cell structures which can produce a remarkable strengthening effect to the steel matrix.By contrast,due to massive residual micropores,the PEP 316L steel has the lowest strength.展开更多
This paper focuses on the high-temperature tensile failure mechanism of RTM(resin transfer moulding)-made symmetric and asymmetric composite T-joints.The failure modes as well as the load-displacement curves of symmet...This paper focuses on the high-temperature tensile failure mechanism of RTM(resin transfer moulding)-made symmetric and asymmetric composite T-joints.The failure modes as well as the load-displacement curves of symmetric(three specimens)and asymmetric(three specimens)composite T-joints were determined by tensile tests at room and high temperatures.Progressive damage models(PDMs)of symmetric and asymmetric composite T-joints at room and high temperatures were established based on mixed criteria,and the result predicted from the aforementioned PDMs were compared with experimental data.The predicted initial and final failure loads and failure modes are in good agreement with the experimental results.The failure mechanisms of composite T-joints at different temperatures were investigated by scanning electron microscopy.The results reveal that while the failure mode of asymmetric T-joints at high temperatures resembles that at room temperature,there is a difference in the failure modes of symmetric T-joints.The ultimate failure load of symmetric and asymmetric T-joints at elevated temperatures increases and reduces by 18.4%and 4.97%,albeit with a more discrete distri-bution.This work is expected to provide us with more knowledge about the usability of composite T-joints in elevated temperature environments.展开更多
In this work,synchronous cutting of concave and convex surfaces was achieved using the duplex helical method for the hypoid gear,and the problem of tooth surface error correction was studied.First,the mathematical mod...In this work,synchronous cutting of concave and convex surfaces was achieved using the duplex helical method for the hypoid gear,and the problem of tooth surface error correction was studied.First,the mathematical model of the hypoid gears machined by the duplex helical method was established.Second,the coordinates of discrete points on the tooth surface were obtained by measurement center,and the normal errors of the discrete points were calculated.Third,a tooth surface error correction model is established,and the tooth surface error was corrected using the Levenberg-Marquard algorithm with trust region strategy and least square method.Finally,grinding experiments were carried out on the machining parameters obtained by Levenberg-Marquard algorithm with trust region strategy,which had a better effect on tooth surface error correction than the least square method.After the tooth surface error is corrected,the maximum absolute error is reduced from 30.9μm before correction to 6.8μm,the root mean square of the concave error is reduced from 15.1 to 2.1μm,the root mean square of the convex error is reduced from 10.8 to 1.8μm,and the sum of squared errors of the concave and convex surfaces was reduced from 15471 to 358μm^(2).It is verified that the Levenberg-Marquard algorithm with trust region strategy has a good accuracy for the tooth surface error correction of hypoid gear machined by duplex helical method.展开更多
High intensity focused ultrasound(HIFU)therapy is an effective method in clinical treatment of tumors,in order to explore the bio-heat conduction mechanism of in multi-layer media by concave spherical transducer,tempe...High intensity focused ultrasound(HIFU)therapy is an effective method in clinical treatment of tumors,in order to explore the bio-heat conduction mechanism of in multi-layer media by concave spherical transducer,temperature field induced by this kind of transducer in multi-layer media will be simulated through solving Pennes equation with finite difference method,and the influence of initial sound pressure,absorption coefficient,and thickness of different layers of biological tissue as well as thermal conductivity parameter on sound focus and temperature distribution will be analyzed,respectively.The results show that the temperature in focus area increases faster while the initial sound pressure and thermal conductivity increase.The absorption coefficient is smaller,the ultrasound intensity in the focus area is bigger,and the size of the focus area is increasing.When the thicknesses of different layers of tissue change,the focus position changes slightly,but the sound intensity of the focus area will change obviously.The temperature in focus area will rise quickly before reaching a threshold,and then the temperature will keep in the threshold range.展开更多
First-principles calculations are performed to investigate the relaxation and electronic properties of sulfide minerals surfaces(MoS2, Sb2S3, Cu2 S, ZnS, PbS and FeS2) in presence of H2 O molecule. The calculated resu...First-principles calculations are performed to investigate the relaxation and electronic properties of sulfide minerals surfaces(MoS2, Sb2S3, Cu2 S, ZnS, PbS and FeS2) in presence of H2 O molecule. The calculated results show that the structure and electronic properties of sulfide minerals surfaces have been influenced in presence of H2 O molecule. The adsorption of the flotation reagent at the interface of mineral-water would be different from that of mineral surface due to the changes of surface structures and electronic properties caused by H2 O molecule. Hence, the influence of H2 O molecule on the reaction of flotation reagent with sulfide mineral surface will attract more attention.展开更多
The plasma characteristics of a lightning discharge channel are reviewed.The spectrum of the natural lightning is investigated by employing the slit-less spectrograph.It is found that the spectrum characteristics are ...The plasma characteristics of a lightning discharge channel are reviewed.The spectrum of the natural lightning is investigated by employing the slit-less spectrograph.It is found that the spectrum characteristics are closely related to the intensity of the lightning discharge.The lines in the lightning spectrum are classified into essential lines and characteristic lines,according to the characteristics of lightning spectra with different intensities.The characteristics of the lightning channel and the radiation of the lighting plasma are analyzed in the visible and infrared regions.It is shown that,the visible spectrum of lightning is determined by the radiation generated from the early stage to the development of lightning,while the near-infrared spectrum is determined by the radiation generated after current of lightning reaches the peak.The channel temperature and the electron density are calculated using the information obtained from the lightning spectrum.Both the temperature and the density decrease with the increasing length of lightning channel.Moreover,X-rays and neutrons are produced in the process of lighting mainly due to the pinch effects.展开更多
C/C-SiC composites with SiC island distribution Were prepared via a new processing route. The fabrication process mainly included silicon infiltration by ultrasonic vibration, chemical vapor deposition （CVD）, silico...C/C-SiC composites with SiC island distribution Were prepared via a new processing route. The fabrication process mainly included silicon infiltration by ultrasonic vibration, chemical vapor deposition （CVD）, siliconizing, liquid phase impregnation and carbonization. The wear and friction properties were tested by an MM-1000 wet friction machine. The results show that SiC phases are mainly distributed between carbon fibers and pyrocarbons as well as among the pryoearbons. The dynamic friction coefficient of the composites decreases gradually from 0.126 to 0.088 with the increase of the surface pressure from 0.5 to 2.5 MPa at the same rotary speed. Furthermore, under the constant surface pressure, the dynamic friction coefficient increases from 0.114 to 0.126 with the increase of the rotary speed from 1 500 to 2 500 r/min. However, the coefficient decreases to 0.104 when the rotary speed exceeds 4 500 r/min. During the friction process, the friction coefficient of C/C-SiC composite is between 0.088 and 0.126, and the wear value is zero after 300 times brake testing.展开更多
Natural scapolite including the S-2impurity is a typical silicate luminescent mineral.According to the formation conditions and chemical composition of natural scapolite,we synthesized Na_(4)Ca_(4)Al_(6)Si_(9)O_(24)(s...Natural scapolite including the S-2impurity is a typical silicate luminescent mineral.According to the formation conditions and chemical composition of natural scapolite,we synthesized Na_(4)Ca_(4)Al_(6)Si_(9)O_(24)(scapolite)by the high temperature solid-phase reaction,and prepared the synthetic scapolite phosphors activated with Ce^3+and Tb^3+.The photoluminescence(PL)properties of the obtained phosphors were studied.The results indicated that the PL intensity of green(545nm)emission corresponding to the 5 D4→7 F5 transition within Tb^3+in the Ce^3+,Tb^3+-codoped samples was much higher than that of the Tb^3+-doped samples.The PL properties of the samples activated with various Ce^3+concentrations were measured,and their fluorescence lifetime and energy transfer mechanism were analyzed.We proved that there was energy transfer from Ce^3+to Tb^3+,and the energy transfer efficiency was at its maximum when the Ce^3+to Tb^3+mass ratio was 0.02∶0.03.Upon measurement by chromaticity coordinates,we found that the luminescence of the samples could be adjusted in the green area with varying Ce^3+concentrations.We thus deem that scapolite phosphors Na4Ca4Al6Si9O24∶Ce^3+,Tb^3+are promising to become the new white LED phosphors.展开更多
This paper presents a kind of attitude estimation algorithm based on quaternion-vector switching and square-root cubature Kalman filter for autonomous underwater vehicle(AUV).The filter formulation is based on geomagn...This paper presents a kind of attitude estimation algorithm based on quaternion-vector switching and square-root cubature Kalman filter for autonomous underwater vehicle(AUV).The filter formulation is based on geomagnetic field tensor measurement dependent on the attitude and a gyro-based model for attitude propagation. In this algorithm, switching between the quaternion and the three-component vector is done by a couple of the mathematical transformations. Quaternion is chosen as the state variable of attitude in the kinematics equation to time update, while the mean value and covariance of the quaternion are computed by the three-component vector to avoid the normalization constraint of quaternion. The square-root forms enjoy a continuous and improved numerical stability because all the resulting covariance matrices are guaranteed to stay positively semidefinite. The entire square-root cubature attitude estimation algorithm with quaternion-vector switching for the nonlinear equality constraint of quaternion is given. The numerical simulation of simultaneous swing motions in the three directions is performed to compare with the three kinds of filters and the results indicate that the proposed filter provides lower attitude estimation errors than the other two kinds of filters and a good convergence rate.展开更多
An orange reddish phosphor Sr BPO_(5):Sm^(3+)was synthesized by the traditional solid-state method.The phosphor component was characterized by the X-ray powder diffraction(XRD).The photoluminescence excitation(PLE)and...An orange reddish phosphor Sr BPO_(5):Sm^(3+)was synthesized by the traditional solid-state method.The phosphor component was characterized by the X-ray powder diffraction(XRD).The photoluminescence excitation(PLE)and emission spectra(PL)were investigated.The influence of the concentration of Sm^(3+)ions on luminescence properties of samples and concentration quenching mechanism were investigated.The results show that the as-prepared phosphor can be excited by 342 nm,358 nm,370 nm and 399 nm UV light and the strongest one at 399 nm.On being excited by 399 nm,the sample emits yellow,orange and red emission at different wavelength.The optimal activator molar fraction in this phosphor is 0.016 and the only sintering temperature is 1000℃.It is meant for enhancing the emission intensity of Sr BPO_(5):Sm^(3+)phosphor if appropriate Li^(+)ions are added as charge compensator.The thermal stability was evaluated by emission spectra of phosphor at different measuring temperatures.This research studied the influence of reaction temperature and charge compensator on the luminescence characteristics.The chromaticity coordinates of Sr BPO_(5):Sm^(3+),R+phosphor was explored.The results indicate that Sr BPO_(5):Sm^(3+),Li^(+)is a potential orange-reddish phosphor in near UV based white LEDs.展开更多
The photoacoustic spectrum of glucose,sucrose and honey solutions in the visible range are measured by using the single-light photoacoustic spectrometer,and are compared with the spectra from spectrophotometry method....The photoacoustic spectrum of glucose,sucrose and honey solutions in the visible range are measured by using the single-light photoacoustic spectrometer,and are compared with the spectra from spectrophotometry method.The spectral characteristics of the above solutions show that the spectral background intensity and spectral profile have some differences for different kinds of solutions.The spectra of the three kinds of solutions all have strong peak value at 485 and 655nm,but the intensity ratios between the two peaks are different.Besides,there are characteristic peak at 475,576 and 630nm for glucose,and the sucrose has apparent characteristic peak at 632 nm,these characteristic peaks can be used for detecting whether the natural honey has been added glucose or sucrose.By comparing two kinds of spectrum of the same solution,the intensity of photoacoustic spectrum is more responsive to the wavelength,indicating photoacoustic spectrometry has a higher sensitivity in the test of material composition.展开更多
A high-performance porous carbon material for supercapacitor electrodes was prepared by using a polymer blend method. Phenol-formaldehyde resin and gelatin were used as carbon precursor polymer and pore former polymer...A high-performance porous carbon material for supercapacitor electrodes was prepared by using a polymer blend method. Phenol-formaldehyde resin and gelatin were used as carbon precursor polymer and pore former polymer, respectively. The blends were carbonized at 800℃ in nitrogen. SEM, BET measurement and BJH method reveal that the obtained carbon possesses a mesoporous characteristic, with the average pore size between 3.0 nm and 5.0 nm. The electrochemical properties of supercapacitor using these carbons as electrode material were investigated by cyclic voltammetry and constant current charge-discharge. The results indicate that the composition of blended polymers has a strong effect on the specific capacitance. When the mass ratio of PF to gelatin is kept at 1：1, the largest surface area of 222 m2/g is obtained, and the specific capacitance reaches 161 F/g.展开更多
基金supported by the National KeyR&D Program of China(Grant No.2024YFB3817400)the National Natural Science Foundation of China(Grants No.12274276 and No.U24A6002)+1 种基金the Natural Science Foundation of Shanxi Province(China)(Grant No.202403021223008)Supported by Scientific and Technology Innovation Programs of Higher Education Institutions in Shanxi(Grant No.2024Q017 and No.2025L043).
文摘Layered transition-metal compounds(LTMCs)feature stacked architectures,strong magnetic anisotropy,and tunable magnetic order,making them promising material platforms for low-power spintronic technologies and for enabling topological functionalities in the post-Moore era.Here we review recent progress on two-dimensional(2D)magnetism in LTMCs,emphasizing material taxonomy,intrinsic magnetic properties,and external-field controls.This review first presents a classification of LTMCs by crystal structure and chemistry—binary halides,chalcogenides,and ternary families(e.g.,MPX_(3),M_(m)X_(n)Te_(k),MnBi_(2)Te_(4))—followed by a summary of their coupling mechanisms,ordering temperatures,and dimensional effects.It then analyzes the modulation of exchange interactions,magnetic anisotropy,and topological states by electric-field gating,strain engineering,and ion intercalation,with representative experimental demonstrations.Notable advances include room-temperature ferromagnetic metals and semiconductors,observation of the quantum anomalous Hall effect(QAHE)in MnBi2Te4,and synergistic control of magnetic-topological states under multiple external stimuli.Persistent challenges involve the limited availability of intrinsic 2D magnetic semiconductors with high Curie temperatures(Tc),incomplete understanding of the microscopic couplings at interfaces and under quantum confinement,and device-level stability.We conclude by outlining opportunities that lie in the integration of multiscale characterization,first-principles theory,and cross-scale fabrication to precisely co-engineer magnetism,topology,and electronic structure,thereby advancing LTMCs toward spintronic and topological-quantum applications.
文摘In this work,we report a fabrication of recyclable iron oxide decorated MoS_(2)nanosheets via a facile liq-uid exfoliation approach and solvothermal reaction for visible-light photodegradation of tetracycline.The prepared Fe_(3)O_(4)-MoS_(2)was characterized by X-ray diffraction,transmission electron microscopy,X-ray photoelectron spectros-copy,Raman spectroscopy,magnetic hysteresis,and nitrogen adsorption-desorption isotherms.Experimental results indicate that,successful attachment of Fe_(3)O_(4)nanoparticles to MoS_(2)sheets has been achieved.The enhanced surface area of Fe_(3)O_(4)-MoS_(2)induced high rates of adsorption and the adsorbed tetracycline was degraded to 90%after 150 min of visible exposure,which is better than that from pure MoS_(2).The introduction of Fe_(3)O_(4)not only enhances the photo-catalytic performance of Fe_(3)O_(4)-MoS_(2),but also enables its convenient recovery from water by an external magnetic field.Furthermore,both the photocatalytic activity and composite phase of Fe_(3)O_(4)-MoS_(2)were well-retained over cy-cles.Owing to its efficient photocatalytic activity,good stability and magnetic recyclability,the Fe_(3)O_(4)-MoS_(2)nano-composite is considered to be a promising photocatalyst for wastewater treatment.
基金National Natural Science Foundation of China(12125509,11961141003,12275361,U2267205,12175152,12175121)National Key Research and Development Project(2022YFA1602301)Continuous-support Basic Scientific Research Project。
文摘To generate a neutron beam exhibiting a Maxwellian energy distribution with narrow emission angles for measuring the neutron capture reaction rates of the s-process nuclides,a monoenergetic 3.4 MeV proton beam produced by the tandem-accelerator in the China Institute of Atomic Energy was utilized.The proton beam was first transmitted through a 60.5μm aluminum foil and then impinged on a natural LiF target to produce neutron beam via^(7)Li(p,n)7Be reaction.The quasi-Gaussian energy distribution of protons in the LiF target resulted in neutron energy spectra that agreed with a Maxwellian energy distribution at kT=(22±2)keV,which was achieved by integrating neutrons detected within an emission angle of 65.0°±2.6°using a ^(6)Li glass detector positioned at 65°relative to the proton beam direction.The narrow angular spread of the Maxwelliandistributed neutron beam enables direct measurement of neutron capture cross-sections for most s-process nuclides,overcoming previous experimental limitations associated with broad angular distributions.
基金the National Natural Science Foundation of China(12274170 and 52225203)。
文摘Lonsdaleite,also known as hexagonal diamond,is an allotrope of carbon with a hexagonal crystal structure,which was discovered in the nanostructure of the Canyon Diablo meteorite.Theoretical calculations have shown that this structure gives it exceptional physical properties that exceed those of cubic diamond,making it highly promising for groundbreaking applications in superhard cutting tools,wide-bandgap semiconductor devices,and materials for extreme environments.As a result,the controllable synthesis of hexagonal diamond has emerged as a cutting-edge research focus in materials science.This review briefly outlines the progress in this area,with a focus on the mechanisms governing its key synthesis conditions,its intrinsic physical properties,and its potential applications in various fields.
文摘ZnO is a highly significant II-VI semiconductor known for its excellent optoelectronic properties,making it widely applicable and promising for use in light-emitting devices,solar cells,lasers,and photodetectors.The methods for preparing ZnO are diverse,and among them,the hydrothermal method is favored for its simplicity,ease of operation,and low cost,making it an optimal choice for ZnO single-crystal growth.Most studies investigating the effects of different hydrothermal experimental parameters on the morphology and performance of ZnO nano-materials typically focus on only 2—3 variable parameters,with few examining the impact of all possible experimental parameter changes on ZnO nano-mate-rials.The principles of the hydrothermal method and its advantages in nano-material preparation were briefly introduced in this article.The detailed discussion on the influence of various experimental parameters on the preparation of ZnO nano-materials was provided,which including reaction materials,Zn^(2+)/OH^(-)ratio,reaction time and temperature,additives,experimental equipment,and annealing conditions.The review co-vers how different experimental parameters affect the morphology and performance of the materials,as well as how different rare earth doping elements influence the performance of ZnO nano-materials.It is hoped that this work will contribute to future research on the hydrothermal synthesis of nano-materials.
文摘Based on the service characteristics of fuel elements for molten salt reactors,they need to have a high power density,resistance to coolant infiltration,and excellent thermodynamic properties.To solve the problem of the graphite used in the fuel element for these reactors being susceptible to molten salt infiltration,carbon black(CB)was added to increase the density of the graphite,and a fuel element(TRISO(tri-structural isotropic)fuel particles were randomly distributed in the modified graphite matrix)was prepared by cold isostatic pressing process.An out-of-pile performance study shows that the densification and pore structure of the modified graphite matrix were improved,as was the resistance to molten salt infiltration.The median pore size of the modified graphite was reduced from 673 to 433 nm and the threshold pressure for molten salt(FLiBe,66%(molar fraction)LiF and 34%BeF_(2))infiltration was increased from 0.88 to 1.37 MPa.The isotropic CB made the graphite matrix less anisotropic,while its thermal conductivity and compressive strength were reduced due to the difficult graphitization of CB.Fuel elements containing 20%(volume fraction)TRISO particles were prepared.Numerical simulations show that the power and temperature distribution of the fuel were in line with the design requirements.The modified graphite matrix had a higher density,smaller pores,a lower anisotropy and a greater resistance to FLiBe infiltration.
基金Project(2024YFB4608600)supported by the National Key Research and Development Program of ChinaProjects(52271063,U21B2066,U24B2024)supported by the National Natural Science Foundation of China+3 种基金Project(JSGG20210713091539014)supported by the Shenzhen Science and Technology Innovation Commission Key Technical Project,ChinaProject(HNGD2025040)supported by the Overseas High-Level Talents Introduction of Henan Province,ChinaProject(240621041)supported by the Fundamental Research Funds of Henan Academy of Sciences,ChinaProject(20231120233925001)supported by Stabilization Support Program for Higher Education Institutions of Shenzhen,China。
文摘In this work,tensile mechanical behavior of 316L steels fabricated by three different processing methods(casting,powder extrusion printing(PEP)and laser powder bed fusion(LPBF))was studied in the presence of liquid lead-bismuth eutectic(LBE)and air at 350℃.The results show that all three steels tested in LBE are not subjected to evident degradation of tensile elongation to failure and strength compared to those tested in air,suggesting that LME does not occur regardless of the processing methods.The LPBF 316L steel exhibits the highest yield strength(420-435 MPa),followed by casting 316 L(~242 MPa)and PEP 316L(146-165 MPa).Ultimate tensile strength of three steels is comparable and ranges from 427 to 485 MPa.The PEP and casting 316L steels have similar total elongation to failure(i.e.,40.0%-43.8%),whereas this property decreases markedly to 18.6%-19.5% for the LPBF 316 L steel.The superior strength and relatively low ductility of the LPBF 316L steel can be attributed to nanosized dislocations trapped at cell structures which can produce a remarkable strengthening effect to the steel matrix.By contrast,due to massive residual micropores,the PEP 316L steel has the lowest strength.
基金supported by the Natural Science Foundation of Shanghai(Grant No.24ZR1401700)Fundamental Research Funds for the Central Universities(Grant No.2232022D-28)the Young Elite Scientists Sponsorship Program by the China Association for Science and Technology(Grant No.2016QNRC001).
文摘This paper focuses on the high-temperature tensile failure mechanism of RTM(resin transfer moulding)-made symmetric and asymmetric composite T-joints.The failure modes as well as the load-displacement curves of symmetric(three specimens)and asymmetric(three specimens)composite T-joints were determined by tensile tests at room and high temperatures.Progressive damage models(PDMs)of symmetric and asymmetric composite T-joints at room and high temperatures were established based on mixed criteria,and the result predicted from the aforementioned PDMs were compared with experimental data.The predicted initial and final failure loads and failure modes are in good agreement with the experimental results.The failure mechanisms of composite T-joints at different temperatures were investigated by scanning electron microscopy.The results reveal that while the failure mode of asymmetric T-joints at high temperatures resembles that at room temperature,there is a difference in the failure modes of symmetric T-joints.The ultimate failure load of symmetric and asymmetric T-joints at elevated temperatures increases and reduces by 18.4%and 4.97%,albeit with a more discrete distri-bution.This work is expected to provide us with more knowledge about the usability of composite T-joints in elevated temperature environments.
基金Supported by National Natural Science Foundation of China （61079001, 61273006）, National High Technology Research and Development Program of China （863 Program） （2011AA110301）, and Specialized Research Fund for the Doctoral Program of Higher Education of China （20111103110017）
基金Projects(52075552,51575533,51805555,11662004)supported by the National Natural Science Foundation of China。
文摘In this work,synchronous cutting of concave and convex surfaces was achieved using the duplex helical method for the hypoid gear,and the problem of tooth surface error correction was studied.First,the mathematical model of the hypoid gears machined by the duplex helical method was established.Second,the coordinates of discrete points on the tooth surface were obtained by measurement center,and the normal errors of the discrete points were calculated.Third,a tooth surface error correction model is established,and the tooth surface error was corrected using the Levenberg-Marquard algorithm with trust region strategy and least square method.Finally,grinding experiments were carried out on the machining parameters obtained by Levenberg-Marquard algorithm with trust region strategy,which had a better effect on tooth surface error correction than the least square method.After the tooth surface error is corrected,the maximum absolute error is reduced from 30.9μm before correction to 6.8μm,the root mean square of the concave error is reduced from 15.1 to 2.1μm,the root mean square of the convex error is reduced from 10.8 to 1.8μm,and the sum of squared errors of the concave and convex surfaces was reduced from 15471 to 358μm^(2).It is verified that the Levenberg-Marquard algorithm with trust region strategy has a good accuracy for the tooth surface error correction of hypoid gear machined by duplex helical method.
基金Supported by National Natural Science Foundation of China （61079001, 61273006）, National High Technology Research and Development Program of China （863 Program） （2011AAl10301）, Specialized Research Fund for the Doctoral Program of Higher Education of China （20111103110017）, Hebei Province Science and Technology Research and Development Planning Project （10203548D）, Hebei Province Science and Technology Planning Project （13210807） Hebei Province Science and Technology Conditions Building Program （11963546D）
基金Project(11174077)supported by the National Natural Science Foundation of ChinaProject(11JJ3079)supported by the Hunan Provincial Natural Science Foundation of ChinaProjects(12C0237,11C0844)supported by the Science Research Program of Education Department of Hunan Province,China
文摘High intensity focused ultrasound(HIFU)therapy is an effective method in clinical treatment of tumors,in order to explore the bio-heat conduction mechanism of in multi-layer media by concave spherical transducer,temperature field induced by this kind of transducer in multi-layer media will be simulated through solving Pennes equation with finite difference method,and the influence of initial sound pressure,absorption coefficient,and thickness of different layers of biological tissue as well as thermal conductivity parameter on sound focus and temperature distribution will be analyzed,respectively.The results show that the temperature in focus area increases faster while the initial sound pressure and thermal conductivity increase.The absorption coefficient is smaller,the ultrasound intensity in the focus area is bigger,and the size of the focus area is increasing.When the thicknesses of different layers of tissue change,the focus position changes slightly,but the sound intensity of the focus area will change obviously.The temperature in focus area will rise quickly before reaching a threshold,and then the temperature will keep in the threshold range.
基金Project(51164001)supported by the National Natural Science Foundation of China
文摘First-principles calculations are performed to investigate the relaxation and electronic properties of sulfide minerals surfaces(MoS2, Sb2S3, Cu2 S, ZnS, PbS and FeS2) in presence of H2 O molecule. The calculated results show that the structure and electronic properties of sulfide minerals surfaces have been influenced in presence of H2 O molecule. The adsorption of the flotation reagent at the interface of mineral-water would be different from that of mineral surface due to the changes of surface structures and electronic properties caused by H2 O molecule. Hence, the influence of H2 O molecule on the reaction of flotation reagent with sulfide mineral surface will attract more attention.
基金Project supported by National Natural Science Foundation of China （11365019 41005004）.
文摘The plasma characteristics of a lightning discharge channel are reviewed.The spectrum of the natural lightning is investigated by employing the slit-less spectrograph.It is found that the spectrum characteristics are closely related to the intensity of the lightning discharge.The lines in the lightning spectrum are classified into essential lines and characteristic lines,according to the characteristics of lightning spectra with different intensities.The characteristics of the lightning channel and the radiation of the lighting plasma are analyzed in the visible and infrared regions.It is shown that,the visible spectrum of lightning is determined by the radiation generated from the early stage to the development of lightning,while the near-infrared spectrum is determined by the radiation generated after current of lightning reaches the peak.The channel temperature and the electron density are calculated using the information obtained from the lightning spectrum.Both the temperature and the density decrease with the increasing length of lightning channel.Moreover,X-rays and neutrons are produced in the process of lighting mainly due to the pinch effects.
基金Project(2006CB600901) supported by the Major State Basic Research and Development Program of ChinaProject(0991015) supported by Guangxi Science Found, ChinaProject(200808MS083) supported by Guangxi Education Department Found
文摘C/C-SiC composites with SiC island distribution Were prepared via a new processing route. The fabrication process mainly included silicon infiltration by ultrasonic vibration, chemical vapor deposition （CVD）, siliconizing, liquid phase impregnation and carbonization. The wear and friction properties were tested by an MM-1000 wet friction machine. The results show that SiC phases are mainly distributed between carbon fibers and pyrocarbons as well as among the pryoearbons. The dynamic friction coefficient of the composites decreases gradually from 0.126 to 0.088 with the increase of the surface pressure from 0.5 to 2.5 MPa at the same rotary speed. Furthermore, under the constant surface pressure, the dynamic friction coefficient increases from 0.114 to 0.126 with the increase of the rotary speed from 1 500 to 2 500 r/min. However, the coefficient decreases to 0.104 when the rotary speed exceeds 4 500 r/min. During the friction process, the friction coefficient of C/C-SiC composite is between 0.088 and 0.126, and the wear value is zero after 300 times brake testing.
基金the National Natural Science Foundation(11264040,No.11464045)The doctoral scientific research foundation of Xinjiang Normal University(XJNUBS1409)
文摘Natural scapolite including the S-2impurity is a typical silicate luminescent mineral.According to the formation conditions and chemical composition of natural scapolite,we synthesized Na_(4)Ca_(4)Al_(6)Si_(9)O_(24)(scapolite)by the high temperature solid-phase reaction,and prepared the synthetic scapolite phosphors activated with Ce^3+and Tb^3+.The photoluminescence(PL)properties of the obtained phosphors were studied.The results indicated that the PL intensity of green(545nm)emission corresponding to the 5 D4→7 F5 transition within Tb^3+in the Ce^3+,Tb^3+-codoped samples was much higher than that of the Tb^3+-doped samples.The PL properties of the samples activated with various Ce^3+concentrations were measured,and their fluorescence lifetime and energy transfer mechanism were analyzed.We proved that there was energy transfer from Ce^3+to Tb^3+,and the energy transfer efficiency was at its maximum when the Ce^3+to Tb^3+mass ratio was 0.02∶0.03.Upon measurement by chromaticity coordinates,we found that the luminescence of the samples could be adjusted in the green area with varying Ce^3+concentrations.We thus deem that scapolite phosphors Na4Ca4Al6Si9O24∶Ce^3+,Tb^3+are promising to become the new white LED phosphors.
基金supported by the National Natural Science Foundation of China(1140503561004130+4 种基金60834005)the Natural Science Foundation of Heilongjiang Province of China(F201414)the Postdoctoral Scientific Research Developmental Fund of Heilongjiang Province(LBHQ15034)the Stable Supporting Fund of Acoustic Science and Technology Laboratory(JCKYS2019604SSJS002)the Fundamental Research Funds for the Central Universities。
文摘This paper presents a kind of attitude estimation algorithm based on quaternion-vector switching and square-root cubature Kalman filter for autonomous underwater vehicle(AUV).The filter formulation is based on geomagnetic field tensor measurement dependent on the attitude and a gyro-based model for attitude propagation. In this algorithm, switching between the quaternion and the three-component vector is done by a couple of the mathematical transformations. Quaternion is chosen as the state variable of attitude in the kinematics equation to time update, while the mean value and covariance of the quaternion are computed by the three-component vector to avoid the normalization constraint of quaternion. The square-root forms enjoy a continuous and improved numerical stability because all the resulting covariance matrices are guaranteed to stay positively semidefinite. The entire square-root cubature attitude estimation algorithm with quaternion-vector switching for the nonlinear equality constraint of quaternion is given. The numerical simulation of simultaneous swing motions in the three directions is performed to compare with the three kinds of filters and the results indicate that the proposed filter provides lower attitude estimation errors than the other two kinds of filters and a good convergence rate.
基金National Natural Science Foundation of China(61205180)Natural Science Foundation of Hebei Province,China(A2012201013)Distinguished Young Scholars of Hebei University(2012JQ01)
文摘An orange reddish phosphor Sr BPO_(5):Sm^(3+)was synthesized by the traditional solid-state method.The phosphor component was characterized by the X-ray powder diffraction(XRD).The photoluminescence excitation(PLE)and emission spectra(PL)were investigated.The influence of the concentration of Sm^(3+)ions on luminescence properties of samples and concentration quenching mechanism were investigated.The results show that the as-prepared phosphor can be excited by 342 nm,358 nm,370 nm and 399 nm UV light and the strongest one at 399 nm.On being excited by 399 nm,the sample emits yellow,orange and red emission at different wavelength.The optimal activator molar fraction in this phosphor is 0.016 and the only sintering temperature is 1000℃.It is meant for enhancing the emission intensity of Sr BPO_(5):Sm^(3+)phosphor if appropriate Li^(+)ions are added as charge compensator.The thermal stability was evaluated by emission spectra of phosphor at different measuring temperatures.This research studied the influence of reaction temperature and charge compensator on the luminescence characteristics.The chromaticity coordinates of Sr BPO_(5):Sm^(3+),R+phosphor was explored.The results indicate that Sr BPO_(5):Sm^(3+),Li^(+)is a potential orange-reddish phosphor in near UV based white LEDs.
基金National Natural Science Foundation of China under Grant(11475139,11365019)
文摘The photoacoustic spectrum of glucose,sucrose and honey solutions in the visible range are measured by using the single-light photoacoustic spectrometer,and are compared with the spectra from spectrophotometry method.The spectral characteristics of the above solutions show that the spectral background intensity and spectral profile have some differences for different kinds of solutions.The spectra of the three kinds of solutions all have strong peak value at 485 and 655nm,but the intensity ratios between the two peaks are different.Besides,there are characteristic peak at 475,576 and 630nm for glucose,and the sucrose has apparent characteristic peak at 632 nm,these characteristic peaks can be used for detecting whether the natural honey has been added glucose or sucrose.By comparing two kinds of spectrum of the same solution,the intensity of photoacoustic spectrum is more responsive to the wavelength,indicating photoacoustic spectrometry has a higher sensitivity in the test of material composition.
基金Projects(50772033,50972043) supported by the National Natural Science Foundation of ChinaProject(09JJ3095) supported by the Natural Science Foundation of Hunan Province,China+2 种基金Project(09A001) supported by the Scientific Research Fund of Hunan Provincial Education Department,ChinaProject(2010FJ3151) supported by the Science and Research Plan of Hunan Province,ChinaProject supported by the Science and Technology Innovative Research Team in Higher Education Institution of Hunan Province,China
文摘A high-performance porous carbon material for supercapacitor electrodes was prepared by using a polymer blend method. Phenol-formaldehyde resin and gelatin were used as carbon precursor polymer and pore former polymer, respectively. The blends were carbonized at 800℃ in nitrogen. SEM, BET measurement and BJH method reveal that the obtained carbon possesses a mesoporous characteristic, with the average pore size between 3.0 nm and 5.0 nm. The electrochemical properties of supercapacitor using these carbons as electrode material were investigated by cyclic voltammetry and constant current charge-discharge. The results indicate that the composition of blended polymers has a strong effect on the specific capacitance. When the mass ratio of PF to gelatin is kept at 1：1, the largest surface area of 222 m2/g is obtained, and the specific capacitance reaches 161 F/g.
