For regional ecological management,it is important to evaluate the quality of ecosystems and analyze the underlying causes of ecological changes.Using the Google Earth Engine(GEE)platform,the remote sensing ecological...For regional ecological management,it is important to evaluate the quality of ecosystems and analyze the underlying causes of ecological changes.Using the Google Earth Engine(GEE)platform,the remote sensing ecological index(RSEI)was calculated for the Lijiang River Basin in Guangxi Zhuang Autonomous Region for 1991,2001,2011,and 2021.Spatial autocorrelation analysis was employed to investigate spatiotemporal variations in the ecological environmental quality of the Lijiang River Basin.Furthermore,geographic detectors were used to quantitatively analyze influencing factors and their interaction effects on ecological environmental quality.The results verified that:1)From 1991 to 2021,the ecological environmental quality of the Lijiang River Basin demonstrated significant improvement.The area with good and excellent ecological environmental quality in proportion increased by 19.69%(3406.57 km^(2)),while the area with fair and poor ecological environmental quality in proportion decreased by 10.76%(1860.36 km^(2)).2)Spatially,the ecological environmental quality of the Lijiang River Basin exhibited a pattern of low quality in the central region and high quality in the periphery.Specifically,poor ecological environmental quality characterized the Guilin urban area,Pingle County,and Lingchuan County.3)From 1991 to 2021,a significant positive spatial correlation was observed in ecological environmental quality of the Lijiang River Basin.Areas with high-high agglomeration were predominantly forests and grasslands,indicating good ecological environmental quality,whereas areas with low-low agglomeration were dominated by cultivated land and construction land,indicating poor ecological environmental quality.4)Annual average precipitation and temperature exerted the most significant influence on the ecological environmental quality of the basin,and their interactions with other factors had the great influence.This study aimed to enhance understanding of the evolution of the ecological environment in the Lijiang River Basin of Guangxi Zhuang Autonomous Region and provide scientific guidance for decision-making and management related to ecology in the region.展开更多
Cleat serves as the primary flow pathway for coalbed methane(CBM)and water.However,few studies consider the impact of local contact on two-phase flow within cleats.A visual generalized model of endogenous cleats was c...Cleat serves as the primary flow pathway for coalbed methane(CBM)and water.However,few studies consider the impact of local contact on two-phase flow within cleats.A visual generalized model of endogenous cleats was constructed based on microfluidics.A microscopic and mesoscopic observation technique was proposed to simultaneously capture gas-liquid interface morphology of pores and throat and the two-phase flow characteristics in entire cleat system.The local contact characteristics of cleats reduced absolute permeability,which resulted in a sharp increase in the starting pressure.The reduced gas flow capacity narrowed the co-infiltration area and decreased water saturation at the isotonic point in a hydrophilic environment.The increased local contact area of cleats weakened gas phase flow capacity and narrowed the co-infiltration area.Jumping events occurred in methane-water flow due to altered porosity caused by local contact in cleats.The distribution of residual phases changed the jumping direction on the micro-scale as well as the dominant channel on the mesoscale.Besides,jumping events caused additional energy dissipation,which was ignored in traditional two-phase flow models.This might contribute to the overestimation of relative permeability.The work provides new methods and insights for investigating unsaturated flow in complex porous media.展开更多
A long-standing mystery in the study of Field-Aligned Currents(FACs) has been that: how the currents are generated and why they appear to be much stronger at high altitudes than in the ionosphere. Here we present two ...A long-standing mystery in the study of Field-Aligned Currents(FACs) has been that: how the currents are generated and why they appear to be much stronger at high altitudes than in the ionosphere. Here we present two events of magnetotail FACs observed by the Magnetospheric Multiscale Spacecraft(MMS) on 1 st July and 14 th July 2016, to show how the Substorm Current Wedges(SCW) were formed. The results show that particles were transferred heading towards the Earth during the expansion phase of substorms.The azimuthal flow formed clockwise(counter-clockwise) vortex-like motion, and then generated downward(upward) FACs on the tailward/poleward side of the distorted field with opposite vorticity on their Earthward/equatorward side. We also analyzed the Region 1 FACs observed by the Earth Explorer Swarm spacecraft on 1 st July 2016 and found that they were associated with FACs observed by MMS, although differing by a factor of 10. This difference suggests that either there was the closure of the currents at altitudes above 500 km or the currents were not strictly parallel to B and closed at longitudes away from where they were generated.展开更多
The Pinghu slope belt in the Xihu sag of the East China Sea Shelf Basin(ECSSB) is a crucial hydrocarbon production area in eastern China. However, due to the complex geological conditions, publications have lacked com...The Pinghu slope belt in the Xihu sag of the East China Sea Shelf Basin(ECSSB) is a crucial hydrocarbon production area in eastern China. However, due to the complex geological conditions, publications have lacked comprehensive research on the spatial-temporal coupling relationships of primary factors that impact hydrocarbon accumulation in the Pinghu slope belt. Furthermore, the hydrocarbon distribution patterns and the controlling factors across different study areas within the same slope belt are not yet fully understood. This study extensively utilized three-dimensional seismic data, well logging data,geochemical analysis, fluorescence analysis, and oil testing and production data to address these issues.Following a “stratification and differentiation” approach, the study identified seven distinct hydrocarbon migration and accumulation units(HMAU) in the Pinghu slope area based on the structural morphology characteristics, hydrocarbon source-reservoir-cap rock patterns, hydrocarbon migration pathways, and hydrocarbon supply range. Detailed analysis was conducted to examine the hydrocarbon distribution patterns and controlling factors within each migration and accumulation unit across different structural units, including high, medium, and low structural components. All data sources support a “southern-northern sub-area division, eastern-western sub-belt division, and variations in hydrocarbon accumulation” pattern in the Pinghu slope belt. The degree of hydrocarbon accumulation is controlled by the factors of structural morphology, hydrocarbon generation potential of source rocks, the spatial position of source slopes, fault sealing capacity, and sand body distribution. Furthermore, different coupling patterns of faults and sand bodies play a pivotal role in governing hydrocarbon enrichment systems across various migration and accumulation units. These observations indicate that three hydrocarbon accumulation patterns have been established within the slope belt, including near-source to far-source gentle slope with multiple hydrocarbon kitchens in the XP1-XP4 zones, near-source to middle-source gentle slope with dual-hydrocarbon kitchens in the XP5 zone, and near-source steep slope with a single hydrocarbon kitchen in the XP6-XP7 zones. These findings contribute to enhancing the theoretical system of hydrocarbon accumulation in the slope belt.展开更多
The mineralogical development and diagenetic sequence of lacustrine shales in the Chang 7 Member of the Yanchang Formation in the Ordos Basin are detailed studied.A model of their depositional system and a diagenetic ...The mineralogical development and diagenetic sequence of lacustrine shales in the Chang 7 Member of the Yanchang Formation in the Ordos Basin are detailed studied.A model of their depositional system and a diagenetic diagram are proposed in this study.Through detailed petrographic,mineralogical,and elemental analyses,four distinct shale types are identified:argillaceous shale,siliceous shale,calcareous shale,and carbonate,clay,and silt-bearing shale.The main diagenetic process in argillaceous shale is the transformation of illite to smectite,negatively impacting shale porosity.Siliceous shale undergoes carbonate cementation and quartz dissolution,contributing to increased porosity,particularly in mesopores.Calcareous shale experiences diagenesis characterised by carbonate formation and dissolution,with a prevalence of siderite.In carbonate,clay,and silt-bearing shale,the dissolution of K-feldspar contributes to illitization of kaolinite.Argillaceous shale,characterised by more clay minerals and lower mesopore volume,is identified as a potential hydrocarbon seal.Siliceous shale,with the highest pore volume and abundant inter-mineral pores,emerges as a promising shale oil reservoir.These findings contribute to a comprehensive understanding of shale properties,aiding in the prediction of shale oil exploration potential in the studied area.展开更多
Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes th...Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes the formation conditions of large-and medium-sized Cretaceous volcanic oil and gas reservoirs in the Bohai Sea.Research shows that the Mesozoic large intermediate-felsic lava and intermediate-felsic composite volcanic edifices in the Bohai Sea are the material basis for the formation of large-scale volcanic reservoirs.The upper subfacies of effusive facies and cryptoexplosive breccia subfacies of volcanic conduit facies of volcanic vent-proximal facies belts are favorable for large-scale volcanic reservoir formation.Two types of efficient reservoirs,characterized by high porosity and medium to low permeability,as well as medium porosity and medium to low permeability,are the core of the formation of large-and medium-sized volcanic reservoirs.The reservoir with high porosity and medium to low permeability is formed by intermediate-felsic vesicular lava or the cryptoexplosive breccia superimposed by intensive dissolution.The reservoir with medium porosity and medium to low permeability is formed by intense tectonism superimposed by fluid dissolution.Weathering and tectonic transformation are main formation mechanisms for large and medium-sized volcanic reservoirs in the study area.The low-source“source-reservoir draping type”is the optimum source-reservoir configuration relationship for large-and medium-sized volcanic reservoirs.There exists favorable volcanic facies,efficient reservoirs and source-reservoir draping configuration relationship on the periphery of Bozhong Sag,and the large intermediate-felsic lava and intermediate-felsic composite volcanic edifices close to strike-slip faults and their branch faults are the main directions of future exploration.展开更多
The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin wer...The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin were quantitatively evaluated by organic geochemistry and microscopic pore structure characterization experiments.The Multiple Isothermal Stages Pyrolysis(MIS)experiment results show that the content of total oil,adsorbed oil,and free oil in the shales are 3.15-11.25 mg/g,1.41-4.95 mg/g,and 1.74-6.51 mg/g,respectively.among which the silicon-rich shale has the best oil-bearing.The relative content of free oil shows an increasing trend in pores with pore diameters greater than 3 nm.When the relative content of free oil reaches 100%,the pore size of silicon-rich shale is about 200 nm,while that of calcium-rich shale,clay-rich shale,and siliceous mixed shale is about 10 nm.The occurrence law of adsorbed oil is opposite to that of free oil,which indicates that shale oil will occur in the pores and fractures in a free state in a more extensive pore size range(>200 nm).This study also enables us to further understand the occurrence characteristics of shale oil under the interaction of occurrence state and occurrence space.展开更多
The Jurassic coal-measure source rocks in the Junggar Basin have drawn considerable attention in recent years. In our hydrocarbon thermal simulation experiments of these rocks, we found that the dark mudstone evaluate...The Jurassic coal-measure source rocks in the Junggar Basin have drawn considerable attention in recent years. In our hydrocarbon thermal simulation experiments of these rocks, we found that the dark mudstone evaluated as good source rock, had a much lower hydrocarbon generation capacity than the coal and carbonaceous mudstone, evaluated as poor source rock. Based on this background, we performed Fourier transform infrared spectroscopy(FTIR) and combined the results of semi-open thermal simulation experiments to explore the association between the molecular structure and hydrocarbon production capacity, with the aim of obtaining a new understanding of hydrocarbon potential of Jurassic coal-measure source rocks from the perspective of molecular structure. The results indicate that coals exhibit lower condensation of aromatic structures and higher relative abundance of aliphatic structures with a higher degree of branched chaining than mudstones and carbonaceous mudstones. Apparent aromaticity(f_a), aromatic abundance parameter I, and degree of condensation(DOC) are negatively correlated with organic matter abundance. The aliphatic structural parameter H demonstrates a substantial positive correlation with organic matter abundance. Furthermore, aliphatic relative abundance factor A is associated with the type of organic matter;the better is the type of the organic matter, the larger is the A value. The combination of the molecular structures with the thermal simulation results shows that the aliphatic hydrogen enrichment of selected carbonaceous mudstone is similar to that of coal. However, the relative abundance of the aliphatic group of it is high, and the DOC of the aromatic structure is low, making the hydrocarbon generation base stronger and easier to crack. Thus, the hydrocarbon generation capacity of carbonaceous mudstone is slightly higher than that of coal. Mudstone has low H and I values, and the DOC is high, indicating that its hydrocarbon base is low, so it has low hydrocarbon generation capacity. Therefore, the molecular structure is closely associated with the hydrocarbon potential of coal-measure source rocks. When evaluating the qualities of coal-measure source rocks, the influence of molecular structure on these rocks should be considered.展开更多
Characterizing the microscopic occurrence and distribution of in-situ pore water and oil is crucial for resource estimation and development method selection of shale oil.In this paper,a series of nuclear magnetic reso...Characterizing the microscopic occurrence and distribution of in-situ pore water and oil is crucial for resource estimation and development method selection of shale oil.In this paper,a series of nuclear magnetic resonance(NMR)experiments were conducted on shales from the Gulong Sag,Songliao Basin,China,at AR,WR-AR,WOR-AR,Dry,SO,and WR states.In-situ pore water and oil were reconstructed after WOR-AR.An improved T1-T2pattern for shale oil reservoirs comprising water and oil was proposed to classify and quantitatively detect pore fluids at different occurrence states.The total and free oil contents derived from NMR T1-T2spectra at AR states were found to correlate well with those from multistage Rock-Eval.Moreover,the NMR-calculated total and free oil are generally larger than those measured from multistage Rock-Eval,whereas adsorbed oil is the opposite,which implies that adsorbed,bound,and movable oils in shale pores can be accurately and quantitatively detected via NMR,without absorbed hydrocarbons in kerogen.As per the NMR T2and T1-T2spectra at WOR-AR state,the micro-distributions of in-situ pore water and oil were clearly demonstrated.Adsorbed,bound,and movable oils primarily occur in the micropores(<100 nm),mesopores(100-1000 nm),and macropores(>1000 nm),respectively,whereas capillary-bound water is primarily correlated with micropores.Thus,the microscopic occurrence and distribution of adsorbed oil are remarkably affected by pore water,followed by bound oil,and movable oil is hardly affected.This study would be helpful in further understanding the microscopic occurrence characteristics of pore fluids in-situ shale oil reservoirs.展开更多
Using the large-scale thick 4# coal seam from the Mid-Jurassic in the southern Ordos Basin as an example, this paper studied the net primary productivity(NPP) level of the Mid-Jurassic peatland, and discussed its cont...Using the large-scale thick 4# coal seam from the Mid-Jurassic in the southern Ordos Basin as an example, this paper studied the net primary productivity(NPP) level of the Mid-Jurassic peatland, and discussed its control factors. Geophysical logging signals were used for a spectrum analysis to obtain the Milankovitch cycle parameters in coal seam. These were then used to calculate the accumulation rate of the residual carbon in 4# coal seam. The carbon loss can be calculated according to the density and residual carbon content of 4# coal seam. Then, the total carbon accumulation rate of the peatland was further derived, and the NPP of peatland was determined. The results show that the NPP of MidJurassic peatland is higher than that of Holocene at the same latitude. Comprehensive analysis indicates that the temperature, carbon dioxide and oxygen levels in atmosphere are the main control factors of the NPP of Mid-Jurassic peatland.展开更多
Coal and oil shale are two common sedimentary energy sources which are often symbiotically developed in M esozoic- Cenozoic continental fault basins. However, the mechanisms and characteristics of the symbiotic develo...Coal and oil shale are two common sedimentary energy sources which are often symbiotically developed in M esozoic- Cenozoic continental fault basins. However, the mechanisms and characteristics of the symbiotic development are not yet clearly known. In this research study, the typical continental fault basins of eastern China were chosen as examples for the purpose of conducting an examination of the coal and oil shale symbiotic assemblage types, genetic environmental differences, and transformation mechanisms, as well as the development and occurrence characteristics o f different assemblage types. Through a large number of investigations, systematic experimental testing, and sequence stratigraphy studies, the following conclusions were obtained:(1) There were five types of coal and oil shale symbiotic assemblages observed in the continental fault basins,(2) The development of coal and oil shale deposits requires a warm and humid climate, stable structure, abundant organic matter supply, a certain water depth, and a lower terrestrial source debris supply. The observed differences were that the water depth conditions were diversified in the study area, as well as the sources, types, and content of the organic matter.(3) The rapid transformations of the coal and oil shale genetic environments were mainly controlled by the tectonic settings and climatic conditions, which were determined to control the changes in the water depths, salinity,redox conditions, and lake productivity of the genetic environments. Also, in the symbiotic assemblages, genetic environment changes had induced the development of oil shale deposits, which gradually evolved into coal genetic environments.(4) In the isochronous sequence stratigraphic framework of the coal and oil shale symbiotic assemblages, the lake expansion system tracts (EST) were determined to be the most beneficial to the growth o f all the types of assemblages and were characterized by more assemblage development phases and smaller bed thicknesses. From the early to the late stages of the EST, and from the lakesides to lake centers, the thicknesses of the coal seams in the symbiotic assemblages showed trends of thinning, while the thicknesses of the oil shale deposits exhibited increasing trends. The early stages of high stand system tracts were found to be beneficial to the development of the symbiotic assemblages of coal seams overlying the oil shale. This tract type generally presented large bed thicknesses and distribution ranges. The low stand system tract and the late high stand system tract were determined to be unconducive to the development of the symbiotic assemblages.展开更多
Study of dolomite texture can contribute to understanding the process of dolomitization.This research reports textures and homogenization temperatures of dolomites from the Permian-Triassic strata in the Sichuan Basin...Study of dolomite texture can contribute to understanding the process of dolomitization.This research reports textures and homogenization temperatures of dolomites from the Permian-Triassic strata in the Sichuan Basin and the Lower Paleozoic strata in the Tarim Basin,which provided insights into relationships between dolomite textures and their formation temperatures.Our results are summarized as follows：1） dolomites with well-preserved texture indicate low dolomitization temperature.However,in certain diagenetic environments,the hydrothermal dolomitization may completely or partially preserve the original texture of dolomites.2） The formation temperatures of non-planar dolomites are always higher than those of planar dolomites.3） The formation temperatures of dolomite cements are generally higher than those of replacive dolomites.4） Although the formation temperatures of saddle dolomite cements have a wide range,they show higher values than those of the planar subhedral to euhedral dolomite cements.Thus,saddle dolomites could generally be an indicator of high precipitation temperature.5） The fluid Mg/Ca ratio is another element controlling dolomite morphology.Micritic dolomites,which precipitate from hypersaline fluids with a high Mg/Ca ratio in a subaerial environment could also have features of non-planar anhedral crystal shape because of rapid nucleation and crystallization during dolomitization.展开更多
High-energy electron precipitation in the high latitude regions enhances the ionization of the atmosphere,and subsequently increases the atmospheric conductivities and the vertical electric field of the atmosphere nea...High-energy electron precipitation in the high latitude regions enhances the ionization of the atmosphere,and subsequently increases the atmospheric conductivities and the vertical electric field of the atmosphere near the ground as well.The High-Energy Electron Flux(HEEF) data measured by the Fengyun-3 meteorological satellite are analyzed together with the data of nearsurface atmospheric vertical electric field measured at the Russian Vostok Station.Three HEEF enhancements are identified and it is shown that when the HEEF increases to a certain level,the local atmospheric vertical electric field near the ground can increase substantially than usual.The response time of the electric field to HEEF enhancement is about 3.7 to 4 days.展开更多
Microorganism DNA of rhizosphere soil from Pinus koraiensis and Pinus sylvestriformis were extracted by proteinase K based on SDS method, CTAB method, PVP （polyvinylpolypyrrolidone） method, and freezing and thawing ...Microorganism DNA of rhizosphere soil from Pinus koraiensis and Pinus sylvestriformis were extracted by proteinase K based on SDS method, CTAB method, PVP （polyvinylpolypyrrolidone） method, and freezing and thawing method and the crude DNA from rhizosphere soil were purified by dialysis method, silver beads absorption method, and squeezing DNA gel method. The results of different extracting and purifying methods were compared and evaluated. Results indicated that the best method of extraction for microorganism DNA in rhizosphere soil was proteinse K based on SDS method with high salt concentration of 1.0% （w/v） NaCl, which could effectively eliminate humic acids and other impurities. The dialysis method was suitable to purify DNA from rhizosphere soil because of effectively removing brown matters and humic acids and the purified products were suited to PCR amplification. Squeezing DNA gel method was also a good purification method with the advantage of inexpensive in cost and efficient in use.展开更多
From observing cores of 18 wells,identifying 175 ordinary thin sections and 61 thin casting sections,energy spectrum analyses of 37 samples,homogenization temperature measurement of fluid inclusions of 11 samples,we d...From observing cores of 18 wells,identifying 175 ordinary thin sections and 61 thin casting sections,energy spectrum analyses of 37 samples,homogenization temperature measurement of fluid inclusions of 11 samples,we determine the types of diagenesis and pores of the Fuyu oil reservoir in the north Qijia region.We classified the pores and measured their plane porosity using CIA 2000,the software of rock image analysis,calculated the effect of different kinds of diagenesis on porosity,studied the controlling actions of diagenesis to pore evolution quantitatively,combined with burial history,thermal history and their diagenetic environments.Our results show that mechanical compaction and carbonate cementation are the major destructive diagenesed,developed during early diagenesis stages.The reduction in porosity by mechanical compaction and carbonate cementation are about 25% and 8%,while the destructive intensity of siliceous cementation and clay mineral cementation is relatively much smaller,i.e.,the reduction of porosity is about 2% and 0.2% Dissolution is constructive diagenesis,the increment of porosity is about 6%.There are four diagenesis evolution stages,during which the porosity reduced from 30%～38% to 2%～20%.Mechanical compaction and early cementation are the main diageneses in the early diagenesis stages,when porosity was reduced to 2%～10%.Dissolution is the main diagenesis of an A I substage of the middle diagenesis stage,when porosity increased 1%～8%.The dissolution of the A Ⅱ substage of the middle diagenesis stage affected by late cementation,raised porosity 1%～5%.The porosity varied slightly during the middle stage B.展开更多
Based on the data associated with cores,sidewall cores,casting thin sections,reservoir physical properties,conventional logging and imaging logging,the classification schemes of vertical reservoir units are proposed f...Based on the data associated with cores,sidewall cores,casting thin sections,reservoir physical properties,conventional logging and imaging logging,the classification schemes of vertical reservoir units are proposed for the two types of Archaeozoic buried hills(exposed and covered ones)in the Bozhong Sag,Bohai Bay Basin.The geological characteristics and storage spaces of these reservoir units are described,and their identification markers in conventional and imaging log curves are established.The Archaeozoic metamorphic buried hills can be vertically classified into two primary reservoir units:weathering crust and inner buried hill.The weathering crust contains four secondary units,i.e.,the clay zone,weathered glutenite zone,leached zone,disaggregation zone;and the interiors contain two secondary units,i.e.,interior fracture zone and tight zone.In particular,the inner fracture zone was further divided into cataclasite belts and dense-fracture belts.It is proposed that the favorable reservoirs of exposed Archaeozoic metamorphic buried hills are mainly developed in four parts including weathered glutenite zone,leached zone,disintegration zone superposed with the cataclasite belt and the cataclasite belt of inner fracture zone,and are controlled by both weathering and tectonic actions.Favorable reservoirs in covered Archaeozoic metamorphic buried hills are mainly developed in the weathering crust superposed with the cataclasite belts and the cataclasite belts of inner fracture zone,and are mainly controlled by tectonic actions.展开更多
Multiple-seam gas coproduction is a technology with potential to achieve economic targets.Physical experiments could replicate gas flow dynamics in two seams.In this study,numerical simulation was conducted based on p...Multiple-seam gas coproduction is a technology with potential to achieve economic targets.Physical experiments could replicate gas flow dynamics in two seams.In this study,numerical simulation was conducted based on physical experiments.Through calibration,the simulated results agreed with the experimental results.Three findings were obtained.First,the pressure distribution intrinsically depends on the depressurization effectiveness in each coal seam.The gas pressure difference and interval distance influence the pressure distribution by inhibiting depressurization in the top seams and bottom seams,respectively.Second,the production contribution shows a logarithmic relationship with the permeability ratio.The range of the production contribution difference grows from 11.24%to 99.99%when the permeability ratio increases 50 times.By comparison,reservoir pressure has a limited influence,with a maximum of 13.64%.Third,the interlayer interference of the top seams and bottom seams can be intensified by the reservoir pressure difference and the interval distance,respectively.The proposed model has been calibrated and verified and can be directly applied to engineering,serving as a reference for reservoir combination optimization.In summary,coal seams with a permeability ratio within 10,reservoir pressure difference within 1.50 MPa,and interval distances within 50 m are recommended to coproduce together.展开更多
The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofa...The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofacies of subaqueous eruptive pyroclastic rocks is discussed and the facies model is established by taking the tuff cone of Cretaceous Huoshiling Formation in the Chaganhua area of the Changling fault depression,Songliao Basin as the research object.The results indicate that the subaqueous eruptive pyroclastic rocks in the Songliao Basin can be divided into two facies and four subfacies.The two facies are the subaqueous explosive facies and the volcanic sedimentary facies that is formed during the eruption interval.The subaqueous explosive facies can be further divided into three subfacies:gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies.The volcanic sedimentary facies consists of pyroclastic sedimentary rocks containing terrigenous clast subfacies.A typical facies model of the tuff cone that is formed by subaqueous eruptions in the Songliao Basin was established.The tuff cone is generally composed of multiple subaqueous eruption depositional units and can be divided into two facies associations:near-source facies association and far-source facies association.The complete vertical succession of one depositional unit of the near-source facies association is composed of pyroclastic sedimentary rocks containing terrigenous clast subfacies,gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies from bottom to top.The depositional unit of the far-source facies association is dominated by the subaqueous fallout subfacies and contains several thin interlayered deposits of the water-laid density current subfacies.The gas-supported hot pyroclastic flow subfacies and the pyroclastic sedimentary rocks containing terrigenous clast subfacies are favorable subaqueous eruptive facies for reservoirs in continental lacustrine basins.展开更多
The Carboniferous volcanic reservoir in the Chepaizi Uplift became an exploration hot target in recent years for its substantial amount of oils discovered. However, most of the Carboniferous heavy oils were biodegrade...The Carboniferous volcanic reservoir in the Chepaizi Uplift became an exploration hot target in recent years for its substantial amount of oils discovered. However, most of the Carboniferous heavy oils were biodegraded to PM7 or higher with orders of magnitude variation in oil viscosities. Two oil groups (I and II) exactly corresponding to the western and eastern Chepaizi Uplift were distinguished according to their source diagnose. Furthermore, three oil families (II1, II2 and II3), with the biodegradation level of PM7, PM8–8+, PM9+, respectively, were classified based on molecular compositions and parameter-stripping method of strongly bioresistant parameters. Allowing for this extremely high biodegradation case, more biodegradation refractory compound class were added to establish a refined Manco scale to quantitatively evaluate the biodegradation extent. Refined Manco number (RMN2) positively correlated with the oil density, NSO contents, and absolute concentrations of diasteranes and gammacerane, negatively correlated with the absolute concentrations of diahopane, summed tricyclic terpanes and pentacyclic terpanes. This refined scale showed higher resolution than the PM one to differentiate the biodegradation extent of Carboniferous heavy oils from the Chepaizi Uplift, especially those with same PM values but different oil viscosities.展开更多
The research progress of isotopic fractionation in the process of shale gas/coalbed methane migration has been reviewed from three aspects: characteristics and influencing factors, mechanism and quantitative character...The research progress of isotopic fractionation in the process of shale gas/coalbed methane migration has been reviewed from three aspects: characteristics and influencing factors, mechanism and quantitative characterization model, and geological application. It is found that the isotopic fractionation during the complete production of shale gas/coalbed methane shows a four-stage characteristic of “stable-lighter-heavier-lighter again”, which is related to the complex gas migration modes in the pores of shale/coal. The gas migration mechanisms in shale/coal include seepage, diffusion, and adsorption/desorption. Among them, seepage driven by pressure difference does not induce isotopic fractionation, while diffusion and adsorption/desorption lead to significant isotope fractionation. The existing characterization models of isotopic fractionation include diffusion fractionation model, diffusion-adsorption/desorption coupled model, and multi-scale and multi-mechanism coupled model. Results of model calculations show that the isotopic fractionation during natural gas migration is mainly controlled by pore structure, adsorption capacity, and initial/boundary conditions of the reservoir rock. So far, the isotope fractionation model has been successfully used to evaluate critical parameters, such as gas-in-place content and ratio of adsorbed/free gas in shale/coal etc. Furthermore, it has shown promising application potential in production status identification and decline trend prediction of gas well. Future research should focus on:(1) the co-evolution of carbon and hydrogen isotopes of different components during natural gas migration,(2) the characterization of isotopic fractionation during the whole process of gas generation-expulsion-migration-accumulation-dispersion, and(3) quantitative characterization of isotopic fractionation during natural gas migration in complex pore-fracture systems and its application.展开更多
基金supported by the Guangxi Natural Science Foundation(2020GXNSFAA297266)Doctoral Research Foundation of Guilin University of Technology(GUTQDJJ2007059)Guangxi Hidden Metallic Mineral Exploration Key Laboratory。
文摘For regional ecological management,it is important to evaluate the quality of ecosystems and analyze the underlying causes of ecological changes.Using the Google Earth Engine(GEE)platform,the remote sensing ecological index(RSEI)was calculated for the Lijiang River Basin in Guangxi Zhuang Autonomous Region for 1991,2001,2011,and 2021.Spatial autocorrelation analysis was employed to investigate spatiotemporal variations in the ecological environmental quality of the Lijiang River Basin.Furthermore,geographic detectors were used to quantitatively analyze influencing factors and their interaction effects on ecological environmental quality.The results verified that:1)From 1991 to 2021,the ecological environmental quality of the Lijiang River Basin demonstrated significant improvement.The area with good and excellent ecological environmental quality in proportion increased by 19.69%(3406.57 km^(2)),while the area with fair and poor ecological environmental quality in proportion decreased by 10.76%(1860.36 km^(2)).2)Spatially,the ecological environmental quality of the Lijiang River Basin exhibited a pattern of low quality in the central region and high quality in the periphery.Specifically,poor ecological environmental quality characterized the Guilin urban area,Pingle County,and Lingchuan County.3)From 1991 to 2021,a significant positive spatial correlation was observed in ecological environmental quality of the Lijiang River Basin.Areas with high-high agglomeration were predominantly forests and grasslands,indicating good ecological environmental quality,whereas areas with low-low agglomeration were dominated by cultivated land and construction land,indicating poor ecological environmental quality.4)Annual average precipitation and temperature exerted the most significant influence on the ecological environmental quality of the basin,and their interactions with other factors had the great influence.This study aimed to enhance understanding of the evolution of the ecological environment in the Lijiang River Basin of Guangxi Zhuang Autonomous Region and provide scientific guidance for decision-making and management related to ecology in the region.
基金the financial support from the National Natural Science Foundation of China (No.42102127)the Postdoctoral Research Foundation of China (No.2024 M751860)。
文摘Cleat serves as the primary flow pathway for coalbed methane(CBM)and water.However,few studies consider the impact of local contact on two-phase flow within cleats.A visual generalized model of endogenous cleats was constructed based on microfluidics.A microscopic and mesoscopic observation technique was proposed to simultaneously capture gas-liquid interface morphology of pores and throat and the two-phase flow characteristics in entire cleat system.The local contact characteristics of cleats reduced absolute permeability,which resulted in a sharp increase in the starting pressure.The reduced gas flow capacity narrowed the co-infiltration area and decreased water saturation at the isotonic point in a hydrophilic environment.The increased local contact area of cleats weakened gas phase flow capacity and narrowed the co-infiltration area.Jumping events occurred in methane-water flow due to altered porosity caused by local contact in cleats.The distribution of residual phases changed the jumping direction on the micro-scale as well as the dominant channel on the mesoscale.Besides,jumping events caused additional energy dissipation,which was ignored in traditional two-phase flow models.This might contribute to the overestimation of relative permeability.The work provides new methods and insights for investigating unsaturated flow in complex porous media.
基金Supported by National Natural Science Foundation of China(41874190,41231066)
文摘A long-standing mystery in the study of Field-Aligned Currents(FACs) has been that: how the currents are generated and why they appear to be much stronger at high altitudes than in the ionosphere. Here we present two events of magnetotail FACs observed by the Magnetospheric Multiscale Spacecraft(MMS) on 1 st July and 14 th July 2016, to show how the Substorm Current Wedges(SCW) were formed. The results show that particles were transferred heading towards the Earth during the expansion phase of substorms.The azimuthal flow formed clockwise(counter-clockwise) vortex-like motion, and then generated downward(upward) FACs on the tailward/poleward side of the distorted field with opposite vorticity on their Earthward/equatorward side. We also analyzed the Region 1 FACs observed by the Earth Explorer Swarm spacecraft on 1 st July 2016 and found that they were associated with FACs observed by MMS, although differing by a factor of 10. This difference suggests that either there was the closure of the currents at altitudes above 500 km or the currents were not strictly parallel to B and closed at longitudes away from where they were generated.
基金funded by the Natural Science Foundation of Heilongjiang Province (LH 2022D013)supported by the Central Support Program for Young Talents in Local Universities in Heilongjiang Province (14011202101)Key Research and Development Plan Project of Heilongjiang Province (JD22A022)。
文摘The Pinghu slope belt in the Xihu sag of the East China Sea Shelf Basin(ECSSB) is a crucial hydrocarbon production area in eastern China. However, due to the complex geological conditions, publications have lacked comprehensive research on the spatial-temporal coupling relationships of primary factors that impact hydrocarbon accumulation in the Pinghu slope belt. Furthermore, the hydrocarbon distribution patterns and the controlling factors across different study areas within the same slope belt are not yet fully understood. This study extensively utilized three-dimensional seismic data, well logging data,geochemical analysis, fluorescence analysis, and oil testing and production data to address these issues.Following a “stratification and differentiation” approach, the study identified seven distinct hydrocarbon migration and accumulation units(HMAU) in the Pinghu slope area based on the structural morphology characteristics, hydrocarbon source-reservoir-cap rock patterns, hydrocarbon migration pathways, and hydrocarbon supply range. Detailed analysis was conducted to examine the hydrocarbon distribution patterns and controlling factors within each migration and accumulation unit across different structural units, including high, medium, and low structural components. All data sources support a “southern-northern sub-area division, eastern-western sub-belt division, and variations in hydrocarbon accumulation” pattern in the Pinghu slope belt. The degree of hydrocarbon accumulation is controlled by the factors of structural morphology, hydrocarbon generation potential of source rocks, the spatial position of source slopes, fault sealing capacity, and sand body distribution. Furthermore, different coupling patterns of faults and sand bodies play a pivotal role in governing hydrocarbon enrichment systems across various migration and accumulation units. These observations indicate that three hydrocarbon accumulation patterns have been established within the slope belt, including near-source to far-source gentle slope with multiple hydrocarbon kitchens in the XP1-XP4 zones, near-source to middle-source gentle slope with dual-hydrocarbon kitchens in the XP5 zone, and near-source steep slope with a single hydrocarbon kitchen in the XP6-XP7 zones. These findings contribute to enhancing the theoretical system of hydrocarbon accumulation in the slope belt.
基金founded by National Natural Science Foundation of China(grant Nos.:42072186 and 42090025)National Science and Technology Major Project,China(grant No.:2016ZX05046001)+3 种基金Science and Technology Research Project of Petro China Company Limited,China(grant No.:2021DJ1806)the fund support from China Scholarship Council(No.201806440002)the International Postdoctoral Exchange Fellowship Program,China(Talent-Introduction Program,No.270152)Lin Ma wishes to acknowledge the fund support from Natural Environment Research Council,United Kingdom(NE/R013527/1)。
文摘The mineralogical development and diagenetic sequence of lacustrine shales in the Chang 7 Member of the Yanchang Formation in the Ordos Basin are detailed studied.A model of their depositional system and a diagenetic diagram are proposed in this study.Through detailed petrographic,mineralogical,and elemental analyses,four distinct shale types are identified:argillaceous shale,siliceous shale,calcareous shale,and carbonate,clay,and silt-bearing shale.The main diagenetic process in argillaceous shale is the transformation of illite to smectite,negatively impacting shale porosity.Siliceous shale undergoes carbonate cementation and quartz dissolution,contributing to increased porosity,particularly in mesopores.Calcareous shale experiences diagenesis characterised by carbonate formation and dissolution,with a prevalence of siderite.In carbonate,clay,and silt-bearing shale,the dissolution of K-feldspar contributes to illitization of kaolinite.Argillaceous shale,characterised by more clay minerals and lower mesopore volume,is identified as a potential hydrocarbon seal.Siliceous shale,with the highest pore volume and abundant inter-mineral pores,emerges as a promising shale oil reservoir.These findings contribute to a comprehensive understanding of shale properties,aiding in the prediction of shale oil exploration potential in the studied area.
基金Supported by the China National Offshore Oil Corporation Limited Project(2021-KT-YXKY-03)。
文摘Based on the geological and geophysical data of Mesozoic oil-gas exploration in the sea area of Bohai Bay Basin and the discovered high-yield volcanic oil and gas wells since 2019,this paper methodically summarizes the formation conditions of large-and medium-sized Cretaceous volcanic oil and gas reservoirs in the Bohai Sea.Research shows that the Mesozoic large intermediate-felsic lava and intermediate-felsic composite volcanic edifices in the Bohai Sea are the material basis for the formation of large-scale volcanic reservoirs.The upper subfacies of effusive facies and cryptoexplosive breccia subfacies of volcanic conduit facies of volcanic vent-proximal facies belts are favorable for large-scale volcanic reservoir formation.Two types of efficient reservoirs,characterized by high porosity and medium to low permeability,as well as medium porosity and medium to low permeability,are the core of the formation of large-and medium-sized volcanic reservoirs.The reservoir with high porosity and medium to low permeability is formed by intermediate-felsic vesicular lava or the cryptoexplosive breccia superimposed by intensive dissolution.The reservoir with medium porosity and medium to low permeability is formed by intense tectonism superimposed by fluid dissolution.Weathering and tectonic transformation are main formation mechanisms for large and medium-sized volcanic reservoirs in the study area.The low-source“source-reservoir draping type”is the optimum source-reservoir configuration relationship for large-and medium-sized volcanic reservoirs.There exists favorable volcanic facies,efficient reservoirs and source-reservoir draping configuration relationship on the periphery of Bozhong Sag,and the large intermediate-felsic lava and intermediate-felsic composite volcanic edifices close to strike-slip faults and their branch faults are the main directions of future exploration.
基金This work was financially supported by the National Natural Science Foundation of China(41972123,41922015)the Natural Science Foundation of Shandong Province(ZR2020QD036).
文摘The occurrence characteristics of shale oil are of great significance to the movability of shale oil.In this study,the occurrence characteristics of oil in the shale matrix at Funing Formation shale in Subei Basin were quantitatively evaluated by organic geochemistry and microscopic pore structure characterization experiments.The Multiple Isothermal Stages Pyrolysis(MIS)experiment results show that the content of total oil,adsorbed oil,and free oil in the shales are 3.15-11.25 mg/g,1.41-4.95 mg/g,and 1.74-6.51 mg/g,respectively.among which the silicon-rich shale has the best oil-bearing.The relative content of free oil shows an increasing trend in pores with pore diameters greater than 3 nm.When the relative content of free oil reaches 100%,the pore size of silicon-rich shale is about 200 nm,while that of calcium-rich shale,clay-rich shale,and siliceous mixed shale is about 10 nm.The occurrence law of adsorbed oil is opposite to that of free oil,which indicates that shale oil will occur in the pores and fractures in a free state in a more extensive pore size range(>200 nm).This study also enables us to further understand the occurrence characteristics of shale oil under the interaction of occurrence state and occurrence space.
基金co-funded by the National Natural Science Foundation of China (Grant Nos. 42372160, 42072172)Shandong Province Natural Science Fund for Distinguished Young Scholars (Grant No. JQ201311)the Graduate Scientific and Technological Innovation Project financially supported by Shandong University of Science and Technology (Grant No. SDKDYC190313)。
文摘The Jurassic coal-measure source rocks in the Junggar Basin have drawn considerable attention in recent years. In our hydrocarbon thermal simulation experiments of these rocks, we found that the dark mudstone evaluated as good source rock, had a much lower hydrocarbon generation capacity than the coal and carbonaceous mudstone, evaluated as poor source rock. Based on this background, we performed Fourier transform infrared spectroscopy(FTIR) and combined the results of semi-open thermal simulation experiments to explore the association between the molecular structure and hydrocarbon production capacity, with the aim of obtaining a new understanding of hydrocarbon potential of Jurassic coal-measure source rocks from the perspective of molecular structure. The results indicate that coals exhibit lower condensation of aromatic structures and higher relative abundance of aliphatic structures with a higher degree of branched chaining than mudstones and carbonaceous mudstones. Apparent aromaticity(f_a), aromatic abundance parameter I, and degree of condensation(DOC) are negatively correlated with organic matter abundance. The aliphatic structural parameter H demonstrates a substantial positive correlation with organic matter abundance. Furthermore, aliphatic relative abundance factor A is associated with the type of organic matter;the better is the type of the organic matter, the larger is the A value. The combination of the molecular structures with the thermal simulation results shows that the aliphatic hydrogen enrichment of selected carbonaceous mudstone is similar to that of coal. However, the relative abundance of the aliphatic group of it is high, and the DOC of the aromatic structure is low, making the hydrocarbon generation base stronger and easier to crack. Thus, the hydrocarbon generation capacity of carbonaceous mudstone is slightly higher than that of coal. Mudstone has low H and I values, and the DOC is high, indicating that its hydrocarbon base is low, so it has low hydrocarbon generation capacity. Therefore, the molecular structure is closely associated with the hydrocarbon potential of coal-measure source rocks. When evaluating the qualities of coal-measure source rocks, the influence of molecular structure on these rocks should be considered.
基金financially supported by the National Natural Science Foundation of China(42302160,42302170,42302183,and 42072174)the Sanya City Science and Technology Innovation Project(2022KJCX51)the Support Plan for Outstanding Youth Innovation Team in Shandong Higher Education Institutions(2022KJ060)。
文摘Characterizing the microscopic occurrence and distribution of in-situ pore water and oil is crucial for resource estimation and development method selection of shale oil.In this paper,a series of nuclear magnetic resonance(NMR)experiments were conducted on shales from the Gulong Sag,Songliao Basin,China,at AR,WR-AR,WOR-AR,Dry,SO,and WR states.In-situ pore water and oil were reconstructed after WOR-AR.An improved T1-T2pattern for shale oil reservoirs comprising water and oil was proposed to classify and quantitatively detect pore fluids at different occurrence states.The total and free oil contents derived from NMR T1-T2spectra at AR states were found to correlate well with those from multistage Rock-Eval.Moreover,the NMR-calculated total and free oil are generally larger than those measured from multistage Rock-Eval,whereas adsorbed oil is the opposite,which implies that adsorbed,bound,and movable oils in shale pores can be accurately and quantitatively detected via NMR,without absorbed hydrocarbons in kerogen.As per the NMR T2and T1-T2spectra at WOR-AR state,the micro-distributions of in-situ pore water and oil were clearly demonstrated.Adsorbed,bound,and movable oils primarily occur in the micropores(<100 nm),mesopores(100-1000 nm),and macropores(>1000 nm),respectively,whereas capillary-bound water is primarily correlated with micropores.Thus,the microscopic occurrence and distribution of adsorbed oil are remarkably affected by pore water,followed by bound oil,and movable oil is hardly affected.This study would be helpful in further understanding the microscopic occurrence characteristics of pore fluids in-situ shale oil reservoirs.
基金provided by the National Natural Science Foundation of China (No. 41402086)the Colleges Scientific Research Projects of Shandong Province (No. J14LH06)+1 种基金the provincial excellent young talents in colleges and universities in Shandong Province natural science foundation of the mutual funds (No. ZR2015JL016)State key research and development plan (No. 2017YFC0601400)
文摘Using the large-scale thick 4# coal seam from the Mid-Jurassic in the southern Ordos Basin as an example, this paper studied the net primary productivity(NPP) level of the Mid-Jurassic peatland, and discussed its control factors. Geophysical logging signals were used for a spectrum analysis to obtain the Milankovitch cycle parameters in coal seam. These were then used to calculate the accumulation rate of the residual carbon in 4# coal seam. The carbon loss can be calculated according to the density and residual carbon content of 4# coal seam. Then, the total carbon accumulation rate of the peatland was further derived, and the NPP of peatland was determined. The results show that the NPP of MidJurassic peatland is higher than that of Holocene at the same latitude. Comprehensive analysis indicates that the temperature, carbon dioxide and oxygen levels in atmosphere are the main control factors of the NPP of Mid-Jurassic peatland.
基金supported by the National Key Research and Development Plan (2017YFC0601400)SDUST Research Fund (2018TDJH101)the National Natural Science Foundation of China (41402086, 272172)
文摘Coal and oil shale are two common sedimentary energy sources which are often symbiotically developed in M esozoic- Cenozoic continental fault basins. However, the mechanisms and characteristics of the symbiotic development are not yet clearly known. In this research study, the typical continental fault basins of eastern China were chosen as examples for the purpose of conducting an examination of the coal and oil shale symbiotic assemblage types, genetic environmental differences, and transformation mechanisms, as well as the development and occurrence characteristics o f different assemblage types. Through a large number of investigations, systematic experimental testing, and sequence stratigraphy studies, the following conclusions were obtained:(1) There were five types of coal and oil shale symbiotic assemblages observed in the continental fault basins,(2) The development of coal and oil shale deposits requires a warm and humid climate, stable structure, abundant organic matter supply, a certain water depth, and a lower terrestrial source debris supply. The observed differences were that the water depth conditions were diversified in the study area, as well as the sources, types, and content of the organic matter.(3) The rapid transformations of the coal and oil shale genetic environments were mainly controlled by the tectonic settings and climatic conditions, which were determined to control the changes in the water depths, salinity,redox conditions, and lake productivity of the genetic environments. Also, in the symbiotic assemblages, genetic environment changes had induced the development of oil shale deposits, which gradually evolved into coal genetic environments.(4) In the isochronous sequence stratigraphic framework of the coal and oil shale symbiotic assemblages, the lake expansion system tracts (EST) were determined to be the most beneficial to the growth o f all the types of assemblages and were characterized by more assemblage development phases and smaller bed thicknesses. From the early to the late stages of the EST, and from the lakesides to lake centers, the thicknesses of the coal seams in the symbiotic assemblages showed trends of thinning, while the thicknesses of the oil shale deposits exhibited increasing trends. The early stages of high stand system tracts were found to be beneficial to the development of the symbiotic assemblages of coal seams overlying the oil shale. This tract type generally presented large bed thicknesses and distribution ranges. The low stand system tract and the late high stand system tract were determined to be unconducive to the development of the symbiotic assemblages.
基金supported by the National Natural Science Foundation(Nos.41172099,41272130)
文摘Study of dolomite texture can contribute to understanding the process of dolomitization.This research reports textures and homogenization temperatures of dolomites from the Permian-Triassic strata in the Sichuan Basin and the Lower Paleozoic strata in the Tarim Basin,which provided insights into relationships between dolomite textures and their formation temperatures.Our results are summarized as follows：1） dolomites with well-preserved texture indicate low dolomitization temperature.However,in certain diagenetic environments,the hydrothermal dolomitization may completely or partially preserve the original texture of dolomites.2） The formation temperatures of non-planar dolomites are always higher than those of planar dolomites.3） The formation temperatures of dolomite cements are generally higher than those of replacive dolomites.4） Although the formation temperatures of saddle dolomite cements have a wide range,they show higher values than those of the planar subhedral to euhedral dolomite cements.Thus,saddle dolomites could generally be an indicator of high precipitation temperature.5） The fluid Mg/Ca ratio is another element controlling dolomite morphology.Micritic dolomites,which precipitate from hypersaline fluids with a high Mg/Ca ratio in a subaerial environment could also have features of non-planar anhedral crystal shape because of rapid nucleation and crystallization during dolomitization.
基金Supported by the National Basic Research Program of China(2011CB811404)the Natural Science Foundation of China(40774081)+1 种基金the Specialized Research Fund for State Key LaboratoriesCAS-NSSC-135 project
文摘High-energy electron precipitation in the high latitude regions enhances the ionization of the atmosphere,and subsequently increases the atmospheric conductivities and the vertical electric field of the atmosphere near the ground as well.The High-Energy Electron Flux(HEEF) data measured by the Fengyun-3 meteorological satellite are analyzed together with the data of nearsurface atmospheric vertical electric field measured at the Russian Vostok Station.Three HEEF enhancements are identified and it is shown that when the HEEF increases to a certain level,the local atmospheric vertical electric field near the ground can increase substantially than usual.The response time of the electric field to HEEF enhancement is about 3.7 to 4 days.
基金This project was supported by the Knowledge Innovation Project from Chinese Academy （KZCXI-SW-01） and the National Natural Science Foundation of China （30070158）.
文摘Microorganism DNA of rhizosphere soil from Pinus koraiensis and Pinus sylvestriformis were extracted by proteinase K based on SDS method, CTAB method, PVP （polyvinylpolypyrrolidone） method, and freezing and thawing method and the crude DNA from rhizosphere soil were purified by dialysis method, silver beads absorption method, and squeezing DNA gel method. The results of different extracting and purifying methods were compared and evaluated. Results indicated that the best method of extraction for microorganism DNA in rhizosphere soil was proteinse K based on SDS method with high salt concentration of 1.0% （w/v） NaCl, which could effectively eliminate humic acids and other impurities. The dialysis method was suitable to purify DNA from rhizosphere soil because of effectively removing brown matters and humic acids and the purified products were suited to PCR amplification. Squeezing DNA gel method was also a good purification method with the advantage of inexpensive in cost and efficient in use.
基金the National Basic Research Program of China (No.2009 CB219306)the Important National Science & Technology Specific Projects (No.2009GYXQ14)
文摘From observing cores of 18 wells,identifying 175 ordinary thin sections and 61 thin casting sections,energy spectrum analyses of 37 samples,homogenization temperature measurement of fluid inclusions of 11 samples,we determine the types of diagenesis and pores of the Fuyu oil reservoir in the north Qijia region.We classified the pores and measured their plane porosity using CIA 2000,the software of rock image analysis,calculated the effect of different kinds of diagenesis on porosity,studied the controlling actions of diagenesis to pore evolution quantitatively,combined with burial history,thermal history and their diagenetic environments.Our results show that mechanical compaction and carbonate cementation are the major destructive diagenesed,developed during early diagenesis stages.The reduction in porosity by mechanical compaction and carbonate cementation are about 25% and 8%,while the destructive intensity of siliceous cementation and clay mineral cementation is relatively much smaller,i.e.,the reduction of porosity is about 2% and 0.2% Dissolution is constructive diagenesis,the increment of porosity is about 6%.There are four diagenesis evolution stages,during which the porosity reduced from 30%～38% to 2%～20%.Mechanical compaction and early cementation are the main diageneses in the early diagenesis stages,when porosity was reduced to 2%～10%.Dissolution is the main diagenesis of an A I substage of the middle diagenesis stage,when porosity increased 1%～8%.The dissolution of the A Ⅱ substage of the middle diagenesis stage affected by late cementation,raised porosity 1%～5%.The porosity varied slightly during the middle stage B.
基金Supported by the National Natural Science Foundation of China(41790453,41972313).
文摘Based on the data associated with cores,sidewall cores,casting thin sections,reservoir physical properties,conventional logging and imaging logging,the classification schemes of vertical reservoir units are proposed for the two types of Archaeozoic buried hills(exposed and covered ones)in the Bozhong Sag,Bohai Bay Basin.The geological characteristics and storage spaces of these reservoir units are described,and their identification markers in conventional and imaging log curves are established.The Archaeozoic metamorphic buried hills can be vertically classified into two primary reservoir units:weathering crust and inner buried hill.The weathering crust contains four secondary units,i.e.,the clay zone,weathered glutenite zone,leached zone,disaggregation zone;and the interiors contain two secondary units,i.e.,interior fracture zone and tight zone.In particular,the inner fracture zone was further divided into cataclasite belts and dense-fracture belts.It is proposed that the favorable reservoirs of exposed Archaeozoic metamorphic buried hills are mainly developed in four parts including weathered glutenite zone,leached zone,disintegration zone superposed with the cataclasite belt and the cataclasite belt of inner fracture zone,and are controlled by both weathering and tectonic actions.Favorable reservoirs in covered Archaeozoic metamorphic buried hills are mainly developed in the weathering crust superposed with the cataclasite belts and the cataclasite belts of inner fracture zone,and are mainly controlled by tectonic actions.
基金This research was supported by National Science and Technology Major Project(No.2016ZX05044002-005)and National Natural Science Foundation of China(No.41772155)The first author gratefully acknowledges financial support from China Scholarship Council(No.CSC201906420044)and expresses thanks to Richard Smith and Eric Lysczek for grammar check.
文摘Multiple-seam gas coproduction is a technology with potential to achieve economic targets.Physical experiments could replicate gas flow dynamics in two seams.In this study,numerical simulation was conducted based on physical experiments.Through calibration,the simulated results agreed with the experimental results.Three findings were obtained.First,the pressure distribution intrinsically depends on the depressurization effectiveness in each coal seam.The gas pressure difference and interval distance influence the pressure distribution by inhibiting depressurization in the top seams and bottom seams,respectively.Second,the production contribution shows a logarithmic relationship with the permeability ratio.The range of the production contribution difference grows from 11.24%to 99.99%when the permeability ratio increases 50 times.By comparison,reservoir pressure has a limited influence,with a maximum of 13.64%.Third,the interlayer interference of the top seams and bottom seams can be intensified by the reservoir pressure difference and the interval distance,respectively.The proposed model has been calibrated and verified and can be directly applied to engineering,serving as a reference for reservoir combination optimization.In summary,coal seams with a permeability ratio within 10,reservoir pressure difference within 1.50 MPa,and interval distances within 50 m are recommended to coproduce together.
基金Supported by the National Natural Science Foundation of China (41790453,41972313)。
文摘The conventional lithofacies and facies model of subaerial and marine pyroclastic rocks cannot reflect the characteristics of subaqueous volcanic edifice in lacustrine basins.In order to solve this problem,the lithofacies of subaqueous eruptive pyroclastic rocks is discussed and the facies model is established by taking the tuff cone of Cretaceous Huoshiling Formation in the Chaganhua area of the Changling fault depression,Songliao Basin as the research object.The results indicate that the subaqueous eruptive pyroclastic rocks in the Songliao Basin can be divided into two facies and four subfacies.The two facies are the subaqueous explosive facies and the volcanic sedimentary facies that is formed during the eruption interval.The subaqueous explosive facies can be further divided into three subfacies:gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies.The volcanic sedimentary facies consists of pyroclastic sedimentary rocks containing terrigenous clast subfacies.A typical facies model of the tuff cone that is formed by subaqueous eruptions in the Songliao Basin was established.The tuff cone is generally composed of multiple subaqueous eruption depositional units and can be divided into two facies associations:near-source facies association and far-source facies association.The complete vertical succession of one depositional unit of the near-source facies association is composed of pyroclastic sedimentary rocks containing terrigenous clast subfacies,gas-supported hot pyroclastic flow subfacies,water-laid density current subfacies and subaqueous fallout subfacies from bottom to top.The depositional unit of the far-source facies association is dominated by the subaqueous fallout subfacies and contains several thin interlayered deposits of the water-laid density current subfacies.The gas-supported hot pyroclastic flow subfacies and the pyroclastic sedimentary rocks containing terrigenous clast subfacies are favorable subaqueous eruptive facies for reservoirs in continental lacustrine basins.
基金This work was funded by the National Natural Science Foundation of China(Grant No.42072172,41772120)the Shandong Province Natural Science Fund for Distinguished Young Scholars(Grant No.JQ201311)+1 种基金the SDUST Research Fund(Grant No.2015TDJH101)Associated editor Jie Hao and seven anonymous reviewers were deeply acknowledged for their critical comments and helpful suggestions,which greatly improved the early version of this manuscript.
文摘The Carboniferous volcanic reservoir in the Chepaizi Uplift became an exploration hot target in recent years for its substantial amount of oils discovered. However, most of the Carboniferous heavy oils were biodegraded to PM7 or higher with orders of magnitude variation in oil viscosities. Two oil groups (I and II) exactly corresponding to the western and eastern Chepaizi Uplift were distinguished according to their source diagnose. Furthermore, three oil families (II1, II2 and II3), with the biodegradation level of PM7, PM8–8+, PM9+, respectively, were classified based on molecular compositions and parameter-stripping method of strongly bioresistant parameters. Allowing for this extremely high biodegradation case, more biodegradation refractory compound class were added to establish a refined Manco scale to quantitatively evaluate the biodegradation extent. Refined Manco number (RMN2) positively correlated with the oil density, NSO contents, and absolute concentrations of diasteranes and gammacerane, negatively correlated with the absolute concentrations of diahopane, summed tricyclic terpanes and pentacyclic terpanes. This refined scale showed higher resolution than the PM one to differentiate the biodegradation extent of Carboniferous heavy oils from the Chepaizi Uplift, especially those with same PM values but different oil viscosities.
基金National Postdoctoral Innovative Talent Support Program(BX20220062)National Natural Science Foundation of China(41672130 and 41972123)SINOPEC Corp.(P17027-3)。
文摘The research progress of isotopic fractionation in the process of shale gas/coalbed methane migration has been reviewed from three aspects: characteristics and influencing factors, mechanism and quantitative characterization model, and geological application. It is found that the isotopic fractionation during the complete production of shale gas/coalbed methane shows a four-stage characteristic of “stable-lighter-heavier-lighter again”, which is related to the complex gas migration modes in the pores of shale/coal. The gas migration mechanisms in shale/coal include seepage, diffusion, and adsorption/desorption. Among them, seepage driven by pressure difference does not induce isotopic fractionation, while diffusion and adsorption/desorption lead to significant isotope fractionation. The existing characterization models of isotopic fractionation include diffusion fractionation model, diffusion-adsorption/desorption coupled model, and multi-scale and multi-mechanism coupled model. Results of model calculations show that the isotopic fractionation during natural gas migration is mainly controlled by pore structure, adsorption capacity, and initial/boundary conditions of the reservoir rock. So far, the isotope fractionation model has been successfully used to evaluate critical parameters, such as gas-in-place content and ratio of adsorbed/free gas in shale/coal etc. Furthermore, it has shown promising application potential in production status identification and decline trend prediction of gas well. Future research should focus on:(1) the co-evolution of carbon and hydrogen isotopes of different components during natural gas migration,(2) the characterization of isotopic fractionation during the whole process of gas generation-expulsion-migration-accumulation-dispersion, and(3) quantitative characterization of isotopic fractionation during natural gas migration in complex pore-fracture systems and its application.
