Under the context of global energy transition and carbon neutrality,controlling nitrogen oxide(NO_(x))emissions from biomass combustion is of great significance,and the development of high-efficiency low-temperature c...Under the context of global energy transition and carbon neutrality,controlling nitrogen oxide(NO_(x))emissions from biomass combustion is of great significance,and the development of high-efficiency low-temperature catalysts has become a current research focus.In this study,Nb was used to dope and modify the Mn_(7)-Cu_(3)/BCN catalyst to construct the Mn_(7)-Cu_(3)-Nb_(x)/BCN system.The doping amount was optimized through selective catalytic reduction(SCR)activity tests.The reaction mechanism was explored by combining in situ DRIFTS and density functional theory(DFT)simulations.Experimental findings revealed that the catalyst doped with 0.05%Nb achieved the optimal performance,sustaining a NO conversion efficiency of≥94%within the temperature window of 150−275℃while demonstrating improved resistance to alkali metal K poisoning.Mechanistic analyses showed that at low temperatures,the catalyst facilitated the SCR reaction via both the Eley-Rideal(E-R)and Langmuir-Hinshelwood(L-H)pathways,with the synergistic interaction between multiple active sites driving the efficient conversion of NH3 and NO.DFT calculations further confirmed that both pathways had the characteristics of low reaction energy barriers and significant exothermicity,ensuring the high activity and feasibility of the low-temperature reaction.The findings provided foundational theoretical support for the design of Nb-doped Mn-Cu-supported catalysts and the exploration of the underlying working mechanisms.展开更多
The advent of parametric design has resulted in a marked increase in the complexity of building.Unfortunately,traditional construction methods make it difficult to meet the needs.Therefore,construction robots have bec...The advent of parametric design has resulted in a marked increase in the complexity of building.Unfortunately,traditional construction methods make it difficult to meet the needs.Therefore,construction robots have become a pivotal production tool in this context.Since the arm span of a single robot usually does not exceed 3 meters,it is not competent for producing large-scale building components.Accordingly,the extension of the robot,s working range is often achieved by external axes.Nevertheless,the coupling control of external axes and robots and their kinematic solution have become key challenges.The primary technical difficulties include customized construction robots,automatic solutions for external axes,fixed axis joints,and specific motion mode control.This paper proposes solutions to these difficulties,introduces the relevant basic concepts and algorithms in detail,and encapsulates these robotics principles and algorithm processes into the Grasshopper plug-in commonly used by architects to form the FURobot software platform.This platform effectively solves the above problems,lowers the threshold for architects,and improves production efficiency.The effectiveness of the algorithm and software in this paper is verified through simulation experiments.展开更多
In response to the fact that the presence of manganese dithionate(MnS_(2)O_(6))leads to a series of adverse impacts,especially lower purity of manganese sulfate(MnSO_(4))and disruption of its recovery,advanced oxidati...In response to the fact that the presence of manganese dithionate(MnS_(2)O_(6))leads to a series of adverse impacts,especially lower purity of manganese sulfate(MnSO_(4))and disruption of its recovery,advanced oxidation methods such as ozonation system are used to manage MnS_(2)O_(6)in the leaching solution,replacing conventional methods.To ascertain the conversion rate and kinetics of MnS_(2)O_(6)during the ozonation process,we explored the factors influencing its removal rate,including ozone dosage,manganese dithionate concentration,sulfuric acid concentration,and reaction temperature.Batch experiments were conducted to determine the reaction rate constant of ozone(k)and activation energy(Ea)obtained from intermittent experimental data fitting,revealing a least-squares exponential conversion relationship between k and the MnS_(2)O_(6)removal amount,wherein an increase in the aforementioned factors led to an enhanced MnS_(2)O_(6)conversion rate,exceeding 99.3%.The formation mechanism of the ozone products proposed during the experiment was summarized and proposed as follows:1)Mn^(2+)was directly oxidized to MnO_(2),and 2)SO_(4)2−was obtained by the catalytic oxidation of S_(2)O_(6)^(2−)with HO•from O3 decomposition.According to the kinetics analysis,the pre-exponential factor and total activation energy of the ozonation kinetics equation were 1.0×10^(23) s^(−1) and 177.28 kJ/mol,respectively.Overall,the present study demonstrates that O_(3) as an oxidizing agent can effectively facilitate MnS_(2)O_(6)disproportionation while preventing the release of the secondary pollutant,SO_(2)gas.展开更多
Affected by the geological characteristics of coal bearing strata in western mining areas of China,the double soft composite roof has low strength and poor integrity,which is prone to induce disasters such as large de...Affected by the geological characteristics of coal bearing strata in western mining areas of China,the double soft composite roof has low strength and poor integrity,which is prone to induce disasters such as large deformation and roof collapse.Four-point bending tests were conducted on anchored double-layer rock beams with different pre tightening force and upper/lower rock strength ratios(Ⅰ/Ⅱ)based on the digital speckle correlation method(DSCM).The research results indicate that the instability process of anchored roof can be divided into stages of elastic deformation,crack propagation,alternating fracture,and failure collapse.The proportion of crack propagation and alternating fracture processes increased with the increase of pre-tightening force and Ⅰ/Ⅱ.The pre-tightening force can suppress the sliding of the upper/lower rock interface,and delay the initiation and propagation of cracks.As Ⅰ/Ⅱ increases,the failure mode changes from tensile failure steel strip to shear failure anchor rod.Steel strip can improve the continued bearing effect of anchored roof during crack propagation and alternating fracture processes.展开更多
In the field of soil stabilization, only calcium silicate hydrate(CSH) and ettringite(AFt) as hydration products have been reported to directly contribute to the strength enhancement of the soil. A chloride dredger fi...In the field of soil stabilization, only calcium silicate hydrate(CSH) and ettringite(AFt) as hydration products have been reported to directly contribute to the strength enhancement of the soil. A chloride dredger fill, an artificial chloride saline soil, and a non-saline soil were stabilized by Portland cement(PC) and PC with Ca(OH)_2(CH) with different contents. A series of unconfined compressive strength(UCS) tests of stabilized soil specimen after curing for 7 d and 28 d were carried out, and the hydration products and microstructure of the specimens were observed by X-ray diffractometry(XRD), scanning electronic microscopy(SEM), and energy-dispersive X-ray analysis(EDXA). The results showed that the strengths of PC+CH-stabilized chloride saline soils were much higher than those of PC-stabilized soils. A new hydration product of calcium aluminate chloride hydrate, also known as Friedel's salt, appeared in the PC+CH-stabilized chloride saline soils. The solid-phase volume of Friedel's salt expanded during the formation of the hydrate; this volume filled the pores in the stabilized soil. This pore-filling effect was the most important contribution to the significantly enhanced strength of the PC+CH-stabilized chloride saline soils. On the basis of this understanding, a new optimized stabilizer was designed according to the concept that the chloride in saline soil could be utilized as a component of the stabilizer. The strength of the chloride saline soils stabilized by the optimized stabilizer was even further increased compared with that of the PC+CH-stabilized soils.展开更多
Shear-sliding mode(mode Ⅱ)fracture of rocks is a vital failure form in deep underground engineering.To gain deep insight into the anisotropic shear fracture behaviors of a typical shale under high normal stress condi...Shear-sliding mode(mode Ⅱ)fracture of rocks is a vital failure form in deep underground engineering.To gain deep insight into the anisotropic shear fracture behaviors of a typical shale under high normal stress conditions,a series of direct shear tests were conducted on double-notched specimens in three typical bedding orientations(i.e.,the arrester,divider,short-transverse orientations)and under five normal stresses.The modeⅡfracture toughness(K_(Ⅱc))is found to exhibit a significant 3D anisotropy.The maximum K_(Ⅱc)is obtained in the divider orientation,followed by those in the arrester and short-transverse orientations.In contrast,the 3D anisotropy in the critical modeⅡenergy release rate(G_(Ⅱc))is not as significant as that in K_(Ⅱc),and G_(Ⅱc)in the arrester orientation is quite close to that in the divider orientation.The anisotropy in the prepeak input energy accumulated during shearing is found to be exactly consistent with that in G_(Ⅱc),which has not been noted before.Furthermore,the anisotropies in the modeⅡfracture resistances will,unexpectedly,not be weakened by the high normal stress.Owing to the layered structures,tensile cracks are involved during the modeⅡfracture process,resulting in the formation of rough fracture surfaces.展开更多
In order to investigate the size effect and other effects on the stress-strain relationship of confined concrete, 42 specimens with different sizes and section shapes were placed under axial compression loading. Effec...In order to investigate the size effect and other effects on the stress-strain relationship of confined concrete, 42 specimens with different sizes and section shapes were placed under axial compression loading. Effects of key parameters such as size of specimens, tie configuration, transverse reinforcement ratio, and concrete cover were studied. The results show that for specimens with the same configuration and the same volumetric ratio of the transverse reinforcement, along with the increasing specimen size, the peak stress, peak strain and deformation of the post-peak show a down trend, however, the volumetric ratio of the transverse reinforcement is lowered, the decreasing of the peak stress is accelerated, but the decreasing of the deformation is slow down. For specimens with the same volumetric ratio but different configurations of transverse reinforcement, though the transverse reinforcement configuration becomes more complicated, the peak stress of the large size specimen does not improve more than that of the small size. However, the deformation occurs before the stress declines to 85% of peak stress, and the improvement with the grid pattern tie configuration is much greater due to size effect.展开更多
The luminance in the road tunnel threshold zone attracts broad attention due to its enormous energy consumption and direct influence on tunnel transportation security.Current lighting design methods in threshold zones...The luminance in the road tunnel threshold zone attracts broad attention due to its enormous energy consumption and direct influence on tunnel transportation security.Current lighting design methods in threshold zones mostly adopt the reduction coefficient method.However,the determination of reduction coefficient k simply considers tunnel design speed and flow rate,while excluding outside tunnel luminance and threshold zone color temperature and luminance,which have a major impact on driver visual adaptation.Existing problems in the determination of k value are analyzed;a visual performance experiment is utilized;and the reaction time of drivers in changeable outside tunnel luminance and threshold zone color temperature and luminance conditions is obtained;thus,the equations concerning reduction coefficient variation law are derived.In the end,a comparative analysis is made of the k values of the reduction coefficient stipulated by various norms under different color temperature conditions.展开更多
In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined comp...In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).展开更多
In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indi...In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indicate that the evolutions of wave velocities became progressively anisotropic under uniaxial loading due to the direction-dependent development of micro-damage.A wave velocity model considering the inner anisotropic crack evolution is proposed to accurately describe the variations of wave velocities during uniaxial compression testing.Based on which,the effective elastic parameters are inferred by a transverse isotropic constitutive model,and the evolutions of the crack density are inversed using a self-consistent damage model.It is found that the propagation of axial cracks dominates the failure process of brittle rock under uniaxial loading and oblique shear cracks develop with the appearance of macrocrack.展开更多
To study rock damage characteristics under long-term freeze-thaw cycles and loads,rock freeze-thaw and creep damage factors were defined based on nuclear magnetic resonance porosity and volume strain,respectively.The ...To study rock damage characteristics under long-term freeze-thaw cycles and loads,rock freeze-thaw and creep damage factors were defined based on nuclear magnetic resonance porosity and volume strain,respectively.The damage factor is introduced into the basic rheological element,and the non-linear creep damage constitutive model and freeze-thaw rock equation are established to describe non-linear creep characteristics under a constant load.Simultaneously,the creep test of freeze-thaw rock under step loading is performed.Based on the test data,the applicability and accuracy of the creep damage freeze-thaw rock model are analyzed and verified.The results show that freeze-thaw cycles result in continuous rock pore structure damage and deterioration,and nuclear magnetic resonance porosity enhancement.The constant load induces increasing rock plastic deformation,volume,and creep aging damage.As the loading stress increases,the instantaneous rock elastic parameters increase,and the rheological elastic and viscosity parameters decrease.Furthermore,the damage degradation of freeze-thaw cycles weakens the rock viscoplasticity,resulting in a rapid decrease in the viscosity parameter with an increase in freeze-thaw cycles.Generally,the continuous damage of the rock is degraded,and the long-term strength decreases continuously.展开更多
Soils are actually unsaturated in nature. In the present study, a stability analysis of a geosynthetic-reinforced slope in unsaturated soils subjected to various steady flow conditions is conducted based on limit anal...Soils are actually unsaturated in nature. In the present study, a stability analysis of a geosynthetic-reinforced slope in unsaturated soils subjected to various steady flow conditions is conducted based on limit analysis. Work rate by apparent cohesion due to matric suction is calculated based on the effective stress-based equation. Analytical expression of the required cohesion/stability number of slope is derived from the energy balance equation. An optimization code is programmed to capture the optimized solution of the stability number. Comparison is made to verify the present work and a parametric analysis is conducted to investigate the effects of soil type, infilitration rate, reinforcement strength and soil suction on slope stability afterwards. A set of numerical solutions is presented at the end of the paper for preliminary design purposes.展开更多
The study aims to investigate the thermal comfort requirements in residential buildings and to establish an adaptive thermal comfort model in the cold zone of China.A year-long field study was conducted in residential...The study aims to investigate the thermal comfort requirements in residential buildings and to establish an adaptive thermal comfort model in the cold zone of China.A year-long field study was conducted in residential buildings in Xi’an,China.A total of 2069 valid questionnaires,along with indoor environmental parameters were obtained.The results indicated occupants’thermal comfort requirements varied with seasons.The neutral temperatures were 17.9,26.1(highest),25.2,and 17.4℃(lowest),and preferred temperatures were 23.2,25.6(highest),24.8,and 22.4℃(lowest),respectively for spring,summer,autumn,and winter.The neutral temperature and preferred temperature in autumn are close to the neutral temperature in summer,while the neutral temperature and preferred temperature in spring are close to that in winter.Besides,the 80%and 90%acceptable temperature ranges,adaptive thermal comfort models,and thermal comfort zones for each season were established.Human’s adaptability is related to his/her thermal experience of the current season and the previous season.Therefore,compared with the traditional year-round adaptive thermal comfort model,seasonal models can better reflect seasonal variations of human adaptation.This study provides fundamental knowledge of the thermal comfort demand for people in this region.展开更多
Experimental evidence has indicated that clay exhibits strain-softening response under undrained compression following anisotropic consolidation.The purpose of this work was to propose a modeling method under critical...Experimental evidence has indicated that clay exhibits strain-softening response under undrained compression following anisotropic consolidation.The purpose of this work was to propose a modeling method under critical state theory of soil mechanics.Based on experimental data on different types of clay,a simple double-surface model was developed considering explicitly the location of critical state by incorporating the density state into constitutive equations.The model was then used to simulate undrained triaxial compression tests performed on isotropically and anisotropically consolidated samples with different stress ratios.The predictions were compared with experimental results.All simulations demonstrate that the proposed approach is capable of describing the drained and undrained compression behaviors following isotropic and anisotropic consolidations.展开更多
Support vector regression （SVR） method is a novel type of learning machine algorithms, which is seldom applied to the development of urban atmospheric quality models under multiple socio-economic factors. This study...Support vector regression （SVR） method is a novel type of learning machine algorithms, which is seldom applied to the development of urban atmospheric quality models under multiple socio-economic factors. This study presents four SVR models by selecting linear, radial basis, spline, and polynomial functions as kernels, respectively for the prediction of urban dust fall levels. The inputs of the models are identified as industrial coal consumption, population density, traffic flow coefficient, and shopping density coefficient. The training and testing results show that the SVR model with radial basis kernel performs better than the other three both in the training and testing processes. In addition, a number of scenario analyses reveal that the most suitable parameters （insensitive loss function e, the parameter to reduce the influence of error C, and discrete level or average distribution of parameters σ） are 0.001, 0.5, and 2 000, respectively.展开更多
Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance fo...Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance for heating and cooling between passive houses in different climate zones.Therefore,this research develops a comparative analysis on the energy saving potential of passive houses with the conventional around China.A sensitivity analysis of thermal characteristics of building envelope(insulation of exterior walls and windows,and airtightness)on energy consumption is further carried out to improve the climate adaptability of passive house.Moreover,the variation of energy consumption under different heat gain intensity is also compared,to evaluate the effects of envelope thermal characteristics comprehensively.Results suggest that the decrease of exterior wall insulation leads to the greatest increase in energy consumption,especially in severe cold zone in China.However,the optimal insulation may change with the internal heat gain intensity,for instance,the decrease of insulation(from 0.4 to 1.0 W/(m^(2)·K))could reduce the energy consumption by 4.65 kW·h/(m^(2)·a)when the heat gain increases to 20 W/m^(2)for buildings in Hot Summer and Cold Winter zone in China.展开更多
Characteristic of cyclic loading due to passing wheels is associated with one-way loading without stress reversal,which includes a simultaneous cyclic variation of vertical normal stress and horizontal normal stress l...Characteristic of cyclic loading due to passing wheels is associated with one-way loading without stress reversal,which includes a simultaneous cyclic variation of vertical normal stress and horizontal normal stress lasting for a long period of time and generally takes place in partially-drained conditions.Therefore,it is of great practical relevance to study the deformation behaviour according to the characteristic of traffic loading.In this work,a series of one-way stress-controlled cyclic triaxial tests with a simultaneous variation of the vertical and horizontal stress components during cyclic loading were conducted to investigate the deformation behaviour of natural K_0-consolidated soft clay in partially-drained conditions.Test results demonstrate that not only the deviator part of the stress rules accumulation but also the volumetric part significantly contributes.While the deviator part of the stress amplitude is held constant,the increase amplitude of cyclic confining pressure will promote the development of both permanent volumetric strain and axial strain significantly.Furthermore,the effects of cyclic confining pressure on the deformation of natural K_0-consolidated soft clay was quantified.Finally,an empirical formula for permanent axial strain considering the effects of cyclic confining pressure was proposed which can be used for feasibility studies or for the preliminary design of foundations on K_0-consolidated soft clay subjected to traffic loading.展开更多
In the era of network live broadcasting for everyone,the development of live broadcasting platforms is also more intelligent and diversified.However,in the face of a large group of elderly users,the interface interact...In the era of network live broadcasting for everyone,the development of live broadcasting platforms is also more intelligent and diversified.However,in the face of a large group of elderly users,the interface interaction design mode used is still mainly based on the interaction mode for young groups,and is not designed for elderly users.Therefore,a design method for optimizing the interaction interface of live broadcasting platform for elderly users was proposed in this study.Firstly,the case study method and Delphi expert survey method were used to determine the design needs of elderly users and the design mode was analysed.Secondly,the orthogonal design principle was used to design a test sample of the interactive interface of live broadcasting platform applicable for the elderly users,and then a user evaluation system was established to calculate the weights of the design elements using hierarchical analysis,and then the predictive relationship between the design mode of the interactive interface of live broadcasting platform and the elderly users was established by Quantitative Theory I.Finally,Genetic Algorithm was applied to generate the optimized design scheme.The results showed that the design method based on the Genetic Algorithm and the combination of Quantitative Theory can scientifically and effectively optimize the design of the interactive interface of the live broadcasting platform for the elderly users,and improve the experience of the elderly users.展开更多
By conducting experimental measurements and numerical simulations of air distribution and microorganism pollutant distribution in the auditorium and game area in a gymnasium,pollutant dispersion control and indoor air...By conducting experimental measurements and numerical simulations of air distribution and microorganism pollutant distribution in the auditorium and game area in a gymnasium,pollutant dispersion control and indoor air quality improvement methods were put forward. The results show that the fungi and bacteria concentration levels are less than the magnitude of 103 CFU (colony-forming units) which meets the requirements of indoor air quality standard. The numerical simulation results quantitatively agree with the experimental data while some differences between theoretical data and experimental data exist in air distributions. People number in gymnasium plays an important role in affecting indoor air quality and the environmental parameters attained the standard.展开更多
The yield stress of waxy crude oil is a fundamental parameter in the calculation of pipelining technique and analysis of flow safety for the heated oil transported through pipeline.Daqing crude oil was studied and the...The yield stress of waxy crude oil is a fundamental parameter in the calculation of pipelining technique and analysis of flow safety for the heated oil transported through pipeline.Daqing crude oil was studied and the variation of yield stress with shear history was explored through simulation experiment of pipelining.It is found that the effect of throughput variation or shear rate on yield stress is not obvious.With the decrease of final dynamic cooling temperature,the yield stress of waxy crude oil decreases,but there exists a little increase at the beginning.The prediction model of yield stress for waxy crude oil under the condition of shutdown is developed and it can be used to predict the yield stress of Daqing crude oil at certain heating temperature,final dynamic cooling temperature and measurement temperature.For the 139 groups of yield stress data of Daqing crude oil from the simulation experiment of pipelining,the result of prediction with this model shows that the average relative deviation between the yield stress measured and predicted is 30.27%,and the coefficient of correlation is 0.962 3.展开更多
基金Supported by National Key Research and Development Program of China(2020YFD1100302)。
文摘Under the context of global energy transition and carbon neutrality,controlling nitrogen oxide(NO_(x))emissions from biomass combustion is of great significance,and the development of high-efficiency low-temperature catalysts has become a current research focus.In this study,Nb was used to dope and modify the Mn_(7)-Cu_(3)/BCN catalyst to construct the Mn_(7)-Cu_(3)-Nb_(x)/BCN system.The doping amount was optimized through selective catalytic reduction(SCR)activity tests.The reaction mechanism was explored by combining in situ DRIFTS and density functional theory(DFT)simulations.Experimental findings revealed that the catalyst doped with 0.05%Nb achieved the optimal performance,sustaining a NO conversion efficiency of≥94%within the temperature window of 150−275℃while demonstrating improved resistance to alkali metal K poisoning.Mechanistic analyses showed that at low temperatures,the catalyst facilitated the SCR reaction via both the Eley-Rideal(E-R)and Langmuir-Hinshelwood(L-H)pathways,with the synergistic interaction between multiple active sites driving the efficient conversion of NH3 and NO.DFT calculations further confirmed that both pathways had the characteristics of low reaction energy barriers and significant exothermicity,ensuring the high activity and feasibility of the low-temperature reaction.The findings provided foundational theoretical support for the design of Nb-doped Mn-Cu-supported catalysts and the exploration of the underlying working mechanisms.
基金National Key R&D Program of China(Nos.2023YFC3806900,2022YFE0141400)。
文摘The advent of parametric design has resulted in a marked increase in the complexity of building.Unfortunately,traditional construction methods make it difficult to meet the needs.Therefore,construction robots have become a pivotal production tool in this context.Since the arm span of a single robot usually does not exceed 3 meters,it is not competent for producing large-scale building components.Accordingly,the extension of the robot,s working range is often achieved by external axes.Nevertheless,the coupling control of external axes and robots and their kinematic solution have become key challenges.The primary technical difficulties include customized construction robots,automatic solutions for external axes,fixed axis joints,and specific motion mode control.This paper proposes solutions to these difficulties,introduces the relevant basic concepts and algorithms in detail,and encapsulates these robotics principles and algorithm processes into the Grasshopper plug-in commonly used by architects to form the FURobot software platform.This platform effectively solves the above problems,lowers the threshold for architects,and improves production efficiency.The effectiveness of the algorithm and software in this paper is verified through simulation experiments.
基金Project(2022M710619)supported by the Postdoctoral Science Foundation of ChinaProjects(2020YFH0213,2020YFG0039)supported by the Sichuan Science and Technology Program,China+1 种基金Projects(XJ2024001501,KCXTD2023-4)supported by the Basic Scientific Foundation and Innovation Team Funds of China West Normal UniversityProject(CSPC202403)supported by the Open Project Program of Chemical Synthesis and Pollution Control Key Laboratory of Sichuan Province,China。
文摘In response to the fact that the presence of manganese dithionate(MnS_(2)O_(6))leads to a series of adverse impacts,especially lower purity of manganese sulfate(MnSO_(4))and disruption of its recovery,advanced oxidation methods such as ozonation system are used to manage MnS_(2)O_(6)in the leaching solution,replacing conventional methods.To ascertain the conversion rate and kinetics of MnS_(2)O_(6)during the ozonation process,we explored the factors influencing its removal rate,including ozone dosage,manganese dithionate concentration,sulfuric acid concentration,and reaction temperature.Batch experiments were conducted to determine the reaction rate constant of ozone(k)and activation energy(Ea)obtained from intermittent experimental data fitting,revealing a least-squares exponential conversion relationship between k and the MnS_(2)O_(6)removal amount,wherein an increase in the aforementioned factors led to an enhanced MnS_(2)O_(6)conversion rate,exceeding 99.3%.The formation mechanism of the ozone products proposed during the experiment was summarized and proposed as follows:1)Mn^(2+)was directly oxidized to MnO_(2),and 2)SO_(4)2−was obtained by the catalytic oxidation of S_(2)O_(6)^(2−)with HO•from O3 decomposition.According to the kinetics analysis,the pre-exponential factor and total activation energy of the ozonation kinetics equation were 1.0×10^(23) s^(−1) and 177.28 kJ/mol,respectively.Overall,the present study demonstrates that O_(3) as an oxidizing agent can effectively facilitate MnS_(2)O_(6)disproportionation while preventing the release of the secondary pollutant,SO_(2)gas.
基金Project(SDAST2024QT060)supported by the Young Talent of Lifting Engineering for Science and Technology in Shandong,ChinaProjects(52304136,52304149,52204093)supported by the National Natural Science Foundation of China+1 种基金Project(ZR2022ME165)supported by the Shandong Provincial Natural Science Foundation,ChinaProject(2023YD02)supported by the Key Project of Research and Development in Liaocheng,China。
文摘Affected by the geological characteristics of coal bearing strata in western mining areas of China,the double soft composite roof has low strength and poor integrity,which is prone to induce disasters such as large deformation and roof collapse.Four-point bending tests were conducted on anchored double-layer rock beams with different pre tightening force and upper/lower rock strength ratios(Ⅰ/Ⅱ)based on the digital speckle correlation method(DSCM).The research results indicate that the instability process of anchored roof can be divided into stages of elastic deformation,crack propagation,alternating fracture,and failure collapse.The proportion of crack propagation and alternating fracture processes increased with the increase of pre-tightening force and Ⅰ/Ⅱ.The pre-tightening force can suppress the sliding of the upper/lower rock interface,and delay the initiation and propagation of cracks.As Ⅰ/Ⅱ increases,the failure mode changes from tensile failure steel strip to shear failure anchor rod.Steel strip can improve the continued bearing effect of anchored roof during crack propagation and alternating fracture processes.
基金Project(51008007)supported by the National Natural Science Foundation of ChinaProject(2013318J01100)supported by the Science and Technology Project of Ministry of Communications,China
文摘In the field of soil stabilization, only calcium silicate hydrate(CSH) and ettringite(AFt) as hydration products have been reported to directly contribute to the strength enhancement of the soil. A chloride dredger fill, an artificial chloride saline soil, and a non-saline soil were stabilized by Portland cement(PC) and PC with Ca(OH)_2(CH) with different contents. A series of unconfined compressive strength(UCS) tests of stabilized soil specimen after curing for 7 d and 28 d were carried out, and the hydration products and microstructure of the specimens were observed by X-ray diffractometry(XRD), scanning electronic microscopy(SEM), and energy-dispersive X-ray analysis(EDXA). The results showed that the strengths of PC+CH-stabilized chloride saline soils were much higher than those of PC-stabilized soils. A new hydration product of calcium aluminate chloride hydrate, also known as Friedel's salt, appeared in the PC+CH-stabilized chloride saline soils. The solid-phase volume of Friedel's salt expanded during the formation of the hydrate; this volume filled the pores in the stabilized soil. This pore-filling effect was the most important contribution to the significantly enhanced strength of the PC+CH-stabilized chloride saline soils. On the basis of this understanding, a new optimized stabilizer was designed according to the concept that the chloride in saline soil could be utilized as a component of the stabilizer. The strength of the chloride saline soils stabilized by the optimized stabilizer was even further increased compared with that of the PC+CH-stabilized soils.
基金Project(12172240)supported by the National Natural Science Foundation of ChinaProject(2021YFH0030)supported by the Science&Technology Department of Sichuan Province,China。
文摘Shear-sliding mode(mode Ⅱ)fracture of rocks is a vital failure form in deep underground engineering.To gain deep insight into the anisotropic shear fracture behaviors of a typical shale under high normal stress conditions,a series of direct shear tests were conducted on double-notched specimens in three typical bedding orientations(i.e.,the arrester,divider,short-transverse orientations)and under five normal stresses.The modeⅡfracture toughness(K_(Ⅱc))is found to exhibit a significant 3D anisotropy.The maximum K_(Ⅱc)is obtained in the divider orientation,followed by those in the arrester and short-transverse orientations.In contrast,the 3D anisotropy in the critical modeⅡenergy release rate(G_(Ⅱc))is not as significant as that in K_(Ⅱc),and G_(Ⅱc)in the arrester orientation is quite close to that in the divider orientation.The anisotropy in the prepeak input energy accumulated during shearing is found to be exactly consistent with that in G_(Ⅱc),which has not been noted before.Furthermore,the anisotropies in the modeⅡfracture resistances will,unexpectedly,not be weakened by the high normal stress.Owing to the layered structures,tensile cracks are involved during the modeⅡfracture process,resulting in the formation of rough fracture surfaces.
基金Project(50838001) supported by the National Natural Science Foundation of China
文摘In order to investigate the size effect and other effects on the stress-strain relationship of confined concrete, 42 specimens with different sizes and section shapes were placed under axial compression loading. Effects of key parameters such as size of specimens, tie configuration, transverse reinforcement ratio, and concrete cover were studied. The results show that for specimens with the same configuration and the same volumetric ratio of the transverse reinforcement, along with the increasing specimen size, the peak stress, peak strain and deformation of the post-peak show a down trend, however, the volumetric ratio of the transverse reinforcement is lowered, the decreasing of the peak stress is accelerated, but the decreasing of the deformation is slow down. For specimens with the same volumetric ratio but different configurations of transverse reinforcement, though the transverse reinforcement configuration becomes more complicated, the peak stress of the large size specimen does not improve more than that of the small size. However, the deformation occurs before the stress declines to 85% of peak stress, and the improvement with the grid pattern tie configuration is much greater due to size effect.
基金Project(51278507)supported by the National Natural Science Foundation of ChinaProject(cstc2017jcyjAX0346)supported by Chongqing Association for Science and Technology,China
文摘The luminance in the road tunnel threshold zone attracts broad attention due to its enormous energy consumption and direct influence on tunnel transportation security.Current lighting design methods in threshold zones mostly adopt the reduction coefficient method.However,the determination of reduction coefficient k simply considers tunnel design speed and flow rate,while excluding outside tunnel luminance and threshold zone color temperature and luminance,which have a major impact on driver visual adaptation.Existing problems in the determination of k value are analyzed;a visual performance experiment is utilized;and the reaction time of drivers in changeable outside tunnel luminance and threshold zone color temperature and luminance conditions is obtained;thus,the equations concerning reduction coefficient variation law are derived.In the end,a comparative analysis is made of the k values of the reduction coefficient stipulated by various norms under different color temperature conditions.
基金Projects(51208333,51078253)supported by the National Natural Science Foundation of China
文摘In order to simulate and study the mechanism of cement stabilized soils polluted by different contents of magnesium sulfate(MS), a series of tests were conducted on the cemented soil samples, including unconfined compression strength(UCS) tests of blocks, X-ray diffraction(XRD) phase analysis of powder samples, microstructure by scanning electronic microscopy(SEM),element composition by energy dispersive spectrometry(EDS), and pore distribution analysis by Image Processed Plus 6.0(IPP 6.0)software. The UCS test results show that UCS of cemented soils reaches the peak value when the MS content is 4.5 g/kg. While, the UCS for Sample MS4 having the MS content of 18.0 g/kg is the lowest among all tested samples. Based on the EDS analysis results,Sample MS4 has the greater contents for the three elements, oxygen(O), magnesium(Mg) and sulfur(S), than Sample MS1. From the XRD phase analysis, C-A-S-H(3Ca O·Al2O3·3Ca SO4·32H2O and 3Ca O·Al2O3·Ca SO4·18H2O), M-A-H(Mg O·Al2O3·H2O), M-S-H(Mg O·Si O2·H2O), Mg(OH)2 and Ca SO4 phase diffraction peaks are obviously intense due to the chemical action associated with the MS. The pore distribution analysis shows that the hydrated products change the distribution of cemented soil pores and the pores with average diameter(AD) of 2-50 μm play a key role in terms of the whole structure of cemented soil. The microscopic structure of the cemented soil with MS exhibits the intertwined and embedded characteristics between the cement and granular soils from the SEM images of cemented soils. The microstructure analysis shows that the magnesium sulfate acts as the additive, which is beneficial to the soil strength when the MS content is low(i.e., Sample MS2). However, higher MS amount involving a chemical action makes samples crystallize and expand, which is adverse to the UCS of cemented soils(i.e., Sample MS4).
基金Projects(41502283,41772309)supported by the National Natural Science Foundation of ChinaProject(2017YFC1501302)supported by the National Key Research and Development Program of ChinaProject(2017ACA102)supported by the Major Program of Technological Innovation of Hubei Province,China。
文摘In this study,the micro-failure process and failure mechanism of a typical brittle rock under uniaxial compression are investigated via continuous real-time measurement of wave velocities.The experimental results indicate that the evolutions of wave velocities became progressively anisotropic under uniaxial loading due to the direction-dependent development of micro-damage.A wave velocity model considering the inner anisotropic crack evolution is proposed to accurately describe the variations of wave velocities during uniaxial compression testing.Based on which,the effective elastic parameters are inferred by a transverse isotropic constitutive model,and the evolutions of the crack density are inversed using a self-consistent damage model.It is found that the propagation of axial cracks dominates the failure process of brittle rock under uniaxial loading and oblique shear cracks develop with the appearance of macrocrack.
基金Projects(41502327,51474252,51774323)supported by the National Natural Science Foundation of ChinaProject(2020JJ4712)supported by the Natural Science Foundation of Hunan Province,China+1 种基金Project(CX20190221)supported by the Hunan Provincial Innovation Foundation for Postgraduate,ChinaProject(ZJRMG-2018-Z03)supported by the Key Laboratory of Rock Mechanics and Geohazards of Zhejiang Province,China。
文摘To study rock damage characteristics under long-term freeze-thaw cycles and loads,rock freeze-thaw and creep damage factors were defined based on nuclear magnetic resonance porosity and volume strain,respectively.The damage factor is introduced into the basic rheological element,and the non-linear creep damage constitutive model and freeze-thaw rock equation are established to describe non-linear creep characteristics under a constant load.Simultaneously,the creep test of freeze-thaw rock under step loading is performed.Based on the test data,the applicability and accuracy of the creep damage freeze-thaw rock model are analyzed and verified.The results show that freeze-thaw cycles result in continuous rock pore structure damage and deterioration,and nuclear magnetic resonance porosity enhancement.The constant load induces increasing rock plastic deformation,volume,and creep aging damage.As the loading stress increases,the instantaneous rock elastic parameters increase,and the rheological elastic and viscosity parameters decrease.Furthermore,the damage degradation of freeze-thaw cycles weakens the rock viscoplasticity,resulting in a rapid decrease in the viscosity parameter with an increase in freeze-thaw cycles.Generally,the continuous damage of the rock is degraded,and the long-term strength decreases continuously.
基金Project(2019M650011)supported by China Postdoctoral Science FoundationProject(51421005)supported by the Science Fund for Creative Research Groups of the National Natural Science Foundation of ChinaProject(2015CB057902)supported by the National Basic Research Program of China
文摘Soils are actually unsaturated in nature. In the present study, a stability analysis of a geosynthetic-reinforced slope in unsaturated soils subjected to various steady flow conditions is conducted based on limit analysis. Work rate by apparent cohesion due to matric suction is calculated based on the effective stress-based equation. Analytical expression of the required cohesion/stability number of slope is derived from the energy balance equation. An optimization code is programmed to capture the optimized solution of the stability number. Comparison is made to verify the present work and a parametric analysis is conducted to investigate the effects of soil type, infilitration rate, reinforcement strength and soil suction on slope stability afterwards. A set of numerical solutions is presented at the end of the paper for preliminary design purposes.
基金Project(51325803)supported by the National Science Foundation for Distinguished Young Scholars of ChinaProject(2020M673489)supported by China Postdoctoral Science FoundationProject(2020-K-196)supported by the Science and Technology Project of Ministry of Housing and Urban-Rural Development,China。
文摘The study aims to investigate the thermal comfort requirements in residential buildings and to establish an adaptive thermal comfort model in the cold zone of China.A year-long field study was conducted in residential buildings in Xi’an,China.A total of 2069 valid questionnaires,along with indoor environmental parameters were obtained.The results indicated occupants’thermal comfort requirements varied with seasons.The neutral temperatures were 17.9,26.1(highest),25.2,and 17.4℃(lowest),and preferred temperatures were 23.2,25.6(highest),24.8,and 22.4℃(lowest),respectively for spring,summer,autumn,and winter.The neutral temperature and preferred temperature in autumn are close to the neutral temperature in summer,while the neutral temperature and preferred temperature in spring are close to that in winter.Besides,the 80%and 90%acceptable temperature ranges,adaptive thermal comfort models,and thermal comfort zones for each season were established.Human’s adaptability is related to his/her thermal experience of the current season and the previous season.Therefore,compared with the traditional year-round adaptive thermal comfort model,seasonal models can better reflect seasonal variations of human adaptation.This study provides fundamental knowledge of the thermal comfort demand for people in this region.
基金Project(SKLGP2011K013)supported by the State Key Laboratory of Geohazard Prevention and Geoenvironment Protection,ChinaProject(20110073120012)supported by the Research Fund for the Doctoral Program of Higher Education of China+1 种基金Project(11PJ1405700)supported by the the Shanghai Pujiang Talent Plan,ChinaProject(41002091)supported by the National Natural Science Foundation of China
文摘Experimental evidence has indicated that clay exhibits strain-softening response under undrained compression following anisotropic consolidation.The purpose of this work was to propose a modeling method under critical state theory of soil mechanics.Based on experimental data on different types of clay,a simple double-surface model was developed considering explicitly the location of critical state by incorporating the density state into constitutive equations.The model was then used to simulate undrained triaxial compression tests performed on isotropically and anisotropically consolidated samples with different stress ratios.The predictions were compared with experimental results.All simulations demonstrate that the proposed approach is capable of describing the drained and undrained compression behaviors following isotropic and anisotropic consolidations.
基金Projects(2007JT3018, 2008JT1013, 2009FJ4056) supported by the Key Project in Hunan Science and Technology Program, ChinaProject(20090161120014) supported by the New Teachers Sustentation Fund in Doctoral Program, Ministry of Education, China
文摘Support vector regression （SVR） method is a novel type of learning machine algorithms, which is seldom applied to the development of urban atmospheric quality models under multiple socio-economic factors. This study presents four SVR models by selecting linear, radial basis, spline, and polynomial functions as kernels, respectively for the prediction of urban dust fall levels. The inputs of the models are identified as industrial coal consumption, population density, traffic flow coefficient, and shopping density coefficient. The training and testing results show that the SVR model with radial basis kernel performs better than the other three both in the training and testing processes. In addition, a number of scenario analyses reveal that the most suitable parameters （insensitive loss function e, the parameter to reduce the influence of error C, and discrete level or average distribution of parameters σ） are 0.001, 0.5, and 2 000, respectively.
基金Project(51825802)supported by the National Science Foundation for Distinguished Young Scholars of ChinaProject(2018YFE0106100)supported by the National Key R&D Program of China。
文摘Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance for heating and cooling between passive houses in different climate zones.Therefore,this research develops a comparative analysis on the energy saving potential of passive houses with the conventional around China.A sensitivity analysis of thermal characteristics of building envelope(insulation of exterior walls and windows,and airtightness)on energy consumption is further carried out to improve the climate adaptability of passive house.Moreover,the variation of energy consumption under different heat gain intensity is also compared,to evaluate the effects of envelope thermal characteristics comprehensively.Results suggest that the decrease of exterior wall insulation leads to the greatest increase in energy consumption,especially in severe cold zone in China.However,the optimal insulation may change with the internal heat gain intensity,for instance,the decrease of insulation(from 0.4 to 1.0 W/(m^(2)·K))could reduce the energy consumption by 4.65 kW·h/(m^(2)·a)when the heat gain increases to 20 W/m^(2)for buildings in Hot Summer and Cold Winter zone in China.
基金Projects(51238009,51578426,51308420)supported by the National Natural Science Foundation of China
文摘Characteristic of cyclic loading due to passing wheels is associated with one-way loading without stress reversal,which includes a simultaneous cyclic variation of vertical normal stress and horizontal normal stress lasting for a long period of time and generally takes place in partially-drained conditions.Therefore,it is of great practical relevance to study the deformation behaviour according to the characteristic of traffic loading.In this work,a series of one-way stress-controlled cyclic triaxial tests with a simultaneous variation of the vertical and horizontal stress components during cyclic loading were conducted to investigate the deformation behaviour of natural K_0-consolidated soft clay in partially-drained conditions.Test results demonstrate that not only the deviator part of the stress rules accumulation but also the volumetric part significantly contributes.While the deviator part of the stress amplitude is held constant,the increase amplitude of cyclic confining pressure will promote the development of both permanent volumetric strain and axial strain significantly.Furthermore,the effects of cyclic confining pressure on the deformation of natural K_0-consolidated soft clay was quantified.Finally,an empirical formula for permanent axial strain considering the effects of cyclic confining pressure was proposed which can be used for feasibility studies or for the preliminary design of foundations on K_0-consolidated soft clay subjected to traffic loading.
文摘In the era of network live broadcasting for everyone,the development of live broadcasting platforms is also more intelligent and diversified.However,in the face of a large group of elderly users,the interface interaction design mode used is still mainly based on the interaction mode for young groups,and is not designed for elderly users.Therefore,a design method for optimizing the interaction interface of live broadcasting platform for elderly users was proposed in this study.Firstly,the case study method and Delphi expert survey method were used to determine the design needs of elderly users and the design mode was analysed.Secondly,the orthogonal design principle was used to design a test sample of the interactive interface of live broadcasting platform applicable for the elderly users,and then a user evaluation system was established to calculate the weights of the design elements using hierarchical analysis,and then the predictive relationship between the design mode of the interactive interface of live broadcasting platform and the elderly users was established by Quantitative Theory I.Finally,Genetic Algorithm was applied to generate the optimized design scheme.The results showed that the design method based on the Genetic Algorithm and the combination of Quantitative Theory can scientifically and effectively optimize the design of the interactive interface of the live broadcasting platform for the elderly users,and improve the experience of the elderly users.
基金Project(2006BAJ02A10) supported by the National Key Technologies R & D Program of China
文摘By conducting experimental measurements and numerical simulations of air distribution and microorganism pollutant distribution in the auditorium and game area in a gymnasium,pollutant dispersion control and indoor air quality improvement methods were put forward. The results show that the fungi and bacteria concentration levels are less than the magnitude of 103 CFU (colony-forming units) which meets the requirements of indoor air quality standard. The numerical simulation results quantitatively agree with the experimental data while some differences between theoretical data and experimental data exist in air distributions. People number in gymnasium plays an important role in affecting indoor air quality and the environmental parameters attained the standard.
基金Project(07E1007) supported by the Youth Innovation Foundation for Petroleum Science and Technology of China National Petroleum CorportationProject(2006AA09Z357) supported by the National High Technology Research and Development of China
文摘The yield stress of waxy crude oil is a fundamental parameter in the calculation of pipelining technique and analysis of flow safety for the heated oil transported through pipeline.Daqing crude oil was studied and the variation of yield stress with shear history was explored through simulation experiment of pipelining.It is found that the effect of throughput variation or shear rate on yield stress is not obvious.With the decrease of final dynamic cooling temperature,the yield stress of waxy crude oil decreases,but there exists a little increase at the beginning.The prediction model of yield stress for waxy crude oil under the condition of shutdown is developed and it can be used to predict the yield stress of Daqing crude oil at certain heating temperature,final dynamic cooling temperature and measurement temperature.For the 139 groups of yield stress data of Daqing crude oil from the simulation experiment of pipelining,the result of prediction with this model shows that the average relative deviation between the yield stress measured and predicted is 30.27%,and the coefficient of correlation is 0.962 3.
