Despite the promising potential of transition metal oxides(TMOs)as capacitive deionization(CDI)electrodes,the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity,...Despite the promising potential of transition metal oxides(TMOs)as capacitive deionization(CDI)electrodes,the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity,posing a major obstacle.Herein,we prepared the kinetically favorable Zn_(x)Ni_(1−x)O electrode in situ growth on carbon felt(Zn_(x)Ni_(1−x)O@CF)through constraining the rate of OH^(−)generation in the hydrothermal method.Zn_(x)Ni_(1−x)O@CF exhibited a high-density hierarchical nanosheet structure with three-dimensional open pores,benefitting the ion transport/electron transfer.And tuning the moderate amount of redox-inert Zn-doping can enhance surface electroactive sites,actual activity of redox-active Ni species,and lower adsorption energy,promoting the adsorption kinetic and thermodynamic of the Zn_(0.2)Ni_(0.8)O@CF.Benefitting from the kinetic-thermodynamic facilitation mechanism,Zn_(0.2)Ni_(0.8)O@CF achieved ultrahigh desalination capacity(128.9 mgNaCl g^(-1)),ultra-low energy consumption(0.164 kW h kgNaCl^(-1)),high salt removal rate(1.21 mgNaCl g^(-1) min^(-1)),and good cyclability.The thermodynamic facilitation and Na^(+)intercalation mechanism of Zn_(0.2)Ni_(0.8)O@CF are identified by the density functional theory calculations and electrochemical quartz crystal microbalance with dissipation monitoring,respectively.This research provides new insights into controlling electrochemically favorable morphology and demonstrates that Zn-doping,which is redox-inert,is essential for enhancing the electrochemical performance of CDI electrodes.展开更多
Ammonia(NH_(3))is an irreplaceable chemical that has been widely demanded to keep the sustainable development of modern society.However,its industrial production consumes a huge amount of energy and releases extraordi...Ammonia(NH_(3))is an irreplaceable chemical that has been widely demanded to keep the sustainable development of modern society.However,its industrial production consumes a huge amount of energy and releases extraordinary greenhouse gases(GHGs),leading to various environmental issues.Achieving the green production of ammonia is a great challenge,which has been extensively pursued in the last decade.In this review,the most promising strategy,electrochemical nitrate reduction reaction(e-NO_(3)RR),is comprehensively investigated to give a complete understanding of its development and mechanism and provide guidance for future directions.However,owing to the complex reactions and limited selectivity,a comprehensive understanding of the mechanisms is crucial to further development and commercialization.Moreover,NO_(3)^(-)RR is a promising strategy for simultaneous water treatment and NH_(3)production.A detailed overview of the recent progress in NO_(3)^(-)RR for NH_(3)production with nontransition and transition metal based electrocatalysts is summarized.In addition,critical advanced techniques,future challenges,and prospects are discussed to guide future research on transition metal-based catalysts for commercial NH_(3)synthesis by NO_(3)^(-)reduction.展开更多
Membrane desalination is an economical and energy-efficient method to meet the current worldwide water scarcity.However,state-of-the-art reverse osmosis membranes are gradually being replaced by novel membrane materia...Membrane desalination is an economical and energy-efficient method to meet the current worldwide water scarcity.However,state-of-the-art reverse osmosis membranes are gradually being replaced by novel membrane materials as a result of ongoing technological advancements.These novel materials possess intrinsic pore structures or can be assembled to form lamellar membrane channels for selective transport of water or solutes(e.g.,NaCl).Still,in real applications,the results fall below the theoretical predictions,and a few properties,including large-scale fabrication,mechanical strength,and chemical stability,also have an impact on the overall effectiveness of those materials.In view of this,we develop a new evaluation framework in the form of radar charts with five dimensions(i.e.,water permeance,water/NaCl selectivity,membrane cost,scale of development,and stability)to assess the advantages,disadvantages,and potential of state-of-the-art and newly developed desalination membranes.In this framework,the reported thin film nanocomposite membranes and membranes developed from novel materials were compared with the state-of-the-art thin film composite membranes.This review will demonstrate the current advancements in novel membrane materials and bridge the gap between different desalination membranes.In this review,we also point out the prospects and challenges of next-generation membranes for desalination applications.We believe that this comprehensive framework may be used as a future reference for designing next-generation desalination membranes and will encourage further research and development in the field of membrane technology,leading to new insights and advancements.展开更多
Energy and resources including coal, oil, and gas are in demand all over the world. Because these resources near the earth's surface have been exploited for many years, the extraction depth has increased.As mining...Energy and resources including coal, oil, and gas are in demand all over the world. Because these resources near the earth's surface have been exploited for many years, the extraction depth has increased.As mining shafts in the coal extraction process become deeper, especially in western China, an artificial freezing method is used and is concentrated in the fractured rock mass. The frost-heaving pressure(FHP)is directly related to the degree of damage of the fractured rock mass. This paper is focused on FHP during the freezing process, with emphasis on the frost-heaving phenomenon in engineering materials. A review of the frost phenomenon in the geotechnical engineering literature indicates that:(1) During the soil freezing process, the ice content that is influenced by unfrozen water and the freezing rate are the determining factors of FHP;(2) During the freezing process of rock and other porous media, the resulting cracks should be considered because the FHP may damage the crack structure;(3) The FHP in a joint rock mass is analyzed by the joint deformation in field and experimental tests and can be simulated by the equivalent expansion method including water migration and joint deformation.展开更多
Applying the standard Galerkin finite element method for solving flow problems in porous media encounters some difficulties such as numerical oscillation at the shock front and discontinuity of the velocity field on e...Applying the standard Galerkin finite element method for solving flow problems in porous media encounters some difficulties such as numerical oscillation at the shock front and discontinuity of the velocity field on element faces.Discontinuity of velocity field leads this method not to conserve mass locally.Moreover,the accuracy and stability of a solution is highly affected by a non-conservative method.In this paper,a three dimensional control volume finite element method is developed for twophase fluid flow simulation which overcomes the deficiency of the standard finite element method,and attains high-orders of accuracy at a reasonable computational cost.Moreover,this method is capable of handling heterogeneity in a very rational way.A fully implicit scheme is applied to temporal discretization of the governing equations to achieve an unconditionally stable solution.The accuracy and efficiency of the method are verified by simulating some waterflooding experiments.Some representative examples are presented to illustrate the capability of the method to simulate two-phase fluid flow in heterogeneous porous media.展开更多
Complex flow around floating structures is a highly nonlinear problem,and it is a typical feature in ship and ocean engineering.Traditional experimental methods and potential flow theory have limitations in predicting...Complex flow around floating structures is a highly nonlinear problem,and it is a typical feature in ship and ocean engineering.Traditional experimental methods and potential flow theory have limitations in predicting complex viscous flows.With the improvement of high-performance computing and the development of numerical techniques,computational fluid dynamics(CFD)has become increasingly powerful in predicting the complex viscous flow around floating structures.This paper reviews the recent progress in CFD techniques for numerical solutions of typical complex viscous flows in ship and ocean engineering.Applications to free-surface flows,breaking bow waves of high-speed ship,ship hull-propeller-rudder interaction,vortexinduced vibration of risers,vortex-induced motions of deep-draft platforms,and floating offshore wind turbines are discussed.Typical techniques,including volume of fluid for sharp interface,dynamic overset grid,detached eddy simulation,and fluid-structure coupling,are reviewed along with their applications.Some novel techniques,such as high-efficiency Cartesian grid method and GPU acceleration technique,are discussed in the last part as the future perspective for further enhancement of accuracy and efficiency for CFD simulations of complex flow in ship and ocean engineering.展开更多
With the significant development of computer hardware,many advanced numerical techniques have been proposed to investigate complex hydrodynamic problems.This article aims to provide a detailed review of moving particl...With the significant development of computer hardware,many advanced numerical techniques have been proposed to investigate complex hydrodynamic problems.This article aims to provide a detailed review of moving particle semi-implicit(MPS)techniques and their application in ocean and coastal engineering.The achievements of the MPS method in stability and accuracy,boundary conditions,and acceleration techniques are discussed.The applications of the MPS method,which are classified into two main categories,namely,multiphase flows and fluid-structure interactions,are introduced.Finally,the prospects and conclusions are highlighted.The MPS method has the potential to solve practical problems.展开更多
Development of high-efficiency and low-cost electrocatalyst for oxygen evolution reaction(OER) is very important for use at alkaline water electrolysis.Metal-organic frameworks(MOF) provide a rich platform for designi...Development of high-efficiency and low-cost electrocatalyst for oxygen evolution reaction(OER) is very important for use at alkaline water electrolysis.Metal-organic frameworks(MOF) provide a rich platform for designing multi-functional materials due to their controllable composition and ultra-high surface area.Herein,we report our findings in the development of amorphous nickel-cobalt bimetal-organic framework nanosheets with crystalline motifs via a simple "ligands hybridization engineering" strategy.These complexes' ligands contain inorganic ligands(H_2 O and NO_3) and organic ones,hexamethylenetetramine(HMT).Further,we investigated a series of mixed-metal with multi-ligands materials as OER catalysts to explore their possible advantages and features.It is found that the Ni doping is an effective approach for optimizing the electronic configuration,changing lattice ordering degree,and thus enhancing activities of HMT-based electrocatalysts.Also,the crystalline-amorphous boundaries of various HMTbased electrocatalyst can be easily controlled by simply changing amounts of Ni-precursor added.As a result,the optimized ultrathin(Co,0.3 Ni)-HMT nanosheets can reach a current density of 10 mA cm^(-2)at low overpotential of 330 mV with a small Tafel slope of 66 mV dec^(-1).Our findings show that the electronic structure changes induced by Ni doping,2 D nanosheet structure,and MOF frameworks with multiligands compositions play critical roles in the enhancement of the kinetically sluggish electrocatalytic OER.The present study emphasizes the importance of ligands and active metals via hybridization for exploring novel efficient electrocatalysts.展开更多
On 2019-03-04,the largest induced earthquake(ML4.18)occurred in the East Shale Basin,Alberta,and the underlying physical mechanisms have not been fully understood.This paper proposes a synthetical geoengineering metho...On 2019-03-04,the largest induced earthquake(ML4.18)occurred in the East Shale Basin,Alberta,and the underlying physical mechanisms have not been fully understood.This paper proposes a synthetical geoengineering methodology to comprehensively characterize this earthquake caused by hydraulic fracturing.Based on 3D structural,petrophysical,and geomechanical models,an unconventional fracture model is constructed by considering the stress shadow between adjacent hydraulic fractures and the interactions between hydraulic and natural fractures.Coupled poroelastic simulations are conducted to reveal the triggering mechanisms of induced seismicity.It is found that four vertical basement-rooted faults were identified via focal mechanisms analysis.The brittleness index(BI)along two horizontal wells has a high magnitude(BI>0.5),indicating the potential susceptibility of rock brittleness.Due to the presence of overpressure,pre-existing faults in the Duvernay Formation are highly susceptible to fault reactivation.The occurrence of the earthquake clusters has been attributed to the fracturing fluid injection during the west 38^(th)-39^(th) stage and east 38^(th) stage completions.Rock brittleness,formation overpressure,and large fracturing job size account for the nucleation of earthquake clusters,and unconventional natural-hydraulic fracture networks provide fluid flow pathways to cause fault reactivation.This workflow can be used to mitigate potential seismic risks in unconventional reservoirs in other fields.展开更多
A new model is proposed to improve the efficiency of structural modeling. In this model, the bridge structural components are expressed with component description, parametric description and geometric description in a...A new model is proposed to improve the efficiency of structural modeling. In this model, the bridge structural components are expressed with component description, parametric description and geometric description in a software system. This model provides both convenience and flexibility for users in structural modeling process. The object-oriented method is applied in the model implementation. A bridge analysis preprocessor is developed on the basis of this model. It provides an effective way for bridge modeling.展开更多
This paper presents a comprehensive review of historical theory development and current construction practice of pavement engineering in China. Mechanical models, design guides, construction techniques, evaluation met...This paper presents a comprehensive review of historical theory development and current construction practice of pavement engineering in China. Mechanical models, design guides, construction techniques, evaluation methods and maintenance standards are elaborated for Portland cement concrete （PCC） pavements methodology among pavements of rural highways, urban roads and asphalt concrete （AC） pavements. Differences in design and airport fields are discussed based on service requirements. Lessons and experiences based on the past 20 years＇ construction practice and pavement performance are summarized. Current research areas in pavement engineering associated with unconventional geological and/or landscaping in China＇s highway construction and national strategic plan for pavement engineering are also covered.展开更多
Application of pressured grouting method (PGM) in pile engineering can tackle problems encountered during construction of bored piles. Bearing capacity of piles can be increased through compaction of subsoils around p...Application of pressured grouting method (PGM) in pile engineering can tackle problems encountered during construction of bored piles. Bearing capacity of piles can be increased through compaction of subsoils around piles. This paper reports research efforts of this technique by the pile research team in Southwest Jiaotong University in last decade with respect to the construction process, test findings, and primary research conclusions. The social-economical benefits of this method and application market in pile engineering are also analyzed.展开更多
According to the variable toe-to-heel well spacing, combined with the dislocation theory, discrete lattice method, and finite-element-method(FEM) based fluid-solid coupling, an integrated geological-engineering method...According to the variable toe-to-heel well spacing, combined with the dislocation theory, discrete lattice method, and finite-element-method(FEM) based fluid-solid coupling, an integrated geological-engineering method of volume fracturing for fan-shaped well pattern is proposed considering the geomechanical modeling, induced stress calculation, hydraulic fracturing simulation, and post-frac productivity evaluation. Besides, we propose the differential fracturing design for the conventional productivity-area and the potential production area for fan-shaped horizontal wells. After the fracturing of the conventional production area for H1 fan-shaped well platform, the research shows that the maximum reduction of the horizontal principal stress difference in the potential productivity-area is 0.2 MPa, which cannot cause the stress reversal, but this reduction is still conducive to the lateral propagation of hydraulic fractures. According to the optimized fracturing design, in zone-Ⅰ of the potential production area, only Well 2 is fractured, with a cluster spacing of 30 m and an injection rate of 12 m^(3)/min per stage;in zone-Ⅱ, Well 2 is fractured before Well 3, with a cluster spacing of 30 m and an injection rate of 12 m^(3)/min per stage. The swept area of the pore pressure drop in the potential production area is small, showing that the reservoir is not well developed. The hydraulic fracturing in the toe area can be improved by, for example, properly densifying the fractures and adjusting the fracture distribution, in order to enhance the swept volume and increase the reservoir utilization.展开更多
The compaction quality of subgrade filler strongly affects subgrade settlement.The main objective of this research is to analyze the macro-and micro-mechanical compaction characteristics of subgrade filler based on th...The compaction quality of subgrade filler strongly affects subgrade settlement.The main objective of this research is to analyze the macro-and micro-mechanical compaction characteristics of subgrade filler based on the real shape of coarse particles.First,an improved Viola-Jones algorithm is employed to establish a digitalized 2D particle database for coarse particle shape evaluation and discrete modeling purposes of subgrade filler.Shape indexes of 2D subgrade filler are then computed and statistically analyzed.Finally,numerical simulations are performed to quantitatively investigate the effects of the aspect ratio(AR)and interparticle friction coefficient(μ)on the macro-and micro-mechanical compaction characteristics of subgrade filler based on the discrete element method(DEM).The results show that with the increasing AR,the coarse particles are narrower,leading to the increasing movement of fine particles during compaction,which indicates that it is difficult for slender coarse particles to inhibit the migration of fine particles.Moreover,the average displacement of particles is strongly influenced by the AR,indicating that their occlusion under power relies on particle shapes.The dis-placement and velocity of fine particles are much greater than those of the coarse particles,which shows that compaction is primarily a migration of fine particles.Under the cyclic load,the interparticle friction coefficientμhas little effect on the internal structure of the sample;under the quasi-static loads,however,the increase inμwill lead to a significant increase in the porosity of the sample.This study could not only provide a novel approach to investigate the compaction mechanism but also establish a new theoretical basis for the evaluation of intelligent subgrade compaction.展开更多
The supercritical CO_(2) Brayton cycle is considered a promising energy conversion system for Generation IV reactors for its simple layout,compact structure,and high cycle efficiency.Mathematical models of four Brayto...The supercritical CO_(2) Brayton cycle is considered a promising energy conversion system for Generation IV reactors for its simple layout,compact structure,and high cycle efficiency.Mathematical models of four Brayton cycle layouts are developed in this study for different reactors to reduce the cost and increase the thermohydraulic performance of nuclear power generation to promote the commercialization of nuclear energy.Parametric analysis,multi-objective optimizations,and four decision-making methods are applied to obtain each Brayton scheme’s optimal thermohydraulic and economic indexes.Results show that for the same design thermal power scale of reactors,the higher the core’s exit temperature,the better the Brayton cycle’s thermo-economic performance.Among the four-cycle layouts,the recompression cycle(RC)has the best overall performance,followed by the simple recuperation cycle(SR)and the intercooling cycle(IC),and the worst is the reheating cycle(RH).However,RH has the lowest total cost of investment(C_(tot))of$1619.85 million,and IC has the lowest levelized cost of energy(LCOE)of 0.012$/(kWh).The nuclear Brayton cycle system’s overall performance has been improved due to optimization.The performance of the molten salt reactor combined with the intercooling cycle(MSR-IC)scheme has the greatest improvement,with the net output power(W_(net)),thermal efficiencyη_(t),and exergy efficiency(η_(e))improved by 8.58%,8.58%,and 11.21%,respectively.The performance of the lead-cooled fast reactor combined with the simple recuperation cycle scheme was optimized to increase C_(tot) by 27.78%.In comparison,the internal rate of return(IRR)increased by only 7.8%,which is not friendly to investors with limited funds.For the nuclear Brayton cycle,the molten salt reactor combined with the recompression cycle scheme should receive priority,and the gas-cooled fast reactor combined with the reheating cycle scheme should be considered carefully.展开更多
Knowledge of the mechanical behavior of planetary rocks is indispensable for space explorations.The scarcity of pristine samples and the irregular shapes of planetary meteorites make it difficult to obtain representat...Knowledge of the mechanical behavior of planetary rocks is indispensable for space explorations.The scarcity of pristine samples and the irregular shapes of planetary meteorites make it difficult to obtain representative samples for conventional macroscale rock mechanics experiments(macro-RMEs).This critical review discusses recent advances in microscale RMEs(micro-RMEs)techniques and the upscaling methods for extracting mechanical parameters.Methods of mineralogical and microstructural analyses,along with non-destructive mechanical techniques,have provided new opportunities for studying planetary rocks with unprecedented precision and capabilities.First,we summarize several mainstream methods for obtaining the mineralogy and microstructure of planetary rocks.Then,nondestructive micromechanical testing methods,nanoindentation and atomic force microscopy(AFM),are detailed reviewed,illustrating the principles,advantages,influencing factors,and available testing results from literature.Subsequently,several feasible upscaling methods that bridge the micro-measurements of meteorite pieces to the strength of the intact body are introduced.Finally,the potential applications of planetary rock mechanics research to guiding the design and execution of space missions are environed,ranging from sample return missions and planetary defense to extraterrestrial construction.These discussions are expected to broaden the understanding of the microscale mechanical properties of planetary rocks and their significant role in deep space exploration.展开更多
Stability analysis of underground constructions requires a model study of rock masses’ long-term performance. Creep tests under different stress conditions was conducted on intact granite and granite samples fracture...Stability analysis of underground constructions requires a model study of rock masses’ long-term performance. Creep tests under different stress conditions was conducted on intact granite and granite samples fractured at 30° and 45° angles. The experimental results indicate that the steady creep strain rates of intact and fractured rock present an exponential increase trend with the increase of stress level. A nonlinear creep model is developed based on the experimental results, in which the initial damage caused by fracture together with the damage caused by constant load have been taken into consideration. The fitting analysis results indicated that the model proposed is more accurate at identifying the full creep regions in fractured granite, especially the accelerated stage of creep deformation. The least-square fit error of the proposed creep model is significantly lower than that of Nishihara model by almost an order of magnitude. An analysis of the effects of elastic modulus, viscosity coefficient, and damage factors on fractured rock strain rate and creep strain is conducted. If no consideration is given to the effects of the damage, the proposed nonlinear creep model can degenerate into to the classical Nishihara model.展开更多
Establishing a base on the Moon is one of the new goals of human lunar exploration in recent years.Sintered lunar regolith is one of the most potential building materials for lunar bases.The physical,mechanical and th...Establishing a base on the Moon is one of the new goals of human lunar exploration in recent years.Sintered lunar regolith is one of the most potential building materials for lunar bases.The physical,mechanical and thermal properties of sintered lunar regolith are vital performance indices for the structural design of a lunar base and analysis of many critical mechanical and thermal issues.In this study,the HUST-1 lunar regolith simulant(HLRS)was sintered at 1030,1040,1050,1060,1070,and 1080℃.The effect of sintering temperature on the compressive strength was investigated,and the exact value of the optimum vacuum sintering temperature was determined between 1040 and 1060℃.Then,the microstructure and material composition of vacuum sintered HLRS at different temperatures were characterized.It was found that the sintering temperature has no significant effect on the mineral composition in the temperature range of 1030-1080℃.Besides,the heat capacity,thermal conductivity,and coefficient of thermal expansion(CTE)of vacuum sintered HLRS at different temperatures were investigated.Specific heat capacity of sintered samples increases with the increase of test temperature within the temperature range from-75 to 145℃.Besides,the thermal conductivity of the sintered sample is proportional to density.Finally,the two temperatures of 1040 and 1050℃were selected for a more detailed study of mechanical properties.The results showed that compressive strength of sintered sample is much higher than tensile strength.This study reveals the effects of sintering temperature on the physical,mechanical and thermal properties of vacuum sintered HLRS,and these material parameters will provide support for the construction of future lunar bases.展开更多
The ballistic resistance and failure pattern of a bi-layer alumina 99.5%-aluminium alloy 1100-H12 target against steel 4340 ogival nosed projectile has been explored in the present experimental cum numerical study.In ...The ballistic resistance and failure pattern of a bi-layer alumina 99.5%-aluminium alloy 1100-H12 target against steel 4340 ogival nosed projectile has been explored in the present experimental cum numerical study.In the experimental investigation,damage induced in the ceramic layer has been quantified in terms of number of cracks developed and failure zone dimensions.The resultant damage in the backing layer has been studied with variation in the bulge and perforation hole in the backing layer with the varying incidence velocity.The discussion of the experimental results has been further followed by three dimensional finite element computations using ABAQUS/Explicit finite code to investigate the behaviour of different types of bi-layer targets under multi-hit projectile impact.The JH-2 constitutive model has been used to reproduce the behaviour of alumina 99.5%and JC constitutive model has been used for steel 4340 and aluminium alloy 1100-H12.The total energy dissipation has been noted to be of lesser magnitude in case of sub-sequential impact in comparison to simultaneous impact of two projectiles.The distance between the impact points of two projectiles also effected the ballistic resistance of bi-layer target.The ballistic resistance of single tile ceramic front layer and four tile ceramic of equivalent area found to be dependent upon the boundary conditions provided to the target.展开更多
基金supported by The National Natural Science Foundation of China(22276137,52170087)the Fundamental Research Funds for the Central Universities(XJEDU2023Z009).
文摘Despite the promising potential of transition metal oxides(TMOs)as capacitive deionization(CDI)electrodes,the actual capacity of TMOs electrodes for sodium storage is significantly lower than the theoretical capacity,posing a major obstacle.Herein,we prepared the kinetically favorable Zn_(x)Ni_(1−x)O electrode in situ growth on carbon felt(Zn_(x)Ni_(1−x)O@CF)through constraining the rate of OH^(−)generation in the hydrothermal method.Zn_(x)Ni_(1−x)O@CF exhibited a high-density hierarchical nanosheet structure with three-dimensional open pores,benefitting the ion transport/electron transfer.And tuning the moderate amount of redox-inert Zn-doping can enhance surface electroactive sites,actual activity of redox-active Ni species,and lower adsorption energy,promoting the adsorption kinetic and thermodynamic of the Zn_(0.2)Ni_(0.8)O@CF.Benefitting from the kinetic-thermodynamic facilitation mechanism,Zn_(0.2)Ni_(0.8)O@CF achieved ultrahigh desalination capacity(128.9 mgNaCl g^(-1)),ultra-low energy consumption(0.164 kW h kgNaCl^(-1)),high salt removal rate(1.21 mgNaCl g^(-1) min^(-1)),and good cyclability.The thermodynamic facilitation and Na^(+)intercalation mechanism of Zn_(0.2)Ni_(0.8)O@CF are identified by the density functional theory calculations and electrochemical quartz crystal microbalance with dissipation monitoring,respectively.This research provides new insights into controlling electrochemically favorable morphology and demonstrates that Zn-doping,which is redox-inert,is essential for enhancing the electrochemical performance of CDI electrodes.
基金supported by the National Natural Science Foundation of China(Grant Nos.22050410268,22176131)Shenzhen Basic Research General Project(JCYJ20210324095205015,JCYJ20220818095601002)。
文摘Ammonia(NH_(3))is an irreplaceable chemical that has been widely demanded to keep the sustainable development of modern society.However,its industrial production consumes a huge amount of energy and releases extraordinary greenhouse gases(GHGs),leading to various environmental issues.Achieving the green production of ammonia is a great challenge,which has been extensively pursued in the last decade.In this review,the most promising strategy,electrochemical nitrate reduction reaction(e-NO_(3)RR),is comprehensively investigated to give a complete understanding of its development and mechanism and provide guidance for future directions.However,owing to the complex reactions and limited selectivity,a comprehensive understanding of the mechanisms is crucial to further development and commercialization.Moreover,NO_(3)^(-)RR is a promising strategy for simultaneous water treatment and NH_(3)production.A detailed overview of the recent progress in NO_(3)^(-)RR for NH_(3)production with nontransition and transition metal based electrocatalysts is summarized.In addition,critical advanced techniques,future challenges,and prospects are discussed to guide future research on transition metal-based catalysts for commercial NH_(3)synthesis by NO_(3)^(-)reduction.
基金supported by a grant from the Research Grants Council of the Hong Kong Special Administration Region,China(SRFS2021-7S04)Partial support was also received from the Seed Funding for Strategic Interdisciplinary Research Scheme(102010174)+1 种基金Seed Fund for Basic Research(202111159075)of The University of Hong KongIn addition,part of this work was supported by the European Union’s Horizon 2020 research and innovation programme under grant agreement INTELWAT(No 958454).
文摘Membrane desalination is an economical and energy-efficient method to meet the current worldwide water scarcity.However,state-of-the-art reverse osmosis membranes are gradually being replaced by novel membrane materials as a result of ongoing technological advancements.These novel materials possess intrinsic pore structures or can be assembled to form lamellar membrane channels for selective transport of water or solutes(e.g.,NaCl).Still,in real applications,the results fall below the theoretical predictions,and a few properties,including large-scale fabrication,mechanical strength,and chemical stability,also have an impact on the overall effectiveness of those materials.In view of this,we develop a new evaluation framework in the form of radar charts with five dimensions(i.e.,water permeance,water/NaCl selectivity,membrane cost,scale of development,and stability)to assess the advantages,disadvantages,and potential of state-of-the-art and newly developed desalination membranes.In this framework,the reported thin film nanocomposite membranes and membranes developed from novel materials were compared with the state-of-the-art thin film composite membranes.This review will demonstrate the current advancements in novel membrane materials and bridge the gap between different desalination membranes.In this review,we also point out the prospects and challenges of next-generation membranes for desalination applications.We believe that this comprehensive framework may be used as a future reference for designing next-generation desalination membranes and will encourage further research and development in the field of membrane technology,leading to new insights and advancements.
基金financial assistance provided by the National Natural Science Foundation of China (Nos. B14021 and 51304209)the Science Foundation of Jiangsu (No. 16KJB580014)
文摘Energy and resources including coal, oil, and gas are in demand all over the world. Because these resources near the earth's surface have been exploited for many years, the extraction depth has increased.As mining shafts in the coal extraction process become deeper, especially in western China, an artificial freezing method is used and is concentrated in the fractured rock mass. The frost-heaving pressure(FHP)is directly related to the degree of damage of the fractured rock mass. This paper is focused on FHP during the freezing process, with emphasis on the frost-heaving phenomenon in engineering materials. A review of the frost phenomenon in the geotechnical engineering literature indicates that:(1) During the soil freezing process, the ice content that is influenced by unfrozen water and the freezing rate are the determining factors of FHP;(2) During the freezing process of rock and other porous media, the resulting cracks should be considered because the FHP may damage the crack structure;(3) The FHP in a joint rock mass is analyzed by the joint deformation in field and experimental tests and can be simulated by the equivalent expansion method including water migration and joint deformation.
基金Iranian Offshore Oil Company (IOOC) for financial support of this work
文摘Applying the standard Galerkin finite element method for solving flow problems in porous media encounters some difficulties such as numerical oscillation at the shock front and discontinuity of the velocity field on element faces.Discontinuity of velocity field leads this method not to conserve mass locally.Moreover,the accuracy and stability of a solution is highly affected by a non-conservative method.In this paper,a three dimensional control volume finite element method is developed for twophase fluid flow simulation which overcomes the deficiency of the standard finite element method,and attains high-orders of accuracy at a reasonable computational cost.Moreover,this method is capable of handling heterogeneity in a very rational way.A fully implicit scheme is applied to temporal discretization of the governing equations to achieve an unconditionally stable solution.The accuracy and efficiency of the method are verified by simulating some waterflooding experiments.Some representative examples are presented to illustrate the capability of the method to simulate two-phase fluid flow in heterogeneous porous media.
基金supported by the National Natural Science Foundation of China(51809169,51879159)Chang Jiang Scholars Program(T2014099)+2 种基金Shanghai Excellent Academic Leaders Program(17XD1402300)Innovative Special Project of Numerical Tank of Ministry of Industry and Information Technology of China(2016-23/09)National Key Research and Development Program of China(2019YFB1704203,2019YFC0312400).
文摘Complex flow around floating structures is a highly nonlinear problem,and it is a typical feature in ship and ocean engineering.Traditional experimental methods and potential flow theory have limitations in predicting complex viscous flows.With the improvement of high-performance computing and the development of numerical techniques,computational fluid dynamics(CFD)has become increasingly powerful in predicting the complex viscous flow around floating structures.This paper reviews the recent progress in CFD techniques for numerical solutions of typical complex viscous flows in ship and ocean engineering.Applications to free-surface flows,breaking bow waves of high-speed ship,ship hull-propeller-rudder interaction,vortexinduced vibration of risers,vortex-induced motions of deep-draft platforms,and floating offshore wind turbines are discussed.Typical techniques,including volume of fluid for sharp interface,dynamic overset grid,detached eddy simulation,and fluid-structure coupling,are reviewed along with their applications.Some novel techniques,such as high-efficiency Cartesian grid method and GPU acceleration technique,are discussed in the last part as the future perspective for further enhancement of accuracy and efficiency for CFD simulations of complex flow in ship and ocean engineering.
基金Supported by the National Key Research and Development Program of China(2019YFB1704200)the National Natural Science Foundation of China(51879159,52131102).
文摘With the significant development of computer hardware,many advanced numerical techniques have been proposed to investigate complex hydrodynamic problems.This article aims to provide a detailed review of moving particle semi-implicit(MPS)techniques and their application in ocean and coastal engineering.The achievements of the MPS method in stability and accuracy,boundary conditions,and acceleration techniques are discussed.The applications of the MPS method,which are classified into two main categories,namely,multiphase flows and fluid-structure interactions,are introduced.Finally,the prospects and conclusions are highlighted.The MPS method has the potential to solve practical problems.
基金financial support from the National Natural Science Foundation of China (No. 51768016)Guangxi Natural Science Foundation (No. 2018GXNSFAA138199)Guangxi Engineering and Technology Center for Utilization of Industrial Waste Residue in Building Materials, Guangxi Key Laboratory of New Energy and Building Energy Saving (19-J-21-17)。
文摘Development of high-efficiency and low-cost electrocatalyst for oxygen evolution reaction(OER) is very important for use at alkaline water electrolysis.Metal-organic frameworks(MOF) provide a rich platform for designing multi-functional materials due to their controllable composition and ultra-high surface area.Herein,we report our findings in the development of amorphous nickel-cobalt bimetal-organic framework nanosheets with crystalline motifs via a simple "ligands hybridization engineering" strategy.These complexes' ligands contain inorganic ligands(H_2 O and NO_3) and organic ones,hexamethylenetetramine(HMT).Further,we investigated a series of mixed-metal with multi-ligands materials as OER catalysts to explore their possible advantages and features.It is found that the Ni doping is an effective approach for optimizing the electronic configuration,changing lattice ordering degree,and thus enhancing activities of HMT-based electrocatalysts.Also,the crystalline-amorphous boundaries of various HMTbased electrocatalyst can be easily controlled by simply changing amounts of Ni-precursor added.As a result,the optimized ultrathin(Co,0.3 Ni)-HMT nanosheets can reach a current density of 10 mA cm^(-2)at low overpotential of 330 mV with a small Tafel slope of 66 mV dec^(-1).Our findings show that the electronic structure changes induced by Ni doping,2 D nanosheet structure,and MOF frameworks with multiligands compositions play critical roles in the enhancement of the kinetically sluggish electrocatalytic OER.The present study emphasizes the importance of ligands and active metals via hybridization for exploring novel efficient electrocatalysts.
基金This research was supported by Science Foundation of China University of Petroleum,Beijing(No.2462023BJRC001)National Natural Science Foundation of China Project(No.52204039).
文摘On 2019-03-04,the largest induced earthquake(ML4.18)occurred in the East Shale Basin,Alberta,and the underlying physical mechanisms have not been fully understood.This paper proposes a synthetical geoengineering methodology to comprehensively characterize this earthquake caused by hydraulic fracturing.Based on 3D structural,petrophysical,and geomechanical models,an unconventional fracture model is constructed by considering the stress shadow between adjacent hydraulic fractures and the interactions between hydraulic and natural fractures.Coupled poroelastic simulations are conducted to reveal the triggering mechanisms of induced seismicity.It is found that four vertical basement-rooted faults were identified via focal mechanisms analysis.The brittleness index(BI)along two horizontal wells has a high magnitude(BI>0.5),indicating the potential susceptibility of rock brittleness.Due to the presence of overpressure,pre-existing faults in the Duvernay Formation are highly susceptible to fault reactivation.The occurrence of the earthquake clusters has been attributed to the fracturing fluid injection during the west 38^(th)-39^(th) stage and east 38^(th) stage completions.Rock brittleness,formation overpressure,and large fracturing job size account for the nucleation of earthquake clusters,and unconventional natural-hydraulic fracture networks provide fluid flow pathways to cause fault reactivation.This workflow can be used to mitigate potential seismic risks in unconventional reservoirs in other fields.
文摘A new model is proposed to improve the efficiency of structural modeling. In this model, the bridge structural components are expressed with component description, parametric description and geometric description in a software system. This model provides both convenience and flexibility for users in structural modeling process. The object-oriented method is applied in the model implementation. A bridge analysis preprocessor is developed on the basis of this model. It provides an effective way for bridge modeling.
文摘This paper presents a comprehensive review of historical theory development and current construction practice of pavement engineering in China. Mechanical models, design guides, construction techniques, evaluation methods and maintenance standards are elaborated for Portland cement concrete （PCC） pavements methodology among pavements of rural highways, urban roads and asphalt concrete （AC） pavements. Differences in design and airport fields are discussed based on service requirements. Lessons and experiences based on the past 20 years＇ construction practice and pavement performance are summarized. Current research areas in pavement engineering associated with unconventional geological and/or landscaping in China＇s highway construction and national strategic plan for pavement engineering are also covered.
文摘Application of pressured grouting method (PGM) in pile engineering can tackle problems encountered during construction of bored piles. Bearing capacity of piles can be increased through compaction of subsoils around piles. This paper reports research efforts of this technique by the pile research team in Southwest Jiaotong University in last decade with respect to the construction process, test findings, and primary research conclusions. The social-economical benefits of this method and application market in pile engineering are also analyzed.
基金Supported by National Natural Science Foundation of China (52104029,U2139204)PetroChina Science and Technology Innovation Foundation (2021 DQ02-0501)。
文摘According to the variable toe-to-heel well spacing, combined with the dislocation theory, discrete lattice method, and finite-element-method(FEM) based fluid-solid coupling, an integrated geological-engineering method of volume fracturing for fan-shaped well pattern is proposed considering the geomechanical modeling, induced stress calculation, hydraulic fracturing simulation, and post-frac productivity evaluation. Besides, we propose the differential fracturing design for the conventional productivity-area and the potential production area for fan-shaped horizontal wells. After the fracturing of the conventional production area for H1 fan-shaped well platform, the research shows that the maximum reduction of the horizontal principal stress difference in the potential productivity-area is 0.2 MPa, which cannot cause the stress reversal, but this reduction is still conducive to the lateral propagation of hydraulic fractures. According to the optimized fracturing design, in zone-Ⅰ of the potential production area, only Well 2 is fractured, with a cluster spacing of 30 m and an injection rate of 12 m^(3)/min per stage;in zone-Ⅱ, Well 2 is fractured before Well 3, with a cluster spacing of 30 m and an injection rate of 12 m^(3)/min per stage. The swept area of the pore pressure drop in the potential production area is small, showing that the reservoir is not well developed. The hydraulic fracturing in the toe area can be improved by, for example, properly densifying the fractures and adjusting the fracture distribution, in order to enhance the swept volume and increase the reservoir utilization.
基金This work was supported by the National Key R&D Program‘Transportation Infrastructure’project(No.2022YFB2603400).
文摘The compaction quality of subgrade filler strongly affects subgrade settlement.The main objective of this research is to analyze the macro-and micro-mechanical compaction characteristics of subgrade filler based on the real shape of coarse particles.First,an improved Viola-Jones algorithm is employed to establish a digitalized 2D particle database for coarse particle shape evaluation and discrete modeling purposes of subgrade filler.Shape indexes of 2D subgrade filler are then computed and statistically analyzed.Finally,numerical simulations are performed to quantitatively investigate the effects of the aspect ratio(AR)and interparticle friction coefficient(μ)on the macro-and micro-mechanical compaction characteristics of subgrade filler based on the discrete element method(DEM).The results show that with the increasing AR,the coarse particles are narrower,leading to the increasing movement of fine particles during compaction,which indicates that it is difficult for slender coarse particles to inhibit the migration of fine particles.Moreover,the average displacement of particles is strongly influenced by the AR,indicating that their occlusion under power relies on particle shapes.The dis-placement and velocity of fine particles are much greater than those of the coarse particles,which shows that compaction is primarily a migration of fine particles.Under the cyclic load,the interparticle friction coefficientμhas little effect on the internal structure of the sample;under the quasi-static loads,however,the increase inμwill lead to a significant increase in the porosity of the sample.This study could not only provide a novel approach to investigate the compaction mechanism but also establish a new theoretical basis for the evaluation of intelligent subgrade compaction.
基金This work was supported of National Natural Science Foundation of China Fund(No.52306033)State Key Laboratory of Engines Fund(No.SKLE-K2022-07)the Jiangxi Provincial Postgraduate Innovation Special Fund(No.YC2022-s513).
文摘The supercritical CO_(2) Brayton cycle is considered a promising energy conversion system for Generation IV reactors for its simple layout,compact structure,and high cycle efficiency.Mathematical models of four Brayton cycle layouts are developed in this study for different reactors to reduce the cost and increase the thermohydraulic performance of nuclear power generation to promote the commercialization of nuclear energy.Parametric analysis,multi-objective optimizations,and four decision-making methods are applied to obtain each Brayton scheme’s optimal thermohydraulic and economic indexes.Results show that for the same design thermal power scale of reactors,the higher the core’s exit temperature,the better the Brayton cycle’s thermo-economic performance.Among the four-cycle layouts,the recompression cycle(RC)has the best overall performance,followed by the simple recuperation cycle(SR)and the intercooling cycle(IC),and the worst is the reheating cycle(RH).However,RH has the lowest total cost of investment(C_(tot))of$1619.85 million,and IC has the lowest levelized cost of energy(LCOE)of 0.012$/(kWh).The nuclear Brayton cycle system’s overall performance has been improved due to optimization.The performance of the molten salt reactor combined with the intercooling cycle(MSR-IC)scheme has the greatest improvement,with the net output power(W_(net)),thermal efficiencyη_(t),and exergy efficiency(η_(e))improved by 8.58%,8.58%,and 11.21%,respectively.The performance of the lead-cooled fast reactor combined with the simple recuperation cycle scheme was optimized to increase C_(tot) by 27.78%.In comparison,the internal rate of return(IRR)increased by only 7.8%,which is not friendly to investors with limited funds.For the nuclear Brayton cycle,the molten salt reactor combined with the recompression cycle scheme should receive priority,and the gas-cooled fast reactor combined with the reheating cycle scheme should be considered carefully.
基金supported by China Postdoctoral Science Foundation(No.2023TQ0247)Shenzhen Science and Technology Program(No.JCYJ20220530140602005)+2 种基金the Fundamental Research Funds for the Central Universities(No.2042023kfyq03)Guangdong Basic and Applied Basic Research Foundation(No.2023A1515111071)the Postdoctoral Fellowship Program(Grade B)of China Postdoctoral Science Foundation(No.GZB20230544).
文摘Knowledge of the mechanical behavior of planetary rocks is indispensable for space explorations.The scarcity of pristine samples and the irregular shapes of planetary meteorites make it difficult to obtain representative samples for conventional macroscale rock mechanics experiments(macro-RMEs).This critical review discusses recent advances in microscale RMEs(micro-RMEs)techniques and the upscaling methods for extracting mechanical parameters.Methods of mineralogical and microstructural analyses,along with non-destructive mechanical techniques,have provided new opportunities for studying planetary rocks with unprecedented precision and capabilities.First,we summarize several mainstream methods for obtaining the mineralogy and microstructure of planetary rocks.Then,nondestructive micromechanical testing methods,nanoindentation and atomic force microscopy(AFM),are detailed reviewed,illustrating the principles,advantages,influencing factors,and available testing results from literature.Subsequently,several feasible upscaling methods that bridge the micro-measurements of meteorite pieces to the strength of the intact body are introduced.Finally,the potential applications of planetary rock mechanics research to guiding the design and execution of space missions are environed,ranging from sample return missions and planetary defense to extraterrestrial construction.These discussions are expected to broaden the understanding of the microscale mechanical properties of planetary rocks and their significant role in deep space exploration.
基金supported by the National Natural Science Foundation of China(No.42307258)the technological research projects in Sichuan Province(No.2022YFSY0007)the China Atomic Energy Authority(CAEA)through the Geological Disposal Program.
文摘Stability analysis of underground constructions requires a model study of rock masses’ long-term performance. Creep tests under different stress conditions was conducted on intact granite and granite samples fractured at 30° and 45° angles. The experimental results indicate that the steady creep strain rates of intact and fractured rock present an exponential increase trend with the increase of stress level. A nonlinear creep model is developed based on the experimental results, in which the initial damage caused by fracture together with the damage caused by constant load have been taken into consideration. The fitting analysis results indicated that the model proposed is more accurate at identifying the full creep regions in fractured granite, especially the accelerated stage of creep deformation. The least-square fit error of the proposed creep model is significantly lower than that of Nishihara model by almost an order of magnitude. An analysis of the effects of elastic modulus, viscosity coefficient, and damage factors on fractured rock strain rate and creep strain is conducted. If no consideration is given to the effects of the damage, the proposed nonlinear creep model can degenerate into to the classical Nishihara model.
基金supported by the National Key Research and Development Program of China(Nos.2021YFF0500300 and 2023YFB3711300)the Strategic Research and Consulting Project of the Chinese Academy of Engineering(Nos.2023-XZ-90 and 2023-JB-09-10).
文摘Establishing a base on the Moon is one of the new goals of human lunar exploration in recent years.Sintered lunar regolith is one of the most potential building materials for lunar bases.The physical,mechanical and thermal properties of sintered lunar regolith are vital performance indices for the structural design of a lunar base and analysis of many critical mechanical and thermal issues.In this study,the HUST-1 lunar regolith simulant(HLRS)was sintered at 1030,1040,1050,1060,1070,and 1080℃.The effect of sintering temperature on the compressive strength was investigated,and the exact value of the optimum vacuum sintering temperature was determined between 1040 and 1060℃.Then,the microstructure and material composition of vacuum sintered HLRS at different temperatures were characterized.It was found that the sintering temperature has no significant effect on the mineral composition in the temperature range of 1030-1080℃.Besides,the heat capacity,thermal conductivity,and coefficient of thermal expansion(CTE)of vacuum sintered HLRS at different temperatures were investigated.Specific heat capacity of sintered samples increases with the increase of test temperature within the temperature range from-75 to 145℃.Besides,the thermal conductivity of the sintered sample is proportional to density.Finally,the two temperatures of 1040 and 1050℃were selected for a more detailed study of mechanical properties.The results showed that compressive strength of sintered sample is much higher than tensile strength.This study reveals the effects of sintering temperature on the physical,mechanical and thermal properties of vacuum sintered HLRS,and these material parameters will provide support for the construction of future lunar bases.
文摘The ballistic resistance and failure pattern of a bi-layer alumina 99.5%-aluminium alloy 1100-H12 target against steel 4340 ogival nosed projectile has been explored in the present experimental cum numerical study.In the experimental investigation,damage induced in the ceramic layer has been quantified in terms of number of cracks developed and failure zone dimensions.The resultant damage in the backing layer has been studied with variation in the bulge and perforation hole in the backing layer with the varying incidence velocity.The discussion of the experimental results has been further followed by three dimensional finite element computations using ABAQUS/Explicit finite code to investigate the behaviour of different types of bi-layer targets under multi-hit projectile impact.The JH-2 constitutive model has been used to reproduce the behaviour of alumina 99.5%and JC constitutive model has been used for steel 4340 and aluminium alloy 1100-H12.The total energy dissipation has been noted to be of lesser magnitude in case of sub-sequential impact in comparison to simultaneous impact of two projectiles.The distance between the impact points of two projectiles also effected the ballistic resistance of bi-layer target.The ballistic resistance of single tile ceramic front layer and four tile ceramic of equivalent area found to be dependent upon the boundary conditions provided to the target.
