The geological structure of coal seams in China is remarkably varied and complex,with coalbed methane reservoirs marked by significant heterogeneity and low permeability,creating substantial technical challenges for e...The geological structure of coal seams in China is remarkably varied and complex,with coalbed methane reservoirs marked by significant heterogeneity and low permeability,creating substantial technical challenges for efficient extraction.This study systematically investigates the impact of liquid nitrogen immersion(LNI)on the coal’s pore structure and its mechanism of enhancing permeability with a combination of quantitative nuclear magnetic resonance(NMR)analysis,nitrogen adsorption experiments,and fractal dimension calculations.The results demonstrate that LNI can damage the coal’s pore structure and promote fracture expansion through thermal stress induction and moisture phase transformation,thereby enhancing the permeability of coal seams.The T_(2)peak area in the NMR experiments on coal samples subjected to LNI treatment shows a significant increase,the Brunauer-Emmett-Teller(BET)specific surface area decreases to 6.02 m^(2)/g,and the Barrett-Joyner-Halenda(BJH)total pore volume increases to 14.99 mm^(3)/g.Furthermore,changes in fractal dimensions(D_(1)rising from 2.804 to 2.837,and D_(2)falling from 2.757 to 2.594)indicate a notable enhancement in the complexity of the pore structure.With increasing LNI cycles,the adsorption capacity of the coal samples diminishes,suggesting a significant optimization of the pore structure.This optimization is particularly evident in the reconstruction of the micropore structure,which in turn greatly enhances the complexity and connectivity of the sample’s pore network.In summary,the study concludes that LNI technology can effectively improve the permeability of coal seams and the extraction efficiency of coalbed methane by optimizing the micropore structure and enhancing pore connectivity,which offers a potential method for enhancing the permeability of gas-bearing coal seams and facilitating the development and utilization of coalbed methane.展开更多
Due to the extreme complexity of mechanical response of soft surrounding rock(SR) around a tunnel under high geostatic stress conditions, the integration of physical and numerical modeling techniques was adopted. Base...Due to the extreme complexity of mechanical response of soft surrounding rock(SR) around a tunnel under high geostatic stress conditions, the integration of physical and numerical modeling techniques was adopted. Based on the similarity theory, new composite-similar material was developed, which showed good agreement with the similarity relation and successfully simulated physico-mechanical properties(PMP) of deep buried soft rock. And the 800 mm×800 mm×200 mm physical model(PM) was conducted, in which the endoscopic camera technique was adopted to track the entire process of failure of the model all the time. The experimental results indicate that the deformation of SR around a underground cavern possessed the characteristics of development by stages and in delay, and the initial damage of SR could induce rapid failure in the later stage, and the whole process could be divided into three stages, including the localized extension of crack(the horizontal load(HL) was in the range of 130 k N to 170 k N, the vertical load(VL) was in the range of 119 k N to 153.8 k N), rapid crack coalescence(the HL was in the range of 170 k N to 210 k N, the VL was in the range of 153.8 k N to 182.5 k N) and residual strength(the HL was greater than 210 k N, the VL was greater than 182.5 k N). Under the high stress conditions, the phenomenon of deformation localization in the SR became serious and different space positions show different deformation characteristics. In order to further explore the deformation localization and progressive failure phenomenon of soft SR around the deeply buried tunnel, applying the analysis software of FLAC3 D three-dimensional explicit finite-difference method, based on the composite strain-softening model of Mohr-Coulomb shear failure and tensile failure, the calculation method of large deformation was adopted. Then, the comparative analysis between the PM experiment and numerical simulation of the three centered arch tunnels was implemented and the relationship of deformation localization and progressive failure of SR around a tunnel under high stress conditions was discussed.展开更多
基金Projects(52204226,52104204,52474276)supported by the National Natural Science Foundation of ChinaProject(tsqnz20221140)supported by the Taishan Scholars Project of China+1 种基金Projects(ZR2022QE243,ZR2024ME097)supported by the Natural Science Foundation of Shandong Province of ChinaProject(252300421010)supported by the Excellent Youth Foundation of Henan Scientific Committee,China。
文摘The geological structure of coal seams in China is remarkably varied and complex,with coalbed methane reservoirs marked by significant heterogeneity and low permeability,creating substantial technical challenges for efficient extraction.This study systematically investigates the impact of liquid nitrogen immersion(LNI)on the coal’s pore structure and its mechanism of enhancing permeability with a combination of quantitative nuclear magnetic resonance(NMR)analysis,nitrogen adsorption experiments,and fractal dimension calculations.The results demonstrate that LNI can damage the coal’s pore structure and promote fracture expansion through thermal stress induction and moisture phase transformation,thereby enhancing the permeability of coal seams.The T_(2)peak area in the NMR experiments on coal samples subjected to LNI treatment shows a significant increase,the Brunauer-Emmett-Teller(BET)specific surface area decreases to 6.02 m^(2)/g,and the Barrett-Joyner-Halenda(BJH)total pore volume increases to 14.99 mm^(3)/g.Furthermore,changes in fractal dimensions(D_(1)rising from 2.804 to 2.837,and D_(2)falling from 2.757 to 2.594)indicate a notable enhancement in the complexity of the pore structure.With increasing LNI cycles,the adsorption capacity of the coal samples diminishes,suggesting a significant optimization of the pore structure.This optimization is particularly evident in the reconstruction of the micropore structure,which in turn greatly enhances the complexity and connectivity of the sample’s pore network.In summary,the study concludes that LNI technology can effectively improve the permeability of coal seams and the extraction efficiency of coalbed methane by optimizing the micropore structure and enhancing pore connectivity,which offers a potential method for enhancing the permeability of gas-bearing coal seams and facilitating the development and utilization of coalbed methane.
基金Projects(51374257,50804060)supported by the National Natural Science Foundation of ChinaProject(NCET-09-0844)supported by the New Century Excellent Talent Foundation from MOE of China
文摘Due to the extreme complexity of mechanical response of soft surrounding rock(SR) around a tunnel under high geostatic stress conditions, the integration of physical and numerical modeling techniques was adopted. Based on the similarity theory, new composite-similar material was developed, which showed good agreement with the similarity relation and successfully simulated physico-mechanical properties(PMP) of deep buried soft rock. And the 800 mm×800 mm×200 mm physical model(PM) was conducted, in which the endoscopic camera technique was adopted to track the entire process of failure of the model all the time. The experimental results indicate that the deformation of SR around a underground cavern possessed the characteristics of development by stages and in delay, and the initial damage of SR could induce rapid failure in the later stage, and the whole process could be divided into three stages, including the localized extension of crack(the horizontal load(HL) was in the range of 130 k N to 170 k N, the vertical load(VL) was in the range of 119 k N to 153.8 k N), rapid crack coalescence(the HL was in the range of 170 k N to 210 k N, the VL was in the range of 153.8 k N to 182.5 k N) and residual strength(the HL was greater than 210 k N, the VL was greater than 182.5 k N). Under the high stress conditions, the phenomenon of deformation localization in the SR became serious and different space positions show different deformation characteristics. In order to further explore the deformation localization and progressive failure phenomenon of soft SR around the deeply buried tunnel, applying the analysis software of FLAC3 D three-dimensional explicit finite-difference method, based on the composite strain-softening model of Mohr-Coulomb shear failure and tensile failure, the calculation method of large deformation was adopted. Then, the comparative analysis between the PM experiment and numerical simulation of the three centered arch tunnels was implemented and the relationship of deformation localization and progressive failure of SR around a tunnel under high stress conditions was discussed.
